European Journal of Inorganic Chemistry

Cover image for Vol. 2009 Issue 3

January 2009

Volume 2009, Issue 3

Pages 323–447

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Full Papers
    1. On the Effect of Coordination and Protonation Preferences in the Amphiphilic Behavior of Metallosurfactants with Asymmetric Headgroups (Eur. J. Inorg. Chem. 3/2009) (page 323)

      Frank D. Lesh, Sarmad Sahiel Hindo, Mary Jane Heeg, Marco M. Allard, Prateek Jain, Bo Peng, Lew Hryhorczuk and Cláudio N. Verani

      Version of Record online: 12 JAN 2009 | DOI: 10.1002/ejic.200990000

  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Full Papers
  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Full Papers
  4. Microreview

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Full Papers
    1. No Magnetic Memory

      Superparamagnetic Composites: Magnetism with No Memory (pages 333–343)

      Pedro Tartaj

      Version of Record online: 18 DEC 2008 | DOI: 10.1002/ejic.200800875

      Thumbnail image of graphical abstract

      Superparamagnetic composites represent a good example of how mixing at the nanoscale solves fundamental and technological challenges.

  5. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Full Papers
    1. Metal-Containing Amphiphiles

      On the Effect of Coordination and Protonation Preferences in the Amphiphilic Behavior of Metallosurfactants with Asymmetric Headgroups (pages 345–356)

      Frank D. Lesh, Sarmad Sahiel Hindo, Mary Jane Heeg, Marco M. Allard, Prateek Jain, Bo Peng, Lew Hryhorczuk and Cláudio N. Verani

      Version of Record online: 31 OCT 2008 | DOI: 10.1002/ejic.200800761

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      Metallosurfactants containing NiII, CuII, and ZnII ions were synthesized and studied by compression isotherms and Brewster angle microscopy. Structure/function relationships between amphiphilic properties, coordination modes, and protonation status were drawn based on archetypical modeling and DFT calculations.

    2. Luminescent Oxide Fluorides

      Facile Synthesis of Bastnaesite-Type LaF[CO3] and Its Thermal Decomposition to LaOF for Bulk and Eu3+-Doped Samples (pages 357–362)

      Oliver Janka and Thomas Schleid

      Version of Record online: 9 DEC 2008 | DOI: 10.1002/ejic.200800931

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      Solution-born, precipitated LaF[CO3] with a bastnaesite-type structure was used as a precursor for the synthesis of three forms of LaOF by thermal decomposition. The three LaOF forms were tested as host materials for Eu3+-doped red phosphors on the basis of both the fluoride oxocarbonates and the different oxide fluoride phases.

    3. Zinc Complexes

      Synthesis, Crystal Structures, and Thermal Properties of New [ZnX2(2,5-dimethylpyrazine)] (X = Cl, Br, I) Coordination Compounds (pages 363–372)

      Mario Wriedt, Inke Jeß and Christian Näther

      Version of Record online: 15 DEC 2008 | DOI: 10.1002/ejic.200800646

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      Eight new halidozinc(II) coordination compounds with 2,5-dimethylpyrazine as a ligand were prepared and characterized. Their structures and thermal propertieswere determined. Upon heating, the ligand-rich compounds transform quantitatively into new ligand-deficient compounds.

    4. Copper(II) Compounds

      (1,3,4-Oxadiazole)copper(II) Compounds: Dimensionality, Magnetism and Nuclease Activity (pages 373–388)

      Patricia Gómez-Saiz, Rubén Gil-García, Miguel A. Maestro, Francisco J. Arnaiz, Luis Lezama, Teófilo Rojo, José Luis Pizarro, María Isabel Arriortúa, Marta González-Álvarez, Joaquín Borrás, Virginia Diez-Gómez and Javier García-Tojal

      Version of Record online: 12 DEC 2008 | DOI: 10.1002/ejic.200800812

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      The dimensionality of [2-amino-5-(pyridin-2-yl)-1,3,4-oxadiazole]copper(II) entities and their 4-N-methyl derivatives largely depends on the coligands employed and the experimental parameters. Their magnetic properties and nuclease activity are explored.

    5. Bioorganometallic Chemistry

      Conformational Analysis of β-Lactam-Containing Ferrocene Peptides (pages 389–399)

      Veronika Kovač, Katarina Radolović, Ivan Habuš, Daniel Siebler, Katja Heinze and Vladimir Rapić

      Version of Record online: 10 DEC 2008 | DOI: 10.1002/ejic.200800913

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      The synthesis and characterization of ferrocene bioconjugates with alanine and the β-lactam [3-amino-1-(4-methoxyphenyl)-4-phenyl-β-lactam (≡ Alm)] Fc-CO-Ala-Alm (12), Boc-Fca-Ala-Alm (13), and Fn(CO-Ala-Alm)2 (14) is reported. The conformational preferences of these organometallic peptidomimetics in solution were determined experimentally and corroborated theoretically by DFT calculations.

