European Journal of Inorganic Chemistry

Cover image for Vol. 2009 Issue 1

January 2009

Volume 2009, Issue 1

Pages 3–173

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Editorials
    4. Graphical Abstract
    5. News
    6. Guidelines
    7. Microreview
    8. Short Communications
    9. Full Papers
    1. Oxidovanadium Complexes for the Consumption of Alkylating Toxins (Eur. J. Inorg. Chem. 1/2009) (page 3)

      Jessica M. Fautch, Phillip E. Fanwick and Jonathan J. Wilker

      Version of Record online: 18 DEC 2008 | DOI: 10.1002/ejic.200890106

  2. Editorials

    1. Top of page
    2. Cover Picture
    3. Editorials
    4. Graphical Abstract
    5. News
    6. Guidelines
    7. Microreview
    8. Short Communications
    9. Full Papers
    1. Trust pervades all (pages 4–6)

      Version of Record online: 18 DEC 2008 | DOI: 10.1002/ejic.200890107

    2. All from ChemPubSocEurope (page 7)

      Version of Record online: 18 DEC 2008 | DOI: 10.1002/ejic.200890108

  3. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Editorials
    4. Graphical Abstract
    5. News
    6. Guidelines
    7. Microreview
    8. Short Communications
    9. Full Papers
  4. News

    1. Top of page
    2. Cover Picture
    3. Editorials
    4. Graphical Abstract
    5. News
    6. Guidelines
    7. Microreview
    8. Short Communications
    9. Full Papers
  5. Guidelines

    1. Top of page
    2. Cover Picture
    3. Editorials
    4. Graphical Abstract
    5. News
    6. Guidelines
    7. Microreview
    8. Short Communications
    9. Full Papers
  6. Microreview

    1. Top of page
    2. Cover Picture
    3. Editorials
    4. Graphical Abstract
    5. News
    6. Guidelines
    7. Microreview
    8. Short Communications
    9. Full Papers
    1. Chemistry of Group 7 Aqua Ions

      The Chemistry of Technetium–Water Complexes within the Manganese Triad: Challenges and Perspectives (pages 21–31)

      Roger Alberto

      Version of Record online: 21 NOV 2008 | DOI: 10.1002/ejic.200800909

      Thumbnail image of graphical abstract

      Pure aqua complexes are frequent for the 3d but scarce for the 4d and 5d transition-element series. Since water can conveniently be substituted, aqua complexes facilitate biomedical applications. Thismicroreview discusses complexes of the manganese triad containing water ligands. A particular focus is placed on technetium and its organometallic aqua ion [99Tc(OH2)3(CO)3]+.

  7. Short Communications

    1. Top of page
    2. Cover Picture
    3. Editorials
    4. Graphical Abstract
    5. News
    6. Guidelines
    7. Microreview
    8. Short Communications
    9. Full Papers
    1. Carcinogen Detoxification

      Oxidovanadium Complexes for the Consumption of Alkylating Toxins (pages 33–37)

      Jessica M. Fautch, Phillip E. Fanwick and Jonathan J. Wilker

      Version of Record online: 14 NOV 2008 | DOI: 10.1002/ejic.200800949

      Thumbnail image of graphical abstract

      Oxidovanadium complexes are known to consume alkylating toxins and yield alcohols. These reactions may help in thedevelopment of second-generation cancer prevention compounds.

    2. Bismuth Thiolates

      Synthesis and Structure of an Unprecedented Linear Pentanuclear Bismuth(III) Zwitterionic Thiolate Complex (pages 38–41)

      Jin-Xiang Chen, Xiao-Yan Tang, Zhi-Gang Ren, Yong Zhang and Jian-Ping Lang

      Version of Record online: 25 NOV 2008 | DOI: 10.1002/ejic.200800969

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      A rare pentanuclear bismuth(III) zwitterionic thiolate complex, [Bi5(Tab)18](PF6)7(NO3)8·6MeCN [1; Tab = 4-(trimethylammonio)benzenethiolato], was obtained from the reaction of Bi(NO3)3 with TabHPF6 in a 1:4 molar ratio in MeCN/MeOH in the presence of Et3N.

  8. Full Papers

    1. Top of page
    2. Cover Picture
    3. Editorials
    4. Graphical Abstract
    5. News
    6. Guidelines
    7. Microreview
    8. Short Communications
    9. Full Papers
    1. Lithiosilanes

      Structural Studies on (–)-Sparteine-Coordinated Lithiosilanes (pages 43–52)

      Christian Däschlein and Carsten Strohmann

      Version of Record online: 18 NOV 2008 | DOI: 10.1002/ejic.200800792

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      On the basis of X-ray crystal structures of monomeric, (–)-sparteine-coordinated lithiosilanes, the influence of the steric demand of the substituents at silicon on their molecular structures was studied. NMR spectroscopic studies indicated equivalent structures in solution and in the solid state. DFT calculations provided very small energy differences between the diastereomers.

