bapbpy = N6,N6′-di(pyridin-2-yl)-2,2′-bipyridine-6,6′-diamine.
Effect of Metal Dilution on the Thermal Spin Transition of [FexZn1–x(bapbpy)(NCS)2]†
Version of Record online: 21 JAN 2013
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
European Journal of Inorganic Chemistry
Special Issue: Spin-Crossover Complexes (Cluster Issue)
Volume 2013, Issue 5-6, pages 1033–1042, February 2013
How to Cite
Zheng, S., Siegler, M. A., Sánchez Costa, J., Fu, W.-T. and Bonnet, S. (2013), Effect of Metal Dilution on the Thermal Spin Transition of [FexZn1–x(bapbpy)(NCS)2] . Eur. J. Inorg. Chem., 2013: 1033–1042. doi: 10.1002/ejic.201201183
- Issue online: 18 FEB 2013
- Version of Record online: 21 JAN 2013
- Manuscript Received: 30 SEP 2012
- Solid-state chemistry;
- Magnetic properties;
- Phase transitions
This study reports on the effects of zinc dilution on the structure and magnetic properties of the mononuclear two-step spin-crossover compound [Fe(bapbpy)(NCS)2] (1; bapbpy = N6,N6′-di(pyridin-2-yl)-2,2′-bipyridine-6,6′-diamine). The zinc analogue of 1, [Zn(bapbpy)(NCS)2] (3), was synthesized and characterized by X-ray powder diffraction, which suggests different structural features from 1. The crystal structure of the related compound [Fe(bapbpy)(NCS)]2[Zn(NCS)4]·3DMF (4) was determined by single-crystal X-ray diffraction. Unlike the hexacoordinate FeII in 1, the ZnII ions in 4 are pentacoordinate. Nine diluted powder samples [FexZn1–x(bapbpy)(NCS)2] were prepared with iron fractions of x = 0.89, 0.81, 0.76, 0.65, 0.60, 0.53, 0.44, 0.38, and 0.24. According to powder X-ray diffraction and infrared spectroscopy, the phase of compound 1 is retained in the zinc-diluted samples when x > 0.53. At higher dilutions (i.e., when x < 0.53), the phase of compound 3 gradually takes over, but the SCO of the iron complexes in the zinc phase remains observable at an iron fraction as low as x = 0.24. Powder X-ray diffraction and infrared spectroscopy data indicate the presence of the zinc phase only (i.e., compound 3) when x ≤ 0.24. Magnetic susceptibility measurements on the diluted samples show that upon decreasing the iron fraction x, both hysteresis cycles become initially narrower, and then vanish to lead to a single-step SCO material at x = 0.76. Upon additional increase of the zinc contents, the cooperativity of the SCO gradually vanishes to lead to a noncooperative SCO material at the lowest iron fraction studied (x = 0.24). Despite the different coordination properties of the bapbpy ligand towards FeII and ZnII, the spin crossover of the hexacoordinate FeII complex is robust enough to withstand dilution into a magnetically silent ZnII phase that is structurally different from that of the iron compound.