Full Paper

Structural Characterization of Amidinatobismuth(III) Diazides

  1. Benjamin Lyhs,
  2. Dieter Bläser,
  3. Christoph Wölper,
  4. Rebekka Haack,
  5. Georg Jansen,
  6. Stephan Schulz

Article first published online: 17 AUG 2012

DOI: 10.1002/ejic.201200699

Issue

European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Volume 2012, Issue 27, pages 4350–4355, September 2012

Additional Information

How to Cite

Lyhs, B., Bläser, D., Wölper, C., Haack, R., Jansen, G. and Schulz, S. (2012), Structural Characterization of Amidinatobismuth(III) Diazides. Eur. J. Inorg. Chem., 2012: 4350–4355. doi: 10.1002/ejic.201200699

Author Information

  1. Faculty of Chemistry, University of Duisburg-Essen, 45117 Essen, Germany, Fax: +49-201-1834635, http://www.uni-due.de/ak_schulz/

Publication History

  1. Issue published online: 11 SEP 2012
  2. Article first published online: 17 AUG 2012
  3. Manuscript Received: 26 JUN 2012

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article with Supporting Information (HTML) Get PDF (434K)

Keywords:

  • Bismuth;
  • N ligands;
  • Azides

Abstract

Amidinatobismuth(III) diazides LBi(N3)2 {L1 = [tBuC(NiPr)2] (2), L2 = [tBuC(NDipp)2] (3, Dipp = 2,6-iPr2-C6H3)} were synthesized in high yields by metathesis reactions of the corresponding halide-substituted complexes L1BiI2 (1) and L2BiCl2 with AgN3. Compounds 1–3 were characterized by using elemental analyses, multinuclear NMR (1H, 13C), and IR spectroscopy as well as by using single-crystal X-ray diffraction (for 2, 3).

View Full Article with Supporting Information (HTML) Get PDF (434K)