European Journal of Inorganic Chemistry

Cover image for Vol. 2009 Issue 18

June 2009

Volume 2009, Issue 18

Pages 2570–2725

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Graphical Abstract
    5. News
    6. Microreview
    7. Short Communication
    8. Full Papers
  2. Editorial

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Graphical Abstract
    5. News
    6. Microreview
    7. Short Communication
    8. Full Papers
    1. The Italian Chemical Society Is 100 Years Old (Eur. J. Org. Chem. 18/2009) (pages 2567–2569)

      Cesare Gennari and Maurizio Peruzzini

      Version of Record online: 5 JUN 2009 | DOI: 10.1002/ejic.200990047

  3. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Graphical Abstract
    5. News
    6. Microreview
    7. Short Communication
    8. Full Papers
  4. News

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Graphical Abstract
    5. News
    6. Microreview
    7. Short Communication
    8. Full Papers
  5. Microreview

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Graphical Abstract
    5. News
    6. Microreview
    7. Short Communication
    8. Full Papers
    1. Solid-State NMR

      Solid-State NMR Investigation of Ligand Mobility and Reactivity in Transition Metal Complexes (pages 2581–2597)

      Michele R. Chierotti and Roberto Gobetto

      Version of Record online: 22 APR 2009 | DOI: 10.1002/ejic.200801205

      Thumbnail image of graphical abstract

      The key question of the influence of the mobility on the solid-state reactivity is the occasion for presenting several selected examples of dynamics and reactivity of transition metal complexes as seen by advanced solid-state NMR techniques.

  6. Short Communication

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Graphical Abstract
    5. News
    6. Microreview
    7. Short Communication
    8. Full Papers
    1. Chiral Metal–Organic Frameworks

      A Chiral Metal–Organic Framework Based on Heptanuclear Zinc Cores (pages 2599–2602)

      Hai-Yang Liu, Bin Zhao, Wei Shi, Zhen-Jie Zhang, Peng Cheng, Dai-Zheng Liao and Shi-Ping Yan

      Version of Record online: 13 MAY 2009 | DOI: 10.1002/ejic.200900185

      Thumbnail image of graphical abstract

      By introducing an additional chiral site into the original ligand (H3L1), we achieved the transformation of a MOFfrom a nonchiral to a chiral structure, which provides a new strategy for designing chiral compounds.

  7. Full Papers

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Graphical Abstract
    5. News
    6. Microreview
    7. Short Communication
    8. Full Papers
    1. Hydrotalcite-Like Nanoparticles

      Hydrotalcite-Like Nanocrystals from Water-in-Oil Microemulsions (pages 2603–2611)

      Francesca Bellezza, Antonio Cipiciani, Umberto Costantino, Morena Nocchetti and Tamara Posati

      Version of Record online: 30 APR 2009 | DOI: 10.1002/ejic.200801114

      Thumbnail image of graphical abstract

      MgAl, NiAl and ZnAl hydrotalcite-like compounds (HTlcs) were prepared as colloidal dispersions of nanoparticles using water-in-oil microemulsions. Nanoparticle sizes and shapes were examined by transmission electron microscopy and atomicforce microscopy. HTlc nanocrystals recovered from the reaction medium were characterized with chemical and thermogravimetric analyses, X-ray powder diffraction, BET surface analysis and porosity and scanning electron microscopy.

    2. Copper(II)–Dipeptide Systems

      The Contribution of Electrospray Mass Spectrometry to the Study of Metal Complexes: The Case of Copper(II)–Dipeptide Systems (pages 2612–2620)

      Giuseppe Maccarrone, Rosario Caruso, Annalinda Contino, Alessandro Giuffrida, Marianna Messina and Vincenzo Cucinotta

      Version of Record online: 30 APR 2009 | DOI: 10.1002/ejic.200900086

      Thumbnail image of graphical abstract

      By investigating the copper(II) complexes of a series of dipeptides it was ascertained that the in-plane coordinated water molecule was not removed in ESI-MS experiments.

    3. Metallosupramolecular Chemistry

      Modulation of Photochemical Properties in Ion-Controlled Multicomponent Dynamic Devices (pages 2621–2628)

      Mihail Barboiu, Yves-Marie Legrand, Luca Prodi, Marco Montalti, Nelsi Zaccheroni, Gavin Vaughan, Arie van der Lee, Eddy Petit and Jean-Marie Lehn

      Version of Record online: 7 MAY 2009 | DOI: 10.1002/ejic.200900089

      Thumbnail image of graphical abstract

      The pyrene-terpyridine-pyrene-based receptor 1 converts from a W to a U shape upon ion-metal cation complexation. The U form of 1 is capable of substrate binding through insertion between the lateral donor-pyrene arms of acceptor-terpyridine-type systems, with the participation of the metal ions, simultaneously coordinating the binding units of such multicomponent dynamic devices.

