European Journal of Inorganic Chemistry

Cover image for Vol. 2008 Issue 15

May 2008

Volume 2008, Issue 15

Pages 2367–2481

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    7. Correction
    1. Synthesis and Crystal Structure Investigations of Trivalent Rare Earth (Y3+, Nd3+, Er3+) Thienyl-Substituted Methoxides (Eur. J. Inorg. Chem. 15/2008) (page 2367)

      Michael Veith, Céline Belot, Laurent Guyard, Volker Huch, Michael Knorr and Michael Zimmer

      Article first published online: 8 MAY 2008 | DOI: 10.1002/ejic.200890038

  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    7. Correction
    1. Graphical Abstract: Eur. J. Inorg. Chem. 15/2008 (pages 2367–2371)

      Article first published online: 8 MAY 2008 | DOI: 10.1002/ejic.200890040

  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    7. Correction
  4. Short Communications

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    7. Correction
    1. Acetylenetitanium Complex Stabilized by Aminopyridinato Ligands (pages 2377–2381)

      Awal Noor and Rhett Kempe

      Article first published online: 9 APR 2008 | DOI: 10.1002/ejic.200800132

      Thumbnail image of graphical abstract

      A rare example of a Cp-free group-4 alkyne complex was synthesized by reducing the corresponding (aminopyridinato)dichlorotitanium complex with magnesium in the presence of bis(trimethylsilyl)acetylene. Structural data indicate that the acetylene ligand is weaker bound than in related titanocenes.

    2. Designed Synthesis of Families of Misfit-Layered Compounds (pages 2382–2385)

      Qiyin Lin, Colby L. Heideman, Ngoc Nguyen, Paul Zschack, Catalin Chiritescu, David G. Cahill and David C. Johnson

      Article first published online: 17 APR 2008 | DOI: 10.1002/ejic.200800158

      Thumbnail image of graphical abstract

      More than 60 unique misfit-layered compounds [(MX)1+x]m(TX2)n have been synthesized in 5 different families with m and n values ranging from 1 to 5. The ability to prepare families of compounds with arange of m and n values from many different families will permit the correlation of composition, nanostructure, and the levels of order and disorder with physical properties.

    3. Dual Supermesityl Stabilization: A Room-Temperature-Stable 1,2,4-Triphosphole Radical, Sigmatropic Hydrogen Rearrangements, and Tetraphospholide Anion (pages 2386–2390)

      Alex S. Ionkin, William J. Marshall, Brian M. Fish, Alexander A. Marchione, Laurie A. Howe, Fredric Davidson and Charles N. McEwen

      Article first published online: 9 APR 2008 | DOI: 10.1002/ejic.200800265

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      The first stable 1H-1,2,4-triphosphole with a P–H bond, its oxidized P–P dimer, cesium 1,2,4-triphospholide and cesium tetraphospholide are synthesized and structurally characterized.

    4. A Ferromagnetically Coupled Diiron(III) Complex with a m-Phenylenediamine-Based Ligand (pages 2391–2395)

      Biplab Biswas, Sunita Salunke-Gawali, Thomas Weyhermüller, Vinzenz Bachler, Eckhard Bill and Phalguni Chaudhuri

      Article first published online: 4 APR 2008 | DOI: 10.1002/ejic.200800255

      Thumbnail image of graphical abstract

      The d5 high-spin iron(III) centers with a separation of 7.90 Å in a diferric complexare ferromagnetically coupled through the spin polarization mechanism.

