European Journal of Inorganic Chemistry

Cover image for Vol. 2009 Issue 28

October 2009

Volume 2009, Issue 28

Pages 4175–4334

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. The Versatile Alkylidene Moiety in Ruthenium Olefin Metathesis Catalysts (Eur. J. Inorg. Chem. 28/2009) (page 4175)

      Charles E. Diesendruck, Eyal Tzur and N. Gabriel Lemcoff

      Version of Record online: 21 SEP 2009 | DOI: 10.1002/ejic.200990078

  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
  4. Microreview

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Olefin Metathesis

      The Versatile Alkylidene Moiety in Ruthenium Olefin Metathesis Catalysts (pages 4185–4203)

      Charles E. Diesendruck, Eyal Tzur and N. Gabriel Lemcoff

      Version of Record online: 28 AUG 2009 | DOI: 10.1002/ejic.200900526

      Thumbnail image of graphical abstract

      The alkylidene fragment has played a key role in ruthenium olefin metathesis. This microreview details the evolution of the active carbene fragment

  5. Short Communications

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Organoditin Compounds

      Synthesis, Structure and Electrochemical Properties of a Ferrocene-Bridged Bis[tris(arylselenolato)stannyl] Compound (pages 4205–4208)

      Hari Pada Nayek, Gerhard Hilt and Stefanie Dehnen

      Version of Record online: 25 AUG 2009 | DOI: 10.1002/ejic.200900664

      Thumbnail image of graphical abstract

      Reactions of (Cl3Sn)2Fc with R2Se2 [R = Ph (1; see figure), 1-Np (2)], yielded ferrocene-bridged bis[tris(arylselenolato)stannyl] compounds that were further investigated by means of DFT calculations and cyclic voltammetry. Compounds 1 and 2 are promising candidates for the synthesis of ternary chalcogenometallate organic hybrid compounds.

    2. Twisted Manganese Clusters

      Decanuclear Manganese Isobutyrate Clusters Featuring a Novel MnII8MnIII2 Core (pages 4209–4212)

      Iurii L. Malaestean, Manfred Speldrich, Arkady Ellern, Svetlana G. Baca, Michael Ward and Paul Kögerler

      Version of Record online: 21 AUG 2009 | DOI: 10.1002/ejic.200900602

      Thumbnail image of graphical abstract

      “Shrink-wrapping” isobutyrate ligands are the key to the formation of new decanuclear MnII8MnIII2 coordination clusters.

    3. Photoluminescent Nanotubes

      Photoluminescent Metal-Organic Nanotubes via Hydrothermal in Situ Ligand Reactions (pages 4213–4218)

      Wen-Ting Liu, Yong-Cong Ou, Yu-Ling Xie, Zhuojia Lin and Ming-Liang Tong

      Version of Record online: 28 AUG 2009 | DOI: 10.1002/ejic.200900555

      Thumbnail image of graphical abstract

      Three photoluminescent CdII coordination polymers with 1D metal-organic nanotube or 1D coordination chain structure were synthesized by hydrothermal reactions of CdCl2, oxalic acid, 1,3,5-benzenetricarboxylic acid and o-phenylene diamine, from which the benzimidazole derivative ligands were generated in situ via hydrothermal metal/ligand condensation of polycarboxylic acid with o-phenylenediamine.

    4. Copper Oxide Nanocubes as Catalyst

      Cu2O Nanocube-Catalyzed Cross-Coupling of Aryl Halides with Phenols via Ullmann Coupling (pages 4219–4223)

      Jee Young Kim, Ji Chan Park, Aram Kim, A. Young Kim, Hyun Ju Lee, Hyunjoon Song and Kang Hyun Park

      Version of Record online: 31 AUG 2009 | DOI: 10.1002/ejic.200900730

      Thumbnail image of graphical abstract

      An efficient cross-coupling reaction of aryl halides and phenol with 0.1 mol-% Cu2O nanocubes as recyclable catalyst and Cs2CO3 as the base in THF at 150 °C is reported. The process is simple and allows the formation of a diverse range of diaryl ethers in excellent yields.

  6. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Copper(I) Ethylene Complexes

      Novel CuI Ethylene Complexes with 6,6′-Diphenyl-4,4′-bipyrimidine Three-Dimensionally Self-Assembled by an Intermolecular π-π Stacking Interaction and a C–H···N Contact (pages 4225–4231)

      Masahiko Maekawa, Toshi Tominaga, Takashi Okubo, Takayoshi Kuroda-Sowa and Megumu Munakata

      Version of Record online: 26 AUG 2009 | DOI: 10.1002/ejic.200900533

      Thumbnail image of graphical abstract

      Four novel CuI–C2H4 adducts [Cu(Ph2bpm)(C2H4)]X (X = BF4, ClO4 and PF6; Ph2bpm = 6,6′-diphenyl-4,4′-bipyrimidine) were three-dimensionally self-assembled by an intermolecular π–π stacking interaction and a C–H···N contact.

