European Journal of Inorganic Chemistry

Cover image for Vol. 2009 Issue 32

November 2009

Volume 2009, Issue 32

Pages 4739–4895

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communication
    7. Full Papers
    8. Correction
    1. Characteristic Structures and Photophysical Properties of Nine-Coordinate Europium(III) Complexes with Tandem-Connected Tridentate Phosphane Oxide Ligands (Eur. J. Inorg. Chem. 32/2009) (page 4739)

      Kohei Miyata, Yasuchika Hasegawa, Yusuke Kuramochi, Tetsuya Nakagawa, Toshiaki Yokoo and Tsuyoshi Kawai

      Version of Record online: 3 NOV 2009 | DOI: 10.1002/ejic.200990087

  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communication
    7. Full Papers
    8. Correction
  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communication
    7. Full Papers
    8. Correction
  4. Microreview

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communication
    7. Full Papers
    8. Correction
    1. High-Nuclearity Grids

      Grids with Unusual, High Nuclearity – A Structural Approach (pages 4751–4770)

      Adrian-Mihail Stadler

      Version of Record online: 26 OCT 2009 | DOI: 10.1002/ejic.200900761

      Thumbnail image of graphical abstract

      Self-assembled supramolecular grid-like architectures with nuclearity higher than four, generated by tri-, tetra- and pentatopic ligands, are fascinating and attractive because of their structural and functional features. The present review is focused on their structural diversity and characterization.

  5. Short Communication

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communication
    7. Full Papers
    8. Correction
    1. Actinide Hexamers

      First Hexanuclear UIV and ThIV Formate Complexes – Structure and Stability Range in Aqueous Solution (pages 4771–4775)

      Shinobu Takao, Koichiro Takao, Werner Kraus, Franziska Emmerling, Andreas C. Scheinost, Gert Bernhard and Christoph Hennig

      Version of Record online: 9 OCT 2009 | DOI: 10.1002/ejic.200900899

      Thumbnail image of graphical abstract

      The actinide(IV) hexanuclear [M63-O(H)}8(HCOO)12(LT)6] complexes were prepared (LT = H2O or CH3OH). HCOO acts as a bridging ligand, which prevents the formation of polynuclear hydrolysis species like UIV hydrous oxide colloids at least up to pH = 3.25, and stabilizes the nanosized clusters in solution. The charge of the hexamer is balanced by the O/OH ratio of the μ3 bridges.

  6. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communication
    7. Full Papers
    8. Correction
    1. Lanthanide Complexes

      Characteristic Structures and Photophysical Properties of Nine-Coordinate Europium(III) Complexes with Tandem-Connected Tridentate Phosphane Oxide Ligands (pages 4777–4785)

      Kohei Miyata, Yasuchika Hasegawa, Yusuke Kuramochi, Tetsuya Nakagawa, Toshiaki Yokoo and Tsuyoshi Kawai

      Version of Record online: 11 SEP 2009 | DOI: 10.1002/ejic.200900598

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      The characteristic structures and photophysical properties of polyhedral f-block metal complexes, nine-coordinate EuIII complexes with tridentate phosphane oxide, are demonstrated for the first time.

    2. Hybrid Vanadates

      Two Self-Catenated Nickel(II) Hybrid Vanadates with Honeycomb-Like 3D Inorganic Frameworks Stabilized by Crossed Organic Bpe Pillars: Thermal, Spectroscopic and Magnetic Properties (pages 4786–4794)

      Roberto Fernández de Luis, Jose L. Mesa, M. Karmele Urtiaga, Teófilo Rojo and María Isabel Arriortua

      Version of Record online: 30 SEP 2009 | DOI: 10.1002/ejic.200900550

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      Two self-catenated hybrid vanadates have been hydrothermally synthesized. Both of them possess a 3D inorganic frameworks stabilized by an organic ligand. Increase of the ligand size enlarges the diameter of the inorganic channels. The thermal behaviour of these rigid architectures shows an irreversible structural transformation due to the removal of coordinated water molecules.

    3. Alkyl Complexes

      Stabilization and Activation: New Alkyl Complexes of Zinc, Magnesium and Cationic Aluminium Featuring Chelating Bisguanidine Ligands (pages 4795–4808)

      Matthias Reinmuth, Ute Wild, Daniel Rudolf, Elisabeth Kaifer, Markus Enders, Hubert Wadepohl and Hans-Jörg Himmel

      Version of Record online: 8 OCT 2009 | DOI: 10.1002/ejic.200900591

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      Bisguanidines were used to synthesizeseveral new zinc, magnesium and cationic aluminium alkyl complexes, and their bond properties and dynamic behaviour were studied in detail.