    4. Mixed-Valent Co Complexes

      Crystal Structures and Solution Behavior of Paramagnetic, Trinuclear, Mixed-Valent Cobalt Complexes with Salen-Type Ligands (pages 2629–2638)

      Lassaad Mechi, Patrizia Siega, Renata Dreos, Ennio Zangrando and Lucio Randaccio

      Version of Record online: 7 MAY 2009 | DOI: 10.1002/ejic.200900122

      Thumbnail image of graphical abstract

      Three new trinuclear mixed-valent cobalt complexes, which show different configurations (cis or trans) in the solid state, have been synthesized and fully characterized.The isotropically shifted 1H NMR spectra show that both the cis and trans isomers are present in solution, with interconversion being slow on the NMR time-scale.

    5. Luminescent Dendrimers

      Long-Lived Luminescent Dendrimers with a [Ru(dpp)3]2+-Type Core: Synthesis and Photophysical Properties (pages 2639–2646)

      Uwe Hahn, Fritz Vögtle, Gabriele De Paoli, Mara Staffilani and Luisa De Cola

      Version of Record online: 11 MAY 2009 | DOI: 10.1002/ejic.200900253

      Thumbnail image of graphical abstract

      Four metallodendrimers with a photoactive luminescent [Ru(dpp)3]2+-type core were prepared. The photophysical characterisation revealed a dendritic effect on the excited-state lifetimes, which were found to increase with growing size of the surrounding dendritic shell.

    6. Multitopological Ligands

      Metalloligands: Rhodium(III) Cyclometallated Compounds Containing Multitopological Binucleating Ligands (pages 2647–2654)

      Santo Lanza, Antonino Giannetto, Giuseppe Bruno, Franco Nicolò and Giuseppe Tresoldi

      Version of Record online: 15 MAY 2009 | DOI: 10.1002/ejic.200900165

      Thumbnail image of graphical abstract

      The metalloligand [Rh(2-phenylpyridine)2{H(isoamyl)2C2N2S2 κ-S,S-Rh}] changes the coordination mode of the binucleatingdithiooxamide when linked to a soft metal fragment MLn [MLn = Rh(cod), Pd(η3-allyl), PdCl(n-propylphosphane)].

    7. Ligand Radicals

      Polynuclear Complexes Containing the Redox Noninnocent Schiff Base Ligand 2-[(E)-2-Mercaptophenylimino]methyl-4,6-di-tert-butylphenolate(2–) (pages 2655–2663)

      Nabarun Roy, Stephen Sproules, Eberhard Bothe, Thomas Weyhermüller and Karl Wieghardt

      Version of Record online: 11 MAY 2009 | DOI: 10.1002/ejic.200900168

      Thumbnail image of graphical abstract

      Polynuclear complexes of Cu, Pd, Pt, and Co were prepared by using a N,O,S-donor Schiff base ligand, 2-[(E)-2-mercaptophenylimino]methyl-4,6-di-tert-butylphenolate.The tetrameric Co and Pd complexes show multiple reversible redox processes. The oxidation was found to be ligand-based, leading to compounds with coordinated phenoxyl radical ligands.

    8. Organostannoxanes

      Synthesis, Structures, and Photophysical Properties of Two Organostannoxanes from a Novel Acrylic Acid Derived from Phenothiazine (pages 2664–2672)

      Dongmei Li, Rentao Hu, Wen Zhou, Pingping Sun, Yuhe Kan, Yupeng Tian, Hongping Zhou, Jieying Wu, Xutang Tao and Minhua Jiang

      Version of Record online: 13 MAY 2009 | DOI: 10.1002/ejic.200900216

      Thumbnail image of graphical abstract

      (E)-3-(10-ethylphenothiazine-3-yl)acrylicacid (LCOOH) and two organostannoxanes have been synthesized and fully characterized. Their structures were solvedby single-crystal X-ray diffraction determination. The two-photon absorption properties of the compounds are much more enhanced than that of LCOOH.

    9. Sandwich Complexes

      Organometallic Osmium(II) and Ruthenium(II) Biphenyl Sandwich Complexes: X-ray Crystal Structures and 187Os NMR Spectroscopic Studies in Solution (pages 2673–2677)

      Jennifer C. Gray, Alain Pagelot, Anna Collins, Francesca P. A. Fabbiani, Simon Parsons and Peter J. Sadler

      Version of Record online: 13 MAY 2009 | DOI: 10.1002/ejic.200900244

      Thumbnail image of graphical abstract

      The osmium biphenyl sandwich complex has both staggered and eclipsed configurations in its X-ray crystal structure, in contrast to the ruthenium complex. The use of inverse heteronuclear multiple bond correlation spectroscopy allows facile observation of the 187Os resonance despite the extreme insensitivity of 187Os to NMR spectroscopic detection by normalmethods.