    2. Metallosurfactant

      The Preparation, Solution and Mesophase Behaviour of Surfactant Complexes of Cobalt(III) (pages 4232–4239)

      Mark J. Danks, Mark E. Light and Duncan W. Bruce

      Version of Record online: 28 AUG 2009 | DOI: 10.1002/ejic.200900593

      Thumbnail image of graphical abstract

      Surfactant complexes of cobalt(III) are described, consisting of a tetradentate tetraamine and a long-chain bipyridine. Critical micelle concentrations and lyotropic liquid-crystal phase behavior are described.

    3. Cluster-Based Assemblies

      Reactions of [Et4N][Tp*W(μ3-S)(μ-S)2­(CuSCN)2] with Nitrogen Donor Ligands: Syntheses, Structures, and Third-Order Nonlinear Optical Properties (pages 4240–4247)

      Zhen-Hong Wei, Ling-Ling Li, Zhi-Gang Ren, Hong-Xi Li, Jian-Ping Lang, Yong Zhang and Zhen-Rong Sun

      Version of Record online: 20 AUG 2009 | DOI: 10.1002/ejic.200900424

      Thumbnail image of graphical abstract

      Reactions of the butterfly-shaped cluster [Et4N][Tp*W(μ3-S)(μ-S)2(CuSCN)2] with py, 4,4′-bipy, and bpp yielded three neutral compounds [Tp*W(μ3-S)(μ-S)2Cu2(SCN)(py)2], [{Tp*W(μ3-S)(μ-S)2Cu2(SCN)}2(4,4′-bipy)]·3.5H2O, and [Tp*W(μ3-S)(μ-S)2Cu2(SCN)(bpp)]2. These compounds were fully characterized. The DMF solutions of these compounds exhibit good third-order nonlinear optical performances.

    4. Carbon and SiC Fibers

      Preparation of Hollow Carbon and Silicon Carbide Fibers with Different Cross-Sections by using Electrospun Fibers as Templates (pages 4248–4254)

      Yongliang Cheng, Jiangfeng Zhang, Yanfei Zhang, Xiaolong Chen, Ying Wang, Hongmei Ma and Xueqiang Cao

      Version of Record online: 26 AUG 2009 | DOI: 10.1002/ejic.200900418

      Thumbnail image of graphical abstract

      Carbon fibers with circular and rectangular cross-sections were synthesized by using electrospun silica fibers as templates and polystyrene as carbon sources. Silicon carbide fibers with circular and rectangular cross-sections could also be fabricated by using carbon fibers as templates.

    5. Isoprene Polymerization

      Scandium Aminopyridinates: Synthesis, Structure and Isoprene Polymerization (pages 4255–4264)

      Christian Döring, Winfried P. Kretschmer, Tobias Bauer and Rhett Kempe

      Version of Record online: 19 AUG 2009 | DOI: 10.1002/ejic.200900504

      Thumbnail image of graphical abstract

      Alkyl- and silylamido-scandium complexes stabilized by an aminopyridinato ligand were synthesized and investigated with regard to isoprene polymerization performance. The alkyl complexes can be used ascatalysts for the controlled 3,4-selective polymerization of isoprene. Drastic changes of the microstructure of the polyisoprene were observed when alkylaluminium compounds were added.

    6. Luminescent Avidin Crosslinkers

      Luminescent Polypyridinerhenium(I) Bis-Biotin Complexes as Crosslinkers for Avidin (pages 4265–4273)

      Man-Wai Louie, Marco Ho-Chuen Lam and Kenneth Kam-Wing Lo

      Version of Record online: 28 AUG 2009 | DOI: 10.1002/ejic.200900518

      Thumbnail image of graphical abstract

      We report the synthesis, photophysical behavior, cytotoxicity, and cellular-uptake properties of two luminescent polypyridinerhenium(I) bis-biotin complexes and theirbiotin-free counterpart. The avidin-binding and -crosslinking properties of the bis-biotin complexes have also been examined.

    7. Metallomesogens

      Coordination Induction of Nonlinear Molecular Shape in Mesomorphic and Luminescent ZnII Complexes Based on Salen-Like Frameworks (pages 4274–4281)

      Daniela Pucci, Iolinda Aiello, Anna Bellusci, Alessandra Crispini, Mauro Ghedini and Massimo La Deda

      Version of Record online: 31 AUG 2009 | DOI: 10.1002/ejic.200900536

      Thumbnail image of graphical abstract

      The synthesis of nonlinear-core ZnII complexes based on tetradentate Schiff bases and their mesomorphic and photophysical properties are reported.