    2. Polypyridylruthenium Complexes

      (Polypyridyl)ruthenium(II) Complexes Based on a Back-to-Back Bis(pyrazolylpyridine) Bridging Ligand (pages 53–61)

      Frank Schramm, Rajadurai Chandrasekar, Thomas A. Zevaco, Manfred Rudolph, Helmar Görls, Wolfgang Poppitz and Mario Ruben

      Version of Record online: 28 NOV 2008 | DOI: 10.1002/ejic.200800628

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      Two ruthenium(II) complexes were synthesised by using a linear back-to-back bridging ligand based on a dipyrazolylpyridine coordination unit. The structural, electrochemical and spectroscopic properties show that this new bridging ligand can be considered as structural and electronic alternative to the widely used terpyridine-based bridging ligand systems.

    3. Azacyclophane Ligands

      Synthesis, Protonation and CuII Complexes of Two Novel Isomeric Pentaazacyclophane Ligands: Potentiometric, DFT, Kinetic and AMP Recognition Studies (pages 62–75)

      Andrés G. Algarra, Manuel G. Basallote, Raquel Belda, Salvador Blasco, C. Esther Castillo, José M. Llinares, Enrique García-España, Laura Gil, M. Ángeles Máñez, Conxa Soriano and Begoña Verdejo

      Version of Record online: 28 NOV 2008 | DOI: 10.1002/ejic.200800576

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      Two new cyclophanes differing only in the aromatic ring substitution have been prepared. Potentiometric measurements suggest the m-substituted ligand is tetradentate in the CuL2+ complex whereas the p-cyclophane is tridentate. DFT calculations suggest this change in the coordination mode is not principally related to first coordination sphere effects but to changes in the hydrogen bond network.

    4. (Amido)(COT)lanthanide Complexes

      Rare-Earth Metal Bis(dimethylsilyl)amide Complexes Supported by Cyclooctatetraenyl Ligands (pages 76–85)

      Christian Meermann, Kouji Ohno, Karl W. Törnroos, Kazushi Mashima and Reiner Anwander

      Version of Record online: 13 NOV 2008 | DOI: 10.1002/ejic.200800649

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      Reaction of (COT)LnI(thf)3 with Li[N(SiHMe2)2] yields (COT)dilanthanide sandwich complexes featuring distinct heterobridged core moieties Ln(μ-I)n[μ-N(SiHMe2)2]mLn (Ln = La: n = 1, m = 2; Ln = Nd, Sm: n = 2, m = 1). Utilization of K[N(SiHMe2)2] affords a (COT)monolanthanide silylamide complex.

    5. Iron Nanospheres

      From Molecular to Nanostructured Iron Complexes of Amphiphilic Chelators Based on 8-Hydroxyquinoline Subunits – Evidence of Self-Assembled Edifices Mimicking Siderophores from Marine Bacteria (pages 86–92)

      Jérémy Brandel, Stéphane Torelli, Gisèle Gellon, Guy Serratrice, Jean-Luc Putaux and Jean-Louis Pierre

      Version of Record online: 14 NOV 2008 | DOI: 10.1002/ejic.200800741

      Thumbnail image of graphical abstract

      Iron-containing nanospheres were obtained from self-assembly of an amphiphilic siderophore derived from 8-hydroxyquinoline. Cryogenic transmission electronmicroscopy images revealed evolution from micelles to flecked spherical structures with time.

    6. Aluminum Hydrazides

      Reactions of Hydrazines with AlH3·NMe2Et – Formation of Aluminum-Nitrogen Heterocycles (pages 93–97)

      Werner Uhl and Andreas Vogelpohl

      Version of Record online: 21 NOV 2008 | DOI: 10.1002/ejic.200800883

      Thumbnail image of graphical abstract

      Heterocyclic or cage-like compounds are formed by the double deprotonation of the hydrazine derivatives H5C6–(H)N–N(H)–C6H5 and H2N–NC4H4 with AlH3·NMe2Et. 1-Aminopyrrole gave a novel structural motif, in which five Al–H fragments are bridged by five dianionic hydrazinediido ligands.

    7. Hindered CO Addition

      Computational Results Provide a Synthetically Unprecedented Explanation for the β-Regioselectivity in the Rh-Catalyzed Hydroformylation of Vinylidenic Substrates (pages 98–103)

      Caterina Ghio, Raffaello Lazzaroni and Giuliano Alagona

      Version of Record online: 28 NOV 2008 | DOI: 10.1002/ejic.200800684

      Thumbnail image of graphical abstract

      In the hydroformylation of 1,1-diphenylethene, a high activation barrier was found for the branched alkyl-Rh(CO)3 intermediate, but not for the linear intermediate. The path leading to the branched aldehyde is thus abandoned early. CO addition, instead of CO migratory insertion or H2 oxidative addition and aldehyde reductive elimination, was found to be the critical step.

    8. Boron Dyes

      Molecular Motion and Performance Enhancement of BORAZAN Fluorescent Dyes (pages 104–110)

      Tyler J. Morin, Sergey V. Lindeman and James R. Gardinier

      Version of Record online: 25 NOV 2008 | DOI: 10.1002/ejic.200800806

      Thumbnail image of graphical abstract

      Diphenylboryl complexes of 2,6-bis(pyrazolyl)anilines are more robust and more highly-emissive colour-tuneable fluorophores than derivatives with only one pyrazolyl bound to the aniline ring. Evident from VT-NMR studies, the origin of these favourable characteristics is likely kinetic via promotion of chelate ring formation should dissociation occur.

