European Journal of Inorganic Chemistry

Cover image for Vol. 2009 Issue 11

April 2009

Volume 2009, Issue 11

Pages 1423–1535

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    8. Correction
    1. Noble Reactions for the Actinides: Safe Gold-Based Access to Organouranium and Azido Complexes (Eur. J. Inorg. Chem. 11/2009) (page 1423)

      Robert K. Thomson, Christopher R. Graves, Brian L. Scott and Jaqueline L. Kiplinger

      Article first published online: 30 MAR 2009 | DOI: 10.1002/ejic.200990024

  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    8. Correction
  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    8. Correction
  4. Microreview

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    8. Correction
    1. Polyhedral Boranes in Medicine

      Polyhedral Boranes for Medical Applications: Current Status and Perspectives (pages 1433–1450)

      Igor B. Sivaev and Vladimir V. Bregadze

      Article first published online: 12 MAR 2009 | DOI: 10.1002/ejic.200900003

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      The current status and perspectives of the use of polyhedral boron hydrides in medicine are discussed. The topics included in this microreview are boron neutron capture therapy, radionuclide diagnostics and therapy, X-ray contrast diagnostics, and drug design.

  5. Short Communications

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    8. Correction
    1. Actinide Oxidative Functionalization

      Noble Reactions for the Actinides: Safe Gold-Based Access to Organouranium and Azido Complexes (pages 1451–1455)

      Robert K. Thomson, Christopher R. Graves, Brian L. Scott and Jaqueline L. Kiplinger

      Article first published online: 19 FEB 2009 | DOI: 10.1002/ejic.200900034

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      Uranium Goes for the Gold! A new safe gold-based protocol has been developed for the oxidative functionalization of uranium with azide and carbon anions. These reactions proceed rapidly in high yields, and represent a new class of reaction for gold.

    2. Metallacycles

      Synthesis of Hafnacyclopentanes from Hafnocene Alkyne Complexes: Influence of Styrene Substituents on the C–C Coupling Regioselectivity (pages 1456–1459)

      Torsten Beweries, Vladimir V. Burlakov, Perdita Arndt, Wolfgang Baumann, Anke Spannenberg and Uwe Rosenthal

      Article first published online: 12 MAR 2009 | DOI: 10.1002/ejic.200900117

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      The hafnocene alkyne complex rac-(ebthi)Hf(η2-Me3SiC2SiMe3) reacts with styrene and p-(trifluoromethyl)styrene, respectively, to give aryl-substituted hafnacyclopentanes. The coupling regioselectivity is influenced by the styrene substituents.

    3. Ferromagnetic Polyoxometalates

      An Unexpected Ferromagnetic Coupling in a Dinuclear Manganese(II) Linked Trivacant Heteropolymolybdate Derivative (pages 1460–1463)

      Yanyan Yang, Lin Xu, Guanggang Gao, Fengyan Li, Xizheng Liu and Weihua Guo

      Article first published online: 6 MAR 2009 | DOI: 10.1002/ejic.200801133

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      An unexpected ferromagnetically coupled dinuclear manganese(II) linked trivacant heteropolymolybdate [HN(CH3)3]10[Mn2(VVMo9O33)2]·10H2O has been synthesized in aqueous solution and characterized by elemental analysis, IR spectroscopy, thermal gravimetric analysis, and single-crystal X-ray diffraction.

    4. Sn-Rich Ge/Sn Alloys

      Laser CVD of Nanodisperse Ge–Sn Alloys Obtained by Dielectric Breakdown of SnH4/GeH4 Mixtures (pages 1464–1467)

      Tomáš Křenek, Petr Bezdička, Nataliya Murafa, Jan Šubrt and Josef Pola

      Article first published online: 12 MAR 2009 | DOI: 10.1002/ejic.200801172

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      Upon IR laser irradiation of a gaseous equimolar mixture of GeH4/SnH4 in Ar, nanoparticles of Sn-rich Ge/Sn alloys with different contents of Sn incorporated into the Ge lattice were deposited by chemical vapour deposition. These nanoparticles underwent changes in composition at temperatures as low as 200 °C.

  6. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    8. Correction
    1. Stannole Chemistry

      Reactions of 3-(Diethylboryl)stannoles with Isocyanates (pages 1469–1476)

      Bernd Wrackmeyer, Peter Thoma and Rhett Kempe

      Article first published online: 12 MAR 2009 | DOI: 10.1002/ejic.200900061

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      Treatment of 3-(diethylboryl)stannoles with isocyanates leads diastereoselectively to novel bicyclic compounds containing an aminoborane unit. These compounds react with methanol through rearrangement and elimination of ethyl(dimethoxy)borane to give novel 1-stannacyclopent-3-ene derivatives.

    2. Perovskite-Type Ceramics

      Preparation, Stability and Thermodynamic Properties of Nd- and Lu-Doped BaCeO3 Proton-Conducting Ceramics (pages 1477–1482)

      Nata I. Matskevich, Thomas Wolf, Mariya Yu. Matskevich and Tatiana I. Chupakhina

      Article first published online: 10 MAR 2009 | DOI: 10.1002/ejic.200800589

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      BaCe0.8Lu0.2O2.9 was prepared by a solid-state reaction for the first time. The standard formation enthalpies of BaCe0.8Lu0.2O2.9 and BaCe0.8Nd0.2O2.9 were determined by solution calorimetry. It was found that BaCe0.8RE0.2O2.9 (RE = Lu, Nd) reacted with water, Al2O3 and ZrO2 at ambient temperature.

