Unconventional Spin Crossover in Dinuclear and Trinuclear Iron(III) Complexes with Cyanido and Metallacyanido Bridges (pages 3141–3154)
Ivan Šalitroš, Roman Boča, L'ubor Dlháň, Milan Gembický, Jozef Kožíšek, Jorge Linares, Ján Moncol', Ivan Nemec, Lucia Perašínová, Franz Renz, Ingrid Svoboda and Hartmut Fuess
Article first published online: 17 JUN 2009 | DOI: 10.1002/ejic.200900169
On the basis of magnetic data and Mössbauer spectra, spin crossover was identified in a number of dinuclear and trinuclear FeIII complexes. The energy bands formed of spin multiplets for the reference states LL and LH show an overlap, which results in spin crossover interference with the magnetic exchange interaction.