  5. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    7. Correction
    1. Synthesis and Crystal Structure Investigations of Trivalent Rare Earth (Y3+, Nd3+, Er3+) Thienyl-Substituted Methoxides (pages 2397–2406)

      Michael Veith, Céline Belot, Laurent Guyard, Volker Huch, Michael Knorr and Michael Zimmer

      Article first published online: 27 FEB 2008 | DOI: 10.1002/ejic.200701259

      Thumbnail image of graphical abstract

      The aminolysis reactions between tris(2-thienyl)methanol (1) or tris(2,2′-bithienyl-5-yl)methanol (2) and M[N(SiMe3)2]3(M = Y3+, Nd3+, Er3+) yield the rare earth thienylmethoxides Y[OC(C4H3S)3]3(thf)2 (3a), {Y[OC(C4H3S)3]3(thf)2}·toluene (3b), Y[OC(C4H3S)3]3(py)2 (4a), {Y[OC(C4H3S)3]3(py)2}·toluene (4b), Y[OC(C8H5S2)3]3(thf)2 (5), {Nd[OC(C4H3S)3]3(thf)3}·thf (6), {Nd[OC(C8H5S2)3]3(thf)3}·4thf (7), Er[OC(C4H3S)3]3(thf)3 (8) and Er[OC(C8H5S2)3]3(thf) (9), whose structural characterization is reported.

    2. Plasticity in [(R4–xR1x)4N]4[Cu4{S2C2(CN)2}4] (x = 0–4) is Molded by a Guest Cation on an Elastic Anionic Host (pages 2407–2420)

      Biplab K. Maiti, Kuntal Pal and Sabyasachi Sarkar

      Article first published online: 15 APR 2008 | DOI: 10.1002/ejic.200800094

      Thumbnail image of graphical abstract

      The compounds [(R4–xR1)4N]4[Cu4{S2C2(CN)2}4], which lose plasticity on dissolution to release the relaxed elastic anion, show varying degrees of partially opened umbrella-shaped structures depending on R and R1. The molecular structural design information stored in this new cation is molded to the elastic anionic host framework through H-bonding to create a new plastic supramolecular entity.

    3. Luminescent Gold(I) and Copper(I) Phosphane Complexes Containing the 4-Nitrophenylthiolate Ligand: Observation of π[RIGHTWARDS ARROW]π* Charge-Transfer Emission (pages 2421–2428)

      Cheng-Hui Li, Steven Chi Fai Kui, Iona Hiu Tung Sham, Stephen Sin-Yin Chui and Chi-Ming Che

      Article first published online: 15 APR 2008 | DOI: 10.1002/ejic.200700675

      Thumbnail image of graphical abstract

      The photoluminescence of [(PCy3)Au(SC6H4NO2-4)] (1), [Au2(μ-dcpm)(SC6H4NO2-4)2] (2), [Au2(μ-dppm)(SC6H4NO2-4)2] (3), and [(μ2-SC6H4NO2-4)23-SC6H4NO2-4)2(CuPPh3)4] (4) in solid state and alcoholic glassy solutions at 77 K isassigned to the [π(S)[RIGHTWARDS ARROW]π*(C6H4NO2-4)] charge-transfer excited state, as supported by the results of DFT and TDDFT calculations.

    4. Template-Free Synthesis, Controlled Conversion, and CO Oxidation Properties of CeO2 Nanorods, Nanotubes, Nanowires, and Nanocubes (pages 2429–2436)

      Chengsi Pan, Dengsong Zhang, Liyi Shi and Jianhui Fang

      Article first published online: 17 APR 2008 | DOI: 10.1002/ejic.200800047

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      A template-free method is employed first to synthesize single-crystal CeO2 nanorods at room temperature and pressure, and then the controlled conversion of nanorods into nanotubes, nanowires, and nanocubes is realized. Finally, CO oxidation properties of CeO2 nanostructures were investigated systematically and CeO2 nanorods were found to have excellent catalytic performance.

    5. Coupling of Allenes with μ-Alkylidyne Ligands in Diiron Complexes: Synthesis of Novel Bridging Thio- and Aminobutadienylidene Complexes (pages 2437–2447)

      Luigi Busetto, Fabio Marchetti, Mauro Salmi, Stefano Zacchini and Valerio Zanotti

      Article first published online: 9 APR 2008 | DOI: 10.1002/ejic.200800048

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      A C4 chain is successfully constructedby assembling allenes with bridging C1 (alkylidyne) ligands. The reactions areregioselective and afford new bridgingbutadienylidene diiron complexes containing heteroatom (N, S) functionalities.