    4. Dehydrogenation

      The Borane Complexes Htbo·BH3 and Htbn·BH3 (Htbo = 1,4,6-Triazabicyclo[3.3.0]oct-4-ene, Htbn = 1,5,7-Triazabicyclo[4.3.0]non-6-ene): Synthesis and Dehydrogenation to Dinuclear Boron Hydrides (pages 4809–4819)

      Nikola Schulenberg, Mascha Jäkel, Elisabeth Kaifer and Hans-Jörg Himmel

      Version of Record online: 5 OCT 2009 | DOI: 10.1002/ejic.200900646

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      Fine-tuning of the dehydrogenation process of borane adducts to bicyclic guanidines is possible by variation of the ring size.

    5. Linear Tetrasilver(I) Complexes

      Synthesis and Characterization of Linear Tetranuclear Silver(I) Complexes Bridged by Tetraphosphane Ligands (pages 4820–4829)

      Yukie Takemura, Takayuki Nakajima and Tomoaki Tanase

      Version of Record online: 30 SEP 2009 | DOI: 10.1002/ejic.200900652

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      A tetraphosphane meso-bis[(diphenylphosphanylmethyl)phenylphosphanyl]methane(dpmppm) afforded a series of tetranuclear AgI complexes, in which two dpmppmligands are disposed in syn- and anti-fashions with respect to the fluxional and labile Ag4 strings.

    6. Ruthenium Cluster Compounds

      Carboxylato-Modified New Oxo-Centred Triruthenium Cluster Compounds with CO and Solvent Ligands: The X-ray Structure of [Ru3O(C2H5CO2)6(CO)(THF)2] (pages 4830–4836)

      Atsushi Inatomi, Masaaki Abe and Yoshio Hisaeda

      Version of Record online: 9 OCT 2009 | DOI: 10.1002/ejic.200900701

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      A new series of μ3-oxo-triruthenium cluster compounds with varied bridging carboxylato groups of the type [Ru3O(RCO2)6(CO)(solvent)2] where R = C2H5 and C6H5 has been synthesised and the structures,redox chemistry and photo-induced CO dissociation reactions have been examined.

    7. Titanium Complexes with ILs

      Syntheses, Crystal Structures, Thermal Properties and Spectroscopic Characterization of Complex Chloridotitanates(IV) with Ionic Liquids (pages 4837–4843)

      Johann-Christian Leye, Mimoza Gjikaj and Arnold Adam

      Version of Record online: 8 OCT 2009 | DOI: 10.1002/ejic.200900507

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      The synthesis and characterization of new chloridotitanates(IV) [EMIm]2 [TiCl6] (I), [EMIm][TiCl5MeCN] (II) and [EMIm]4[TiCl6][Ti2Cl10] (III) are presented. Whereas compounds I and II consist of an octahedral [TiL6] polyhedron, compound III possesses both octahedral [TiCl6] and edge-sharing dichlorido-bridged bioctahedral [Ti2Cl10] units. The dimer–monomer conversion of III is also discussed.

    8. Chiral Lanthanide Complexes

      Synthesis and Physical Properties of Two Chiral Terpyridyl Europium(III) Complexes with Distinct Crystal Polarity (pages 4844–4849)

      Dong-Ping Li, Cheng-Hui Li, Jun Wang, Ling-Cheng Kang, Tao Wu, Yi-Zhi Li and Xiao-Zeng You

      Version of Record online: 30 SEP 2009 | DOI: 10.1002/ejic.200900655

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      Two novel chiral terpyridyl EuIII complexes were synthesized. Complex 1 crystallizes in the polar space group P21, and 2 in the nonpolar space group P212121. In contrast to 2, 1 exhibits brilliant triboluminescence, intense NLO properties and ferroelectric behaviour at room temperature. The distinct chiral physical properties of complexes 1 and 2 can be explained by the different crystal polarity.

    9. Electron Transfer

      Cyclometalated Iridium(III) Complexes as Photosensitizers for Long-Range Electron Transfer: Occurrence of a Coulomb Barrier (pages 4850–4859)

      David Hanss, Jonathan C. Freys, Gérald Bernardinelli and Oliver S. Wenger

      Version of Record online: 12 OCT 2009 | DOI: 10.1002/ejic.200900673

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      Coulomb barriers imposed by metal-to-ligand charge transfer excited electrons are found to have an important impact on the rates of photoinduced long-range electron transfers.

