European Journal of Inorganic Chemistry

Cover image for Vol. 2009 Issue 21

July 2009

Volume 2009, Issue 21

Pages 3031–3187

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Cyclometallated [C,N,O] Complexes as Metalloligands: Synthesis and Structural Characterisation of New Di-, Tri-, Tetra- and Pentanuclear Heterometallic Complexes (Eur. J. Inorg. Chem. 21/2009) (page 3031)

      Nina Gómez-Blanco, Jesús J. Fernández, Alberto Fernández, Digna Vázquez-García, Margarita López-Torres and José M. Vila

      Article first published online: 10 JUL 2009 | DOI: 10.1002/ejic.200990057

  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
  4. Microreview

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Platinum Polymers

      Platinum Stacking Interactions in Homoleptic Platinum Polymers (pages 3041–3054)

      Bernard M. Anderson and Stephanie K. Hurst

      Article first published online: 22 JUN 2009 | DOI: 10.1002/ejic.200900225

      Thumbnail image of graphical abstract

      All Stacked Up: The ability of platinum complexes to form columnar structures arises from the overlap of dmath image orbitals. This microreview summarizes progress in the synthesis, characterization, and material properties of homoleptic platinum complexes with significant Pt–Pt overlap (≤ 3.5 Å), where the platinum metal overlap is the primary bonding interaction.

  5. Short Communications

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Ammonia Borane Activation

      Selective B–H versus N–H Bond Activation in Ammonia Borane by [Ir(dppm)2]OTf (pages 3055–3059)

      Andrea Rossin, Maria Caporali, Luca Gonsalvi, Annalisa Guerri, Agustí Lledós, Maurizio Peruzzini and Fabrizio Zanobini

      Article first published online: 22 JUN 2009 | DOI: 10.1002/ejic.200900465

      Thumbnail image of graphical abstract

      Reaction between ammonia borane (AB, NH3–BH3) and the highly reactive IrI species [Ir(dppm)2][OTf] led to the formation ofIrIII hydrides, as a consequence of a selective B–H versus N–H bond activation.

    2. Luminescent Clusters

      A Luminescent Heteronuclear Cluster Featuring an Unusual Cu6 Boat-Shaped Core Assembled by Two Dialkynyl-Cycloplatinated Units (pages 3060–3066)

      Álvaro Díez, Ana García, Elena Lalinde and M. Teresa Moreno

      Article first published online: 25 JUN 2009 | DOI: 10.1002/ejic.200900413

      Thumbnail image of graphical abstract

      An unusual luminescent octanuclear cluster [Pt2Cu6(bzq)2(C≡C–C5H4N-2)6I2] formed by a central dicationic hexanuclear copper core [Cu6(C≡C–C5H4N-2)2I2]2+ assembled by two monoanionic [Pt(bzq)(C≡C–C5H4N-2)2] fragments is described.

    3. Titanium Silicalite Hollow Structures

      Semi In Situ Synthesis of NHTS: A New Hollow Titanium Silicalite Modified by a Noble Metal (pages 3067–3070)

      Chunfeng Shi, Bin Zhu, Min Lin and Jun Long

      Article first published online: 25 JUN 2009 | DOI: 10.1002/ejic.200900321

      Thumbnail image of graphical abstract

      NHTS, a new hollow titanium silicalite with a noble metal incorporated into it, was synthesized by the addition of a noble metal to a mixture of tetraethyl orthosilicate and tetrabutylorthotitanate, with the formation of an intermediate, under basic conditions. The entire process is called a “semi in situ” synthesis. This NHTS has intraparticle voids and exhibits bifunctional catalytic performance.

  6. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Cyclopalladated Metalloligands

      Cyclometallated [C,N,O] Complexes as Metalloligands: Synthesis and Structural Characterisation of New Di-, Tri-, Tetra- and Pentanuclear Heterometallic Complexes (pages 3071–3083)

      Nina Gómez-Blanco, Jesús J. Fernández, Alberto Fernández, Digna Vázquez-García, Margarita López-Torres and José M. Vila

      Article first published online: 6 APR 2009 | DOI: 10.1002/ejic.200900052

      Thumbnail image of graphical abstract

      Palladium(II) compounds with terdentate [C,N,O] ligands bearing pyridine rings may behave as new metalloligands through their non-coordinated nitrogen atoms. The π–π slipped stacking interactions found in the solid state for these complexes suggest a certain degree of metalloaromaticity.

