European Journal of Inorganic Chemistry

Cover image for Vol. 2009 Issue 36

December 2009

Volume 2009, Issue 36

Pages 5459–5591

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
    1. Ferromagnetic Properties of a Trinuclear Nickel(II) Complex with a Trithiocyanurate Bridge (Eur. J. Inorg. Chem. 36/2009) (page 5459)

      Pavel Kopel, Jerzy Mrozinski, Karel Doležal, Vratislav Langer, Roman Boča, Alina Bieńko and Andrzej Pochaba

      Version of Record online: 8 DEC 2009 | DOI: 10.1002/ejic.200990101

  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
  4. Short Communication

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
    1. A Cu/Co/Ni Pentanuclear Core

      A Pentanuclear Cu/Co/Ni Complex with 2-(Dimethylamino)ethanol – Observation of a Rare Molecular Structure Type and Its Place in General Structural Types: An Analysis of the Cambridge Structural Database (pages 5469–5473)

      Dmytro S. Nesterov, Vladimir N. Kokozay and Brian W. Skelton

      Version of Record online: 18 NOV 2009 | DOI: 10.1002/ejic.200900815

      Thumbnail image of graphical abstract

      The heterotrimetallic Cu/Co/Ni complex with 2-(dimethylamino)ethanol has been prepared by direct synthesis. The pentanuclear coordination core of the presented complex possesses extremely rare asymmetric organization. The general pentanuclear molecular structure types and their comparison with the structure of the presented compound are discussed.

  5. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
    1. Trinuclear Ni(III) Complexes

      Ferromagnetic Properties of a Trinuclear Nickel(II) Complex with a Trithiocyanurate Bridge (pages 5475–5482)

      Pavel Kopel, Jerzy Mrozinski, Karel Doležal, Vratislav Langer, Roman Boča, Alina Bieńko and Andrzej Pochaba

      Version of Record online: 29 OCT 2009 | DOI: 10.1002/ejic.200900617

      Thumbnail image of graphical abstract

      The trinuclear nickel(II) complex [Ni3(pmdien)3(μ-ttc)](ClO4)3 with N,N,N′,N″,N″-pentamethyldiethylenetriamine (pmdien) and a trithiocyanurate(3–) (ttc3–) bridge was synthesized. This trinuclear nickel(II) complex has a regular triangular Ni3 core. The trimer showed ferromagnetic interactions among the NiII magnetic centers and spin-glass properties. Biological studies were also investigated.

    2. Coordination Versatility in Supramolecules

      Structure and Properties of Copper(II), Manganese(III), and Iron(III) Complexes with Potentially Pentaanionic Heptadentate Ligands Including Alkoxido, Amido, and Phenoxido Donors (pages 5483–5493)

      Liliana Stoicescu, Carine Duhayon, Laure Vendier, Ana Tesouro-Vallina, Jean-Pierre Costes and Jean-Pierre Tuchagues

      Version of Record online: 5 NOV 2009 | DOI: 10.1002/ejic.200900791

      Thumbnail image of graphical abstract

      The coordination ability and versatility of the potentially pentaanionic heptadentate ligands H5L1–H5L3 towards transition-metal ions is demonstrated by the different dinucleating chelation modes described in this report. The sheetlike packing in the 2D [Cu2(L1)(OAc)Cs2(MeOH)2]n coordination polymer is shown.

    3. Tuning Supramolecular Networks

      Change in Supramolecular Networks through In Situ Esterification of Porphyrins (pages 5494–5505)

      Wentong Chen and Shunichi Fukuzumi

      Version of Record online: 17 NOV 2009 | DOI: 10.1002/ejic.200900801

      Thumbnail image of graphical abstract

      Eight esterified TCPP compounds were successfully synthesized by solvothermal reactions and characterized. The reaction mechanism was investigated. Esterification plays a vital role in the properties, structural motifs and supramolecular networks.

    4. Biomimetic Chemistry

      Synthesis, Characterization, and Oxygenation Studies of Carboxylate-Bridged Diiron(II) Complexes with Aromatic Substrates Tethered to Pyridine Ligands and the Formation of a Unique Trinuclear Complex (pages 5506–5515)

      Simone Friedle and Stephen J. Lippard

      Version of Record online: 5 NOV 2009 | DOI: 10.1002/ejic.200900821

      Thumbnail image of graphical abstract

      Carboxylate-rich diiron compounds are prepared with tethered aromatic substrates as structural and functional models for the active sites of non-heme diiron metalloproteins.

    5. Bis(phosphoranido) Complexes

      Syntheses and Characterization of Novel trans-Bis(phosphoranido)platinum(II) Complexes: Reactions of Lithium Bis(naphth-1,8-diyl-8-oxy)phosphoranide with cis-PtCl2(PR3)2 (R = OPh, OMe, Me) (pages 5516–5521)

      Kazumasa Kajiyama, Issei Sato, Satoru Yamashita and Takeshi K. Miyamoto

      Version of Record online: 17 NOV 2009 | DOI: 10.1002/ejic.200900834

      Thumbnail image of graphical abstract

      trans-Bis(phosphoranido)platinum(II) complexes, which are the first square-planar complexes to bear two phosphoranide ligands in a trans array, were synthesized. The structural property was confirmed by X-ray structural analysis of the bis(phosphoranido) complex bearing triphenyl phosphites.

    6. Hydroxyapatite Hollow Spheres

      Solvothermal Synthesis and Characterization of Hierarchically Nanostructured Hydroxyapatite Hollow Spheres (pages 5522–5526)

      Ming-Guo Ma and Jie-Fang Zhu

      Version of Record online: 4 NOV 2009 | DOI: 10.1002/ejic.200900839

      Thumbnail image of graphical abstract

      The solvothermal synthesis of hierarchically nanostructured hydroxyapatite hollow spheres assembled from nanorods was carried out at 200 °C for 24 h in water/N,N-dimethylformamide (DMF) mixed solvents.