    8. Lanthanum Complex KP772

      New Insights into the Chemistry of the Antineoplastic Lanthanum Complex Tris(1,10-phenanthroline)tris(thiocyanato-κN)lanthanum(III) (KP772) and Its Interaction with Biomolecules (pages 4282–4287)

      Florian Biba, Michael Groessl, Alexander Egger, Alexander Roller, Christian G. Hartinger and Bernhard K. Keppler

      Version of Record online: 26 AUG 2009 | DOI: 10.1002/ejic.200900038

      Thumbnail image of graphical abstract

      The antineoplastic lanthanum complex KP772 [tris(1,10-phenanthroline)tris(thiocyanato-κN)lanthanum(III)] was fully characterized, the crystal structure solved, the behavior in water studied and the binding to DNA model compounds and human serum proteins investigated.

    9. Heterocyclic Carbenes

      Benzothiazolin-2-ylidene and Azole Mixed-Ligand Complexes of Palladium (pages 4288–4297)

      Swee Kuan Yen, Lip Lin Koh, Han Vinh Huynh and T. S. Andy Hor

      Version of Record online: 20 AUG 2009 | DOI: 10.1002/ejic.200900447

      Thumbnail image of graphical abstract

      A series of palladium(II) complexes stabilized by azole-based C- and N-donors has been crystallographically characterized and applied to benzylic coupling.

    10. Gallium-68 Sugar Complexes

      InIII and GaIII Complexes of Sugar-Substituted Tripodal Trisalicylidene Imines: The First 68Ga-Labelled Sugar Derivative (pages 4298–4307)

      Michael Gottschaldt, Carmen Bohlender, Anne Pospiech, Helmar Görls, Martin Walther, Dirk Müller, Ingo Klette, Richard P. Baum and Ulrich S. Schubert

      Version of Record online: 14 AUG 2009 | DOI: 10.1002/ejic.200900561

      Thumbnail image of graphical abstract

      Sugar-substituted tripodal triamines were synthesised. Condensation to differentsalicylaldehydes resulted in the formation of tripodal trisalicylaldimines as versatile ligands for trivalent metal ions. The formation of InIII and GaIII complexes was studied, and their structure could be assigned. Labelling of one of the ligands with 68Ga was achieved in high radiochemical yield, and the complex displayed stability towards apo-transferin and blood plasma.

    11. 1,2-Hydrogen Shift Migration

      Reactivity of {Ru(C5Me5)[η2-P,O-Ph2PCH2C(tBu)=O](CO)}[PF6] towards Terminal Alkynes and Unexpected Rearrangement of a Fischer-Type Carbene Ligand (pages 4308–4313)

      Bernard Demerseman and Loïc Toupet

      Version of Record online: 24 AUG 2009 | DOI: 10.1002/ejic.200900574

      Thumbnail image of graphical abstract

      Isomerization of a Fischer-type carbene ligand into an η2-coordinated vinylic ether occurred under moderate thermal activation (dichloromethane at reflux) conditions.

    12. Complexes of a Macrocyclic Ligand

      A Macrocyclic Bistriazene and its Complexes with Divalent Metal Ions (pages 4314–4319)

      Johannes Beck, Manfredo Hörner and Gertrud Dittmann

      Version of Record online: 19 AUG 2009 | DOI: 10.1002/ejic.200900470

      Thumbnail image of graphical abstract

      Ring closure reaction of mono diazotized 2,2′-diaminoditolane gives rise to a macrocyclic bistriazene of planar molecular shape. After deprotonation the respective bis(tolanetriazendiide) is a suitable complexating ligand for divalent transition metals like Co2+ and Ni2+. The rigidity of the molecular system retains the planarity in the complexes.

    13. N-Heterocyclic Carbene Polymorphism

      N-Heterocyclic Carbene Complexes of Rhodium and Iridium: Steric Effects on Molecular Conformation (pages 4320–4328)

      Gary S. Nichol, Jonathan Rajaseelan, Laura J. Anna and Edward Rajaseelan

      Version of Record online: 20 AUG 2009 | DOI: 10.1002/ejic.200900480

      Thumbnail image of graphical abstract

      Synthesis and structural characterization of new N-heterocyclic carbene complexes of Rh and Ir are reported, including the first determination of polymorphism in this type of complex. Differences in wingtip substituent give different molecular conformations, rationalized in terms of steric crowding and attractive intramolecularforces.

    14. Titanium/Coin Metal Cluster Complexes

      Syntheses, Structures and Theoretical Investigations of [Li(thf)4]2[Ti2Cu8S4(SPh)10] and [Ti2Ag6S6Cl2(PPhiPr2)6] (pages 4329–4334)

      Heino Sommer, Nedko Drebov, Andreas Eichhöfer, Reinhart Ahlrichs and Dieter Fenske

      Version of Record online: 25 AUG 2009 | DOI: 10.1002/ejic.200900581

      Thumbnail image of graphical abstract

      We describe syntheses, crystal structures and results of DFT treatments of the new titanium/coin metal chalcogenide cluster complexes [Li(thf)4]2[Ti2Cu8S4(SPh)10] and [Ti2Ag6S6Cl2(PPhiPr2)6].

SEARCH

SEARCH BY CITATION