    2. Substituted Tetrathiafulvalenes

      Pyridine-Functionalised (Vinylenedithio)tetrathiafulvalene (VDT–TTF) Derivatives and Their Dithiolene Analogues (pages 3084–3093)

      Andrew C. Brooks, Peter Day, Sandra I. G. Dias, Sandra Rabaça, Isabel C. Santos, Rui T. Henriques, John D. Wallis and Manuel Almeida

      Article first published online: 17 JUN 2009 | DOI: 10.1002/ejic.200900278

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      A group of vinylenedithio–TTFs bearing two or four 2- or 4-pyridyl groups are described, along with related nickel and gold bidithiolene complexes, as potential substrates for preparing multifunctional materials.

    3. Nonanuclear Clusters

      Nonanuclear Coordination Compounds Featuring {M9L12}6+ Cores (M = NiII, CoII, or ZnII; L = 1,2,3-Benzotriazolate) (pages 3094–3101)

      Shyam Biswas, Markus Tonigold, Manfred Speldrich, Paul Kögerler and Dirk Volkmer

      Article first published online: 16 JUN 2009 | DOI: 10.1002/ejic.200900156

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      Three novel nonanuclear coordination compounds possessing {M9L12}6+ cores (M = NiII, CoII, or ZnII; L = 1,2,3-benzotriazolate) were successfully synthesized and their structures and magnetic properties studied.

    4. Phosphide Tellurides

      Chemistry and Physical Properties of the Phosphide Telluride Zr2PTe2 (pages 3102–3110)

      Kristina Tschulik, Michael Ruck, Michael Binnewies, Edgar Milke, Stefan Hoffmann, Walter Schnelle, Boniface P. T. Fokwa, Michael Gilleßen and Peer Schmidt

      Article first published online: 17 JUN 2009 | DOI: 10.1002/ejic.200900346

      Thumbnail image of graphical abstract

      The synthesis of Zr2PTe2 was accomplished by either a solid-state reaction from the elements or by a thermite-type reaction of Zr and Te8O10(PO4)4. Crystals were grown by chemical vapour transport by using iodine. The compound exhibits metallic behaviour and temperature-independent Pauli paramagnetism.

      Corrected by:

      Correction: Correction: Chemistry and Physical Properties of the Phosphide Telluride Zr2PTe2

      Vol. 2010, Issue 14, 2201, Article first published online: 13 APR 2010

    5. Copper Chelate Complexes

      A New Trigonal-Bipyramidal [CuII(pytBuN3)Cl2] Complex: Synthesis, Structure and Ligand Substitution Behaviour (pages 3111–3118)

      Shaban Y. Shaban, Frank W. Heinemann and Rudi van Eldik

      Article first published online: 17 JUN 2009 | DOI: 10.1002/ejic.200900302

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      A five-coordinate copper(II) complex containing a sterically constrained pytBuN3 chelate ligand was synthesized, characterized by X-ray diffraction and the ligand substitution behaviour was kinetically studied. The substitution reaction is a biphasic process that involves the subsequent displacement of both chloride ligands and follows an associative interchange (Ia) mechanism.

    6. Charge Transfer

      Resonance Raman Studies of Bis(terpyridine)ruthenium(II) Amino Acid Esters and Diesters (pages 3119–3126)

      Katja Heinze, Klaus Hempel, Stefanie Tschierlei, Michael Schmitt, Jürgen Popp and Sven Rau

      Article first published online: 5 JUN 2009 | DOI: 10.1002/ejic.200900309

      Thumbnail image of graphical abstract

      Resonance Raman (rR) spectroscopy in combination with DFT calculations was used to elucidate the nature of the 1metal-to-ligand charge-transfer states (1MLCT) of ester derivatives of homo- and heteroleptic bis(terpyridine)ruthenium(II) complexes.

    7. New LED Phosphors

      Crystal Structure, Vibrational Spectra and Activation of BaCa(P4O12) with Eu2+ Compared with β-Sr(PO3)2:Eu (pages 3127–3130)

      Henning A. Höppe and J. Michel U. Panzer

      Article first published online: 16 JUN 2009 | DOI: 10.1002/ejic.200900098

      Thumbnail image of graphical abstract

      The phosphors β-Sr(PO3)2:Eu and BaCa(PO3)4:Eu emit blue light and will be useful for the development of UV-LED based white LEDs. The refinement of the new crystal structure of BaCa(PO3)4:Eu (Ba yellow and Ca green) is presented.