    7. Spin-Crossover Complexes

      Two New Iron(II) Spin-Crossover Complexes with N4O2 Coordination Sphere and Spin Transition around Room Temperature (pages 5527–5534)

      Birgit Weber, Jaroslava Obel, Dunie Henner-Vásquez and Wolfgang Bauer

      Version of Record online: 4 NOV 2009 | DOI: 10.1002/ejic.200900846

      Thumbnail image of graphical abstract

      A new modification of an N2O2 coordinating Schiff base like ligand enables a more detailed investigation of the influence of H-bonds on spin-crossover properties. A significant increase in the transition temperature was observed.

    8. Trinucelar Complexes

      Control of Exchange Interactions in Trinuclear Complexes Based on Orthogonal Magnetic Orbitals (pages 5535–5540)

      Birgit Weber, Jaroslava Obel, Lucia R. Lorenz, Wolfgang Bauer, Luca Carrella and Eva Rentschler

      Version of Record online: 4 NOV 2009 | DOI: 10.1002/ejic.200900847

      Thumbnail image of graphical abstract

      The magnetic properties of trinuclear complexes can be controlled by using the principles of strict orthogonality of the magnetic orbitals.

    9. Metal-Promoted Cycloadditions

      Platinum(II)-Promoted [2+3] Cycloaddition of Azide with 4-Cyanobenzaldehyde, a Schiff Base Derivative or Dicyanobenzenes To Give Formyl-, Amino(imino)- or Cyano-Functionalized Tetrazolato Complexes (pages 5541–5549)

      Jamal Lasri, M. Fátima C. Guedes da Silva, Maximilian N. Kopylovich, Bhaswati Ghosh Mukhopadhyay and Armando J. L. Pombeiro

      Version of Record online: 4 NOV 2009 | DOI: 10.1002/ejic.200900858

      Thumbnail image of graphical abstract

      Cycloaddition of bis(azido)platinum(II) with 4-cyanobenzaldehyde furnishes (formylphenyl)tetrazolate PtII that reacts with 2-dimethylaminoethylamine to give the corresponding Schiff base derivative; the latter undergoes hydrolysis in the presence of a metal salt. Reactions with dicyanobenzenes give (cyanophenyl)tetrazolate complexes.

    10. Germanium Nanomaterials

      Synthesis and Characterization of Germanium Coordination Compounds for Production of Germanium Nanomaterials (pages 5550–5560)

      Timothy J. Boyle, Louis J. Tribby, Leigh Anna M. Ottley and Sang M. Han

      Version of Record online: 9 NOV 2009 | DOI: 10.1002/ejic.200900556

      Thumbnail image of graphical abstract

      A series of GeII precursors―Ge[OC6H3(C6H5)2]2 shown―were synthesized for production of Ge0 nanomaterials. Upon precipitation from solution, it was found that Ge0 nanodots were formed from the amide, nanowires from alkoxides (shown) and siloxides, and amorphous GexSy from the silanthiolate.

    11. Chiral (Olefin)amine Ligands

      Chiral [Bis(olefin)amine]rhodium(I) Complexes – Transfer Hydrogenation in Ethanol (pages 5561–5576)

      Theo Zweifel, David Scheschkewitz, Timo Ott, Matthias Vogt and Hansjörg Grützmacher

      Version of Record online: 13 NOV 2009 | DOI: 10.1002/ejic.200900875

      Thumbnail image of graphical abstract

      A number of chiral [bis(olefin)amino]rhodium(I) complexes containing a tropylidenyl moiety (blue) were synthesized and tested in enantioselective transfer hydrogenations by using ethanol as “green” hydrogen donor. The best results were obtained with a ligand containing a cyclohex-3′-en-1′-yl group (red) (up to 44 % ee at a substrate/catalyst ratio S/C = 10000).

    12. Boron Clusters

      hypercloso-Hexa(amino)hexaboranes: Structurally Related to Known hypercloso-Dodecaboranes, Metastable with Regard to Their Classical Cycloisomers (pages 5577–5582)

      Wahid Mesbah, Meisam Soleimani, Elham Kianfar, Gertraud Geiseler, Werner Massa, Matthias Hofmann and Armin Berndt

      Version of Record online: 13 NOV 2009 | DOI: 10.1002/ejic.200900850

      Thumbnail image of graphical abstract

      In spite of their weak aromaticity and in contrast to reports in the literature, hypercloso-hexa(amino)hexaboranes like A are higher in energy than the corresponding cycloisomers like B. This is shown experimentally as well as by computations at the B3LYP/6-311+G** level of theory. Compound A is the first hypercloso-hexaborane to be characterized by X-ray structural analysis.

    13. Chiral Phospholenes

      Enantiomerically Pure P,N Chelates Based on Phospholene Rings: Palladium Complexes and Catalytic Applications in Allylic Substitution (pages 5583–5591)

      François Leca, Fernando Fernández, Guillermo Muller, Christophe Lescop, Régis Réau and Montserrat Gómez

      Version of Record online: 11 NOV 2009 | DOI: 10.1002/ejic.200900892

      Thumbnail image of graphical abstract

      The synthesis of optically pure 2-pyridylphospholene ligands by diastereomeric resolution of PdII complexes also bearing the chiral amine (R)-α-methylbenzylamine is described. A full coordination study of these ligands and the corresponding phosphole ligands has been carried out. Their catalytic behaviour in Pd-catalysed allylic substitutions has also been evaluated.

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