    6. Formation of Micro/Macroporous Hierarchical Spheres of Titanosilicate Umbite (pages 2448–2453)

      Víctor Sebastián, Carlos Téllez, Joaquín Coronas and Jesús Santamaría

      Article first published online: 11 APR 2008 | DOI: 10.1002/ejic.200800022

      Thumbnail image of graphical abstract

      Micro/macroporous polycrystalline spheres of microporous titanosilicate umbite were prepared by hydrothermal synthesis without the use of organic structuring agents.

    7. The Noncarbonylative Photochemistry of Group 6 Fischer Carbene Complexes (pages 2454–2462)

      Israel Fernández, Miguel A. Sierra, María José Mancheño, Mar Gómez-Gallego and Fernando P. Cossío

      Article first published online: 15 APR 2008 | DOI: 10.1002/ejic.200800146

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      Computational and experimental data rationalize the two photochemical noncarbonylative mechanisms of group 6 Fischercarbene complexes and also the photochemical reactivity of the “photoinert” tungsten(0)–carbene complexes.

    8. Syntheses, Characterization and Catalytic Application of Palladacycles Containing Phosphane or Phosphane Oxide Functionalities (pages 2463–2470)

      Kuo-Fu Peng, Ming-Tsz Chen, Chi-An Huang and Chi-Tien Chen

      Article first published online: 11 APR 2008 | DOI: 10.1002/ejic.200800007

      Thumbnail image of graphical abstract

      Palladacycles containing phosphane or phosphane oxide functionalities have beenprepared and applied in catalyzing theSuzuki and Heck reactions.

    9. A General Process for the Fabrication of Air-Stable Metallic Particles (Cd, Zn and Al) by the Decomposition of Alkyl–Metal Compounds (pages 2471–2475)

      Aharon Gedanken and Eran Luvchik

      Article first published online: 1 APR 2008 | DOI: 10.1002/ejic.200701340

      Thumbnail image of graphical abstract

      Ait-stable metal–carbon core/shell structures are formed by thermal decomposition of alkyl–metal compounds.

    10. Synthesis of a Bulky Bis(carbene)borate Ligand – Contrasting Structures of Homoleptic Nickel(II) Bis(pyrazolyl)borate and Bis(carbene)borate Complexes (pages 2476–2480)

      Ismael Nieto, Ranko P. Bontchev and Jeremy M. Smith

      Article first published online: 17 APR 2008 | DOI: 10.1002/ejic.200800034

      Thumbnail image of graphical abstract

      Deprotonation of the “boronium” cation H2B(tBuImH)2+I provides access to the bulky bis(carbene)borate ligand H2B(tBuIm)2. Transfer of the ligand to NiIIyields a square-planar complex. Interestingly, the related bis(pyrazolyl)borate complex is octahedral. The strongly donating bis(carbene)borate ligand stabilizes the square-planar geometry despite unfavorable steric interactions.

  6. Correction

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    7. Correction
    1. You have free access to this content
      A Ferromagnetically Coupled Diiron(III) Complex with a m-Phenylenediamine-Based Ligand (page 2481)

      Biplab Biswas, Sunita Salunke-Gawali, Thomas Weyhermüller, Vinzenz Bachler, Eckhard Bill and Phalguni Chaudhuri

      Article first published online: 21 APR 2008 | DOI: 10.1002/ejic.200800362

      This article corrects:

      A Ferromagnetically Coupled Diiron(III) Complex with a m-Phenylenediamine-Based Ligand

      Vol. 2008, Issue 15, 2391–2395, Article first published online: 4 APR 2008

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