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Keywords:

  • Macrocycles;
  • Cage compounds;
  • Cycloaddition;
  • Clathrochelates;
  • Ligand reactivity

Abstract

Cycloaddition of a new pyrazoloxime to macrocyclic iron(II) bis(α-benzyldioximate) unexpectedly gave a mixture of the first hybrid clathrochelatoscorpionate and its pyrazoloxime-armed macrocyclic intermediate, which were characterized by X-ray crystallography, spectroscopy, and cyclic voltammetry.