    6. Anion Coordination Effects

      Anion Coordination Effect on the Nuclearity of CoII, NiII, CuII, and ZnII Complexes with a Benzimidazole Pendant-Armed Crown (pages 400–411)

      Lea Vaiana, David Esteban-Gómez, Marta Mato-Iglesias, Carlos Platas-Iglesias, Andrés de Blas and Teresa Rodríguez-Blas

      Version of Record online: 16 DEC 2008 | DOI: 10.1002/ejic.200800928

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      A pendant-armed crown ether containing benzimidazole pendants (L4) forms mononuclear complexes with CoII, NiII, CuII, and ZnII perchlorates, which upon treatment with chloride anions readily convert into dimeric species of the general formula [M2(L4)(Cl)2(H2O)n](ClO4)2 (M = Co, Cu, n = 0; M = Ni, n = 2).

    7. Amidometal Chemistry

      Synthesis and Structure of Aminopyridinato-Stabilized Yttrium and Lanthanum Amides and Their Reactivity towards Alkylaluminium Compounds (pages 412–418)

      Christian Döring and Rhett Kempe

      Version of Record online: 12 DEC 2008 | DOI: 10.1002/ejic.200800934

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      Aminopyridinato-stabilized (silylamido)lanthanoid complexes were synthesized and investigated with regard to coordinative chain transfer polymerization. Such complexes are not stable in the presence ofalkylaluminium compounds and decompose by aminopyridinato ligand transfer from the rare earth metal to the aluminium atom.

    8. Cluster-Bridged Metallacycles

      Self-Assembled Transition-Metal Macrocycles and Two-Dimensional Coordination Polymers Derived from Flexible C2Co2 Cluster-Bridged Bipyridine Ligands [(4-C5H4NCO2CH2)2C2Co2(CO)6] and [(3-C5H4NCO2CH2)2C2Co2(CO)6] (pages 419–428)

      Li-Cheng Song, Guo-Xia Jin, Li-Qun Zhao, Hu-Ting Wang, Wen-Xiong Zhang and Qing-Mei Hu

      Version of Record online: 12 DEC 2008 | DOI: 10.1002/ejic.200800953

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      The self-assembly of isomeric bipyridine ligands [(4-C5H4NCO2CH2)2C2Co2(CO)6] and [(3-C5H4NCO2CH2)2C2Co2(CO)6] with transition-metal compounds results in the formation of novel metallamacrocycles and 2D polymers in high yields.

    9. Hydroamination Catalysts

      Imido and Amido Titanium Complexes that Contain a [OSSO]-Type Bis(phenolato) Ligand: Synthesis, Structures, and Hydroamination Catalysis (pages 429–434)

      Bing Lian, Thomas P. Spaniol, Patricia Horrillo-Martínez, Kai C. Hultzsch and Jun Okuda

      Version of Record online: 15 DEC 2008 | DOI: 10.1002/ejic.200800977

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      Imido and amido titanium catalysts containing a [OSSO]-type tetradentate bis(phenolato) ligand were readily synthesized and characterized. The imido titaniumcatalysts showed good activity in bothintramolecular aminoalkyne and aminoalkene hydroamination.

    10. Magnetic Effects

      Magnetic Field Effects on the Formation and Properties of Nickel Nanostructures (pages 435–440)

      Lixia Sun and Qianwang Chen

      Version of Record online: 16 DEC 2008 | DOI: 10.1002/ejic.200801039

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      The formation and properties of 1D nickel wires can be influenced by magnetic fields. The magnetic properties of a sample formed in a magnetic field are improved relative to those of a sample formed in the absence of an applied field. Moreover, microwave absorption is enhanced, indicating that the anisotropic wires are not simply an assembly of particles, but that the magnetic domain structure in the wires has been changed by the applied field.

    11. Fluorides in Liquid Ammonia

      The Reactions of Silver, Zirconium, and Hafnium Fluorides with Liquid Ammonia: Syntheses and Crystal Structures of Ag(NH3)2F·2NH3, [M(NH3)4F4]·NH3 (M = Zr, Hf), and (N2H7)F (pages 441–447)

      Florian Kraus, Sebastian A. Baer and Matthias B. Fichtl

      Version of Record online: 9 DEC 2008 | DOI: 10.1002/ejic.200800980

      Thumbnail image of graphical abstract

      By the reaction of fluorides with liquid ammonia the new compounds [MF4(NH3)4F4]·NH3 (M = Zr, Hf), N2H7F, and [Ag(NH3)2]F·2NH3 were obtained. The latter is the first diaminesilver(I) halide characterized by single-crystal X-ray analysis, and N2H7F presents the first ammoniate of ammonium fluoride.

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