    10. Boron–Carbon Bond Cleavage

      1,1′-Diborylferrocenes from [2]Boraferrocenophanes by Boron–Boron Exchange (pages 4860–4863)

      Holger Braunschweig, Bernd Grünewald, Katrin Schwab and Rainer Sigritz

      Version of Record online: 1 OCT 2009 | DOI: 10.1002/ejic.200900772

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      A new reactivity pattern for the alternative synthesis of 1,1′-diborylferrocenes starting from [2]boraferrocenophanes and simple boranes or diboranes is presented.

    11. Lanthanoid Cluster Compounds

      A Chlorine-Centered Cluster of Composition [(Me3Si)2NC(NCy)2SmCl2]5(thf)2 and a Comparison with the Heavier Ytterbium Congener [(Me3Si)2NC(NCy)2YbCl2]2(LiCl)2(thf)4 (pages 4864–4869)

      Zhensheng Zhang, Herbert W. Roesky, Thomas Schulz, Dietmar Stalke and Alexander Döring

      Version of Record online: 8 OCT 2009 | DOI: 10.1002/ejic.200900790

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      The salt-free samarium compound [(Me3Si)2NC(NCy)2SmCl2]5(thf)2 has been prepared. X-ray diffraction studies of this compound result in a unique cluster structure, where a centered chlorine atom coordinates to four samarium atoms. The properties and comparison with a heavier ytterbium congener [(Me3Si)2NC(NCy)2YbCl2]2(LiCl)2(thf)4 have been investigated. Color code: green = chlorine; red = oxygen; yellow = samarium.

    12. Hybrid Materials

      Lead(II) Hybrid Materials from 3- or 4-Phosphonobenzoic Acid (pages 4870–4876)

      Jean-Michel Rueff, Olivier Perez, André Leclaire, Hélène Couthon-Gourvès and Paul-Alain Jaffrès

      Version of Record online: 1 OCT 2009 | DOI: 10.1002/ejic.200900430

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      Three 3D-layered materials (2, 3, and 4) have been synthesised starting from 4-phosphonobenzoic acid and lead(II). These structures are compared with the structure 1 synthesised from 3-phosphonobenzoicacid. The understanding of the stacking of the organic molecules within the layer, the influence of the electronic lone pair and the water molecules are discussed

    13. Phenoxido-Bridged Cu Complexes

      A Combined Experimental and Theoretical Study on the Magnetic Properties of a Family of Bis(μ-phenoxido)dicopper(II) Complexes Bearing ω-[Bis(2-hydroxy-3,5-dimethylbenzyl)amino]alkan-1-ol Ligands (pages 4877–4886)

      Oula Wichmann, Harri Sopo, Enrique Colacio, Antonio J. Mota and Reijo Sillanpää

      Version of Record online: 8 OCT 2009 | DOI: 10.1002/ejic.200900684

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      Five new bis(μ-phenoxido)dicopper(II) neutral complexes with or without a water bridge were prepared from a family of ω-[bis(2-hydroxy-3,5-dimethylbenzyl)amino]alkan-1-ol ligands. Magnetostructural data and DFT calculations demonstrate that the major factor controlling the magnetic coupling is, by far, the Cu–O–Cu bridging angle.

    14. Hydrate Isomerism

      Role of Water and Solvent in the Formation of Three Mononuclear Copper(II) Crystals: A New Type of Hydrate Isomerism in Coordination Chemistry (pages 4887–4894)

      Susanta Hazra, Rajesh Koner, Malabika Nayak, Hazel A. Sparkes, Judith A. K. Howard, Supriya Dutta and Sasankasekhar Mohanta

      Version of Record online: 8 OCT 2009 | DOI: 10.1002/ejic.200900432

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      The syntheses, structures, properties and interconversion behaviour of the nonhydrated compound [CuIIL1], coordinated-water-containing compound [CuIIL1(H2O)]and encapsulated-water-containing compound [CuIIL1blabla(H2O)] derived from the same ligand N,N′-ethylenebis(3-ethoxysalicylaldimine) (H2L1) are described.

  7. Correction

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communication
    7. Full Papers
    8. Correction
    1. You have free access to this content
      Polynuclear Complexes of Macrocyclic Oxamide with Thiocyanate: Syntheses, Crystal Structures and Magnetic Properties (page 4895)

      Ya-Qiu Sun, Dong-Zhao Gao, Wen Dong, Dai-Zheng Liao and Chen-Xi Zhang

      Version of Record online: 14 OCT 2009 | DOI: 10.1002/ejic.200900967

      This article corrects:

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