    8. Metal-Organic Frameworks

      Simultaneous Gas-Phase Loading of MOF-5 with Two Metal Precursors: towards Bimetallics@MOF (pages 3131–3140)

      Felicitas Schröder, Sebastian Henke, Xiaoning Zhang and Roland A. Fischer

      Article first published online: 22 JUN 2009 | DOI: 10.1002/ejic.200900138

      Thumbnail image of graphical abstract

      Simultaneous gas-phase loading of the porous host matrix [Zn4O(bdc)3] (bdc = 1,4-benzenedicarboxylate, MOF-5) with two different MOCVD precursors was investigated. Control of the molar ratios of the adsorbed precursors was possible. Mixed-metal PtRu 3–4 nm nanoparticles were obtained by hydrogen treatment but the MOF matrix collapsed due to some hydrogenation of bdc linkers in case of PtRu@MOF.

    9. Spin Crossover in Fe(III) Complexes

      Unconventional Spin Crossover in Dinuclear and Trinuclear Iron(III) Complexes with Cyanido and Metallacyanido Bridges (pages 3141–3154)

      Ivan Šalitroš, Roman Boča, L'ubor Dlháň, Milan Gembický, Jozef Kožíšek, Jorge Linares, Ján Moncol', Ivan Nemec, Lucia Perašínová, Franz Renz, Ingrid Svoboda and Hartmut Fuess

      Article first published online: 17 JUN 2009 | DOI: 10.1002/ejic.200900169

      Thumbnail image of graphical abstract

      On the basis of magnetic data and Mössbauer spectra, spin crossover was identified in a number of dinuclear and trinuclear FeIII complexes. The energy bands formed of spin multiplets for the reference states LL and LH show an overlap, which results in spin crossover interference with the magnetic exchange interaction.

    10. Aluminum-Bridged Ferrocenophane

      1,1′-Disubstituted Ferrocenes with Aluminum: Dinuclear and Trinuclear Dialumina[1.1]ferrocenophanes as Pyridine Adducts (pages 3155–3162)

      Bernd Wrackmeyer, Elena V. Klimkina and Wolfgang Milius

      Article first published online: 27 MAY 2009 | DOI: 10.1002/ejic.200900272

      Thumbnail image of graphical abstract

      The dipyridine adducts of ferrocenesbearing dialkylaluminum substituents in the 1,1′-positions were transformed into dinuclear alkylaluminum-bridged [1.1]ferrocenophanes and finally into the trinuclear aluminum-bridged ferrocenophane.

    11. Aluminum-Bridged Ferrocenophanes

      Synthesis, Characterization and Reactivity of Dinuclear and Trinuclear Aluminum-Bridged Ferrocenophanes (pages 3163–3171)

      Bernd Wrackmeyer, Elena V. Klimkina and Wolfgang Milius

      Article first published online: 10 JUN 2009 | DOI: 10.1002/ejic.200900273

      Thumbnail image of graphical abstract

      The formation and dynamic behaviour of base-free dinuclear and trinuclear aluminum-bridged ferrocenophanes in solution were monitored by NMR spectroscopy, and the dinuclear complex (fc)2Al3Et5 was characterized by X-ray structural analysis.

    12. Anhydrous Ln Hexanuclear Complexes

      A New Series of Anhydrous Lanthanide-Based Octahedral Hexanuclear Complexes (pages 3172–3178)

      Guillaume Calvez, Carole Daiguebonne, Olivier Guillou and Florence Le Dret

      Article first published online: 8 JUN 2009 | DOI: 10.1002/ejic.200900283

      Thumbnail image of graphical abstract

      Lanthanide oxido/hydroxido complexes of the general formula [Ln6O(OH)8(NO3)6(H2O)x]2NO3·2H2O have been obtained and characterized. Their dehydration leads to isostructural anhydrous compounds with the general formula [Ln6O(OH)8(NO3)8]. These anhydrous compounds can be used as molecular precursors for further chemistry.

    13. Technetium and Rhenium Chemistry

      Mixed-Ligand Complexes of Technetium and Rhenium with Tridentate Benzamidines and Bidentate Benzoylthioureas (pages 3179–3187)

      Hung Huy Nguyen, Victor M. Deflon and Ulrich Abram

      Article first published online: 17 JUN 2009 | DOI: 10.1002/ejic.200900288

      Thumbnail image of graphical abstract

      Mixed-ligand complexes of technetium(V) or rhenium(V) containing tridentate N-[(dialkylamino)(thiocarbonyl)]benzamidine(H2L1) and bidentate N,N-dialkyl-N′-benzoylthiourea (HL2) ligands were formed in high yield when (NBu4)[MOCl4] (M = Tc or Re) or [ReOCl3(PPh3)2] was treated with mixtures of the proligands.

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