Short Communication

Phosphane-Pyridine Iron Complexes: Synthesis, Characterization and Application in Reductive Amination through the Hydrosilylation Reaction

  1. Hassen Jaafar1,
  2. Haoquan Li1,
  3. Luis C. Misal Castro1,
  4. Jianxia Zheng1,
  5. Thierry Roisnel2,
  6. Vincent Dorcet2,
  7. Jean-Baptiste Sortais1,
  8. Christophe Darcel1

Article first published online: 22 JUN 2012

DOI: 10.1002/ejic.201200550

Issue

European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Volume 2012, Issue 22, pages 3546–3550, August 2012

Additional Information

How to Cite

Jaafar, H., Li, H., Misal Castro, L. C., Zheng, J., Roisnel, T., Dorcet, V., Sortais, J.-B. and Darcel, C. (2012), Phosphane-Pyridine Iron Complexes: Synthesis, Characterization and Application in Reductive Amination through the Hydrosilylation Reaction. Eur. J. Inorg. Chem., 2012: 3546–3550. doi: 10.1002/ejic.201200550

Author Information

  1. 1

    UMR 6226 CNRS – Université de Rennes 1 “Institut des Sciences Chimiques de Rennes” “Organometallics: Materials and Catalysis” – Campus de Beaulieu, Bat 10C, 263 avenue du Général Leclerc 35042 Rennes Cedex, France

  2. 2

    UMR 6226 CNRS – Université de Rennes 1 “Institut des Sciences Chimiques de Rennes” “Centre de Diffractométrie X” – Campus de Beaulieu, Bat 10B, 263 avenue du Général Leclerc 35042 Rennes Cedex, France

Publication History

  1. Issue published online: 24 JUL 2012
  2. Article first published online: 22 JUN 2012
  3. Manuscript Received: 22 MAY 2012

Funded by

  • Université de Rennes 1
  • Centre National de la Recherche Scientifique (CNRS)
  • Rennes Métropole and Ministère de l′Enseignement Supérieur et de la Recherche
  • “Région Bretagne”
  • Rennes 1 Foundation
  • Ministère des Affaires Etrangères
  • Fundación Gran Mariscal de Ayacucho
  • Axa Research Fund

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article with Supporting Information (HTML) Get PDF (392K)

Keywords:

  • Iron;
  • Homogeneous catalysis;
  • Hydrosilylation;
  • Amination

Abstract

A series of 6 cyclopentadienyl phosphanyl-pyridine piano-stool iron complexes was prepared in good yields, characterized, and studied in the catalytic reductive amination of benzaldehyde derivatives through hydrosilylation reactions by using polymethylhydrosiloxane as the hydrosilane source and in dimethylcarbonate as the solvent at 40 °C. Single-crystal X-ray structural analyses were performed for all the complexes.

View Full Article with Supporting Information (HTML) Get PDF (392K)