    9. Molecular Wires

      Synthesis and Structural and Physicochemical Characterization of {[Rh2(μ-OOCCH3)2(dmbpy)2][BF4]}n Molecular Wire (pages 111–118)

      Magdalena Rak, Florian P. Pruchnik, Leszek Z. Ciunik, Frédéric Lafolet, Sylvie Chardon-Noblat and Alain Deronzier

      Version of Record online: 27 NOV 2008 | DOI: 10.1002/ejic.200800822

      Thumbnail image of graphical abstract

      The rhodium(II) complexes [Rh2(μ-OOCCH3)2(Me2bpy)2(H2O)2]2+ were chemically and electrochemically reduced to the Rh1.5+ wire {[Rh2(μ-OOCCH3)2 (Me2bpy)2]+}n(BF4)n with infinite Rh–Rhbonds. The molecular wire shows strong antiferromagnetic properties. Redox properties of the wires prepared chemically and electrochemically are similar.

    10. Relaxivity of LnIII-DOTPR Complexes

      Lanthanide(III) Complexes of Phosphorus Acid Analogues of H4DOTA as Model Compounds for the Evaluation of the Second-Sphere Hydration (pages 119–136)

      Zuzana Kotková, Giovannia A. Pereira, Kristina Djanashvili, Jan Kotek, Jakub Rudovský, Petr Hermann, Luce Vander Elst, Robert N. Muller, Carlos F. G. C. Geraldes, Ivan Lukeš and Joop A. Peters

      Version of Record online: 7 NOV 2008 | DOI: 10.1002/ejic.200800859

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      The set of DOTA-like complexes lacking a directly coordinated water molecule is studied to explore the relationship between the second hydration sphere and MRI-relevant parameters, and the influence of the ligand pendant arms (size, hydrophilicity) on the complex properties is discussed.

    11. Gold Chemistry

      Bis(1,2,3-thiadiazole)s as Precursors in the Synthesis of Bis(alkynethiolate)gold(I) Derivatives (pages 137–146)

      Elena Cerrada, Mariano Laguna and Nora Lardíes

      Version of Record online: 28 NOV 2008 | DOI: 10.1002/ejic.200800861

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      The cleavage of bis(1,2,3-thiadiazole)s provides a new family of bis(alkynethiolate)gold(I) derivatives [Au2(S–C≡C–spacer–C≡C–S)L2] (L = PR3 or C6F5). X-ray studies confirm the dinuclear structure for (PPN)2[Au2(S–C≡C–C≡C–S)(C6F5)2] and [Au2{3,5-(S–C≡C)2–C7H7N}(PPh3)2] {PPN = bis(triphenylphosphane)iminium}.

    12. Metal–Organic Frameworks

      Topological Diversification in Metal-Organic Frameworks: Secondary Ligand and Metal Effects (pages 147–154)

      Jian-Qiang Liu, Yao-Yu Wang, Ya-Nan Zhang, Ping Liu, Qi-Zhen Shi and Stuart R. Batten

      Version of Record online: 27 NOV 2008 | DOI: 10.1002/ejic.200800898

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      A series of interesting coordination polymers with V-shaped 4,4′-oxybis(benzoic acid) have been prepared. The crystal structures and topological analysis of these compounds, along with a systematic investigation of the effect of metal ions and neutral ligands on their ultimate frameworks, will be discussed.

    13. Lanthanide(III) Complexes

      The Role of Functionalisation, Asymmetry and Shape of a New Macrocyclic Compartmental Ligand in the Formation of Mononuclear, Homo- and Heterodinuclear Lanthanide(III) Complexes (pages 155–167)

      Sergio Tamburini, Sergio Sitran, Valentina Peruzzo and Pietro Alessandro Vigato

      Version of Record online: 28 NOV 2008 | DOI: 10.1002/ejic.200800394

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      A [1+1] asymmetric compartmental macrocycle, bearing a –CH2C6H4OH pendant arm, and related mononuclear, Ln2 homodinuclear and LnLn′ heterodinuclear complexes are reported. Their properties in thesolid-state and in different coordinating solvents have been investigated. The final decomposition at 1200 °C of the heterodinuclear complexes gives pure LnLn′O3 oxides.

    14. Hierarchical Architectures

      Hydrothermal Synthesis of Three-Dimensional Hierarchical CuO Butterfly-Like Architectures (pages 168–173)

      Yajing Zhang, Siu Wing Or, Xiaolei Wang, Tieyu Cui, Weibin Cui, Ying Zhang and Zhidong Zhang

      Version of Record online: 25 NOV 2008 | DOI: 10.1002/ejic.200800911

      Thumbnail image of graphical abstract

      Hierarchical butterfly-like CuO architectures composed of oriented attached rhombic nanoplatelets were synthesized by a simple hydrothermal method. The mechanism for the formation of the CuO hierarchical architectures is proposed.

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