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Abstract

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The cover picture shows the skyline of Rostock at night with a titanocene bis(trimethylsilyl)acetylene complex as well as the unusual metallacyclic complex [Cp2Ti(η2-Me3SiN=S=NSiMe3)], which can readily be obtained from the former complex by reaction with the sulfurdiimide Me3SiN=S=NSiMe3, rising brightly into the sky. The synthesis and a detailed theoretical study of the structure and bonding of this exotic organometallic compound are described in the article by E. D. Jemmis, A. Schulz, U. Rosenthal et al. on p. 611 ff.