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Catalyst Leaching as an Efficient Tool for Constructing New Catalytic Reactions: Application to the Synthesis of Cyclic Vinyl Sulfides and Vinyl Selenides (Eur. J. Inorg. Chem. 9/2009)
Article first published online: 9 MAR 2009
DOI: 10.1002/ejic.200990018
Copyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Ananikov, V. P., Gayduk, K. A., Beletskaya, I. P., Khrustalev, V. N. and Antipin, M. Yu. (2009), Catalyst Leaching as an Efficient Tool for Constructing New Catalytic Reactions: Application to the Synthesis of Cyclic Vinyl Sulfides and Vinyl Selenides (Eur. J. Inorg. Chem. 9/2009). Eur. J. Inorg. Chem., 2009: 1127. doi: 10.1002/ejic.200990018
Publication History
- Issue published online: 9 MAR 2009
- Article first published online: 9 MAR 2009
- Abstract
- Cited By
Abstract
The cover picture shows the impact of the phosphane ligand on solid metal nanoparticles, which initiates transformation of the metal species into a high-performance catalyst. The evolution of the transition-metal complexes was monitored by NMR spectroscopy, and the active form of the catalyst was detected in the 2D HMQC spectrum. A novel synthetic procedure to access cyclic vinyl chalcogenides was developed by utilizing an in situ designed catalyst in an E–E bond addition reaction to acetylenes (E = S, Se). Details are discussed in the article by V. P. Ananikov, I. P. Beletskaya et al. on p. 1149 ff.