    3. Metallaboranes

      An Efficient Route to Group 6 and 8 Metallaborane Compounds: Synthesis of arachno-[Cp*Fe(CO)B3H8] and closo-[(Cp*M)2B5H9] (M = Mo, W) (pages 1483–1487)

      K. Geetharani, Shubhankar Kumar Bose, Goutam Pramanik, Tanmoy Kumar Saha, V. Ramkumar and Sundargopal Ghosh

      Article first published online: 12 MAR 2009 | DOI: 10.1002/ejic.200801137

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      Reaction of [Cp*Fe(CO)2I] with BH3·thf or LiBH4 leads to the isolation of hydrogen-rich ferraborane arachno-[Cp*Fe(CO)B3H8], and in a similar fashion, reaction of [(Cp*M)(CO)3Cl] (M = Mo and W) withBH3·thf or LiBH4 yielded metallaboranes [(Cp*M)2B5H9] (M = Mo, W). Isolatedyields of both arachno-[Cp*Fe(CO)B3H8] and closo-[(Cp*M)2B5H9] are good.

    4. Mixed-Ligand Copper(II) Complexes

      Structural Evidence for an Unusual Conformation and Weak Interligand Interactions in Two Copper Chelates with (o-Nitrophenyl)ethylenediaminediacetic Acid (pages 1488–1494)

      Mustapha Allali, Joël Jaud, Nouzha Habbadi, Michèle Dartiguenave, André L. Beauchamp and Eric Benoist

      Article first published online: 12 MAR 2009 | DOI: 10.1002/ejic.200801201

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      Two mixed-ligand copper(II) complexes bearing a flexible coordinating arm have been synthesised and fully characterised, and the impact of this arm on the structural features of these complexes has been evaluated. Both compounds display unusual inter- and/or intramolecular π-π stacking interactions.

    5. Metal–Radical Exchange Interactions

      Nitronyl Nitroxide Radicals Linked to Exchange-Coupled Metal Dimers – Studies Using X-ray Crystallography, Magnetic Susceptibility Measurements, EPR Spectroscopy, and DFT Calculations (pages 1495–1502)

      Martin Jung, Ajay Sharma, Dariush Hinderberger, Sebastian Braun, Ulrich Schatzschneider and Eva Rentschler

      Article first published online: 9 MAR 2009 | DOI: 10.1002/ejic.200801248

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      To study long-range magnetic interactions, three new homodimetallic complexes with MnII, CoII, and ZnII bridged by a nitronyl nitroxide (NIT) substituted benzoate ligand have been prepared and studied by X-ray crystallography, magnetic susceptibility measurements, EPR spectroscopy, and density functional theory calculations.

    6. Fluorescent Boron Compounds

      Systematic Electronic Control in Ambipolar Compounds Optimizes Their Photoluminescence Properties: Synthesis, Characterization, and Device Fabrication of Four-Coordinate Boron Compounds Containing an N,O-Chelating Oxazolylphenolate Ligand (pages 1503–1513)

      Ho-Jin Son, Won-Sik Han, Kyung-Ryang Wee, Ji-Yun Chun, Kyu-Bum Choi, Su Jung Han, Soon-Nam Kwon, Jaejung Ko, Chongmok Lee and Sang Ook Kang

      Article first published online: 12 MAR 2009 | DOI: 10.1002/ejic.200900017

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      A series of electron-push and -pull aryl-substituted oxazolylphenolate ligands is synthesized and used to prepare boron compounds. The photophysical properties of these boron compounds are evaluated,and the corresponding EL properties studied through device fabrication by using them as emitting materials in a multilayer device.

    7. Olefin Isomerisation Catalysts

      Insight into cis-to-trans Olefin Isomerisation Catalysed by Group 4 and 6 Cyclopentadienyl Compounds (pages 1514–1520)

      Ghaita Chahboun, Cristina E. Petrisor, Enrique Gómez-Bengoa, Eva Royo and Tomás Cuenca

      Article first published online: 12 MAR 2009 | DOI: 10.1002/ejic.200900069

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      A DFT computational study of the intramolecular isomerisation reaction of theallyldimethylsilylcyclopentadienyl molybdenum hydride model provides evidence for the cis to trans conversion mechanism.

    8. DNA Photocleavage

      Highly Efficient Visible-Light-Induced Photocleavage of DNA by a Ruthenium-Substituted Fluorinated Porphyrin (pages 1521–1525)

      Michelle Cunningham, Anna McCrate, Mark Nielsen and Shawn Swavey

      Article first published online: 12 MAR 2009 | DOI: 10.1002/ejic.200900080

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      A new porphyrin and its diruthenium analog have been synthesized. Photolysis of aqueous solutions of circular DNA in thepresence of the ruthenium–porphyrin indicates cleavage of the DNA.

    9. Molecular Materials

      Organoplatinum(IV) Complexes with Amide Groups: Supramolecular Structure as a Function of Ligand Flexibility (pages 1526–1534)

      Richard H. W. Au, Michael C. Jennings and Richard J. Puddephatt

      Article first published online: 12 MAR 2009 | DOI: 10.1002/ejic.200900030

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      Organoplatinum(IV) complexes containing an amide unit incorporated into an alkyl group have been prepared. The amide group takes part in hydrogen bonding to yield supramolecular polymer or dimer structures, depending on the length and flexibility of the alkyl ligand.

  7. Correction

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    8. Correction
    1. You have free access to this content
      Linear Multinuclear RuII Photosensitizers (page 1535)

      Simona Vaduvescu and Pierre G. Potvin

      Article first published online: 6 MAR 2009 | DOI: 10.1002/ejic.200900174

      This article corrects:

      Linear Multinuclear RuII Photosensitizers

      Vol. 2004, Issue 8, 1763–1769, Article first published online: 5 MAR 2004

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