    10. NPO-Zeolite Nitridosilicate

      Ba6Si6N10O2(CN2) – A Nitridosilicate with a NPO-Zeolite Structure Type Containing Carbodiimide Ions (pages 2678–2683)

      Sandro Pagano, Oliver Oeckler, Thorsten Schröder and Wolfgang Schnick

      Version of Record online: 7 MAY 2009 | DOI: 10.1002/ejic.200900157

      Thumbnail image of graphical abstract

      A new precursor approach employing amorphous “Si(CN2)2” led to the NPO-zeolite analogous nitridosilicate Ba6Si6N10O2(CN2) with channels containing carbodiimide ions. The latter is the first nitridosilicate incorporating carbodiimide ions and the partially ordered integration leads to the formation of a superstructure.

    11. Supramolecular Interactions

      An Electron-Poor Host Receptor for Electron-Rich Guests Involving Anion–π and Lone-Pair–π Interactions (pages 2684–2690)

      Paul de Hoog, Arturo Robertazzi, Ilpo Mutikainen, Urho Turpeinen, Patrick Gamez and Jan Reedijk

      Version of Record online: 11 MAY 2009 | DOI: 10.1002/ejic.200900183

      Thumbnail image of graphical abstract

      An electron-deficient cavity formed by four coordinated pyridine rings is capable of hosting a chloride anion or a water molecule.

    12. N,O-Chelating Ligands

      N,O-Chelates of Group 4 Metals: Contrasting the Use of Amidates and Ureates in the Synthesis of Metal Dichlorides (pages 2691–2701)

      David C. Leitch, J. David Beard, Robert K. Thomson, Vincent A. Wright, Brian O. Patrick and Laurel L. Schafer

      Version of Record online: 13 MAY 2009 | DOI: 10.1002/ejic.200900254

      Thumbnail image of graphical abstract

      Group 4 dichloride complexes with amidate or ureate ancillary ligands, while potentially useful as starting materials or precatalysts, have been largely been overlooked in the literature. Here, several examples ofthese compounds have been prepared. A modified salt metathesis procedure is used to synthesize amidate dichlorides, while protonolysis is effective with electron-rich ureate ligands.

    13. Ruthenium Nitrosyl Complexes

      Stabilization of {RuNO}6 and {RuNO}7 States in [RuII(trpy)(bik)(NO)]n+ {trpy = 2,2′:6′,2″-terpyridine, bik = 2,2′-bis(1-methylimidazolyl) ketone} – Formation, Reactivity, and Photorelease of Metal-Bound Nitrosyl (pages 2702–2710)

      Prinaka De, Biprajit Sarkar, Somnath Maji, Atanu Kumar Das, Ece Bulak, Shaikh M. Mobin, Wolfgang Kaim and Goutam Kumar Lahiri

      Version of Record online: 13 MAY 2009 | DOI: 10.1002/ejic.200900021

      Thumbnail image of graphical abstract

      The co-ligands trpy and bik in [(bik)(trpy)RuII(NO)]n+ [4]n+ facilitate the stabilization of both NO+ and NO· redox states and primarily “NO”-based electron-transfer has been reflected by a 300 cm–1 lower shift in ν(NO) frequency on reduction of [4]3+ to [4]2+ while the ν(C=O) of bik remains unaltered. The photocleavage of the Ru–NO+ bond is much faster than that of the Ru–NO· bond.

    14. Calixarene Probe for Anion

      Synthesis, Structures, and Excited-State Geometries of Alkynylgold(I) Complexes (pages 2711–2719)

      Lei Gao, David V. Partyka, James B. Updegraff III, Nihal Deligonul and Thomas G. Gray

      Version of Record online: 5 MAY 2009 | DOI: 10.1002/ejic.200900307

      Thumbnail image of graphical abstract

      A series of new alkynylgold(I) complexes has been synthesized; the luminescence of (arylalkynyl)gold complexes is characterized. The structures of ligand-centeredand metal-centered triplet excited states have been optimized within the density-functional theory.

    15. Copper Complexes

      Synthesis, Structure, Conductivity, and Calculated Nonlinear Optical Properties of Two Novel Bis(triphenylphosphane)copper(I) Dithiocarbamates (pages 2720–2725)

      Abhinav Kumar, Heike Mayer-Figge, William S. Sheldrick and Nanhai Singh

      Version of Record online: 7 MAY 2009 | DOI: 10.1002/ejic.200900013

      Thumbnail image of graphical abstract

      The facile synthesis, crystal structures of [{Cu(PPh3)2}2(piperzdtc)] (1) and [{Cu(PPh3)2}(BzMedtc)] (2), interpretation of the NLO property of asymmetrical 2 by DFT using the finite-field perturbation method and electronic absorptions by TD-DFT calculations and conducting properties of 1 and 2 are reported.

SEARCH

SEARCH BY CITATION