European Journal of Inorganic Chemistry

Cover image for Vol. 2010 Issue 34

December 2010

Volume 2010, Issue 34

Pages 5343–5483

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
  4. Microreview

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Ferrocene in Coordination Polymers

      Ferrocene-Containing Coordination Polymers: Ligand Design and Assembled Structures (pages 5355–5371)

      Ryo Horikoshi and Tomoyuki Mochida

      Version of Record online: 28 OCT 2010 | DOI: 10.1002/ejic.201000525

      Thumbnail image of graphical abstract

      This microreview covers the design and assembled structures of ferrocene-containing coordination polymers with basic bidentate ligands. The structural diversity of the coordination polymers is attributed to the conformational flexibility as well as the flexible design of the ferrocene-containing ligands, which also causes the variation in their properties.

  5. Short Communications

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Metal-Radical Exchange Interaction

      Beyond Kahn's Model: Substituent and Heteroatom Influence on Exchange Interaction in a Metal-Verdazyl Complex (pages 5373–5378)

      Olivier Oms, Jean-Baptiste Rota, Lucie Norel, Carmen J. Calzado, Hélène Rousselière, Cyrille Train and Vincent Robert

      Version of Record online: 29 OCT 2010 | DOI: 10.1002/ejic.201001033

      Thumbnail image of graphical abstract

      The first thiooxoverdazyl metal complex appears as a case study of the metal-radical exchange interaction: wavefunction calculations reveal that the observed ferromagnetic interaction is controlled by the radical substituent rather than by its heteroatom as anticipated by Kahn's model.

    2. Boron Bithiazole Complexes

      Synthesis and Structure of Boron–Bithiazole Complexes (pages 5379–5382)

      Michael Findlater, Nicholas S. Swisher and Peter S. White

      Version of Record online: 26 OCT 2010 | DOI: 10.1002/ejic.201000940

      Thumbnail image of graphical abstract

      Two boronium cations, supported by the bithiazole ligand framework, were synthesized and characterized using spectroscopic techniques. The X-ray single-crystal diffraction study reveals the first structurally characterized p-block bithiazole complex.

    3. Synthesis and Structure of Trisilane-1,3-diyl ansa Half-Sandwich Complexes of Group 6 Metals (pages 5383–5385)

      Holger Braunschweig, Rainer Dörfler, Kai Hammond, Jan Mies and Krzysztof Radacki

      Version of Record online: 27 OCT 2010 | DOI: 10.1002/ejic.201000965

      Thumbnail image of graphical abstract

      The synthesis and characterization of new silicon-bridged ansa half-sandwich complexes of molybdenum and tungsten are described. Furthermore, the synthesis of two new dinuclear half-sandwich complexes is presented.

  6. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Dinuclear Metal Complexes

      A Novel N(3),N(4)-Bridging Coordination Mode of 1-R-Tetrazole-5-thiolates – Synthesis, X-ray Diffraction, Magnetic Properties and Quantum-Chemical Study of a Macrocyclic Dinickel Complex Coligated by 1-Methyltetrazole-5-thiolate (pages 5387–5393)

      Sergei V. Voitekhovich, Ronny Syre, Jochen Lach, Vadim E. Matulis, Pavel N. Gaponik, Oleg A. Ivashkevich and Berthold Kersting

      Version of Record online: 21 OCT 2010 | DOI: 10.1002/ejic.201000735

      Thumbnail image of graphical abstract

      A novel N(3),N(4)-bridging coordination mode of 1-R-tetrazole-5-thiolates has been observed in the dinickel complex [Ni2L(μ-SCN4Me)]BPh4, where L represents a macrocyclic bis(triamine–thiophenolate) ligand.

    2. Distortional Isomerism

      Distortional Isomerism in Copper(II) Nitrato Complexes of N,N′,N″-Tris{[(para-nitrobenzyl)phenyl]aminoethyl}amine (pages 5394–5400)

      Ann Almesåker, Patrick Gamez, Janet L. Scott, Simon J. Teat, Jan Reedijk and Leone Spiccia

      Version of Record online: 27 OCT 2010 | DOI: 10.1002/ejic.201000824

      Thumbnail image of graphical abstract

      Two distortional isomers have been isolated from the reaction of Cu(NO3)2·3H2O with a triaryl derivative of the tripodal tris(aminoethyl)amine, whose distinctively different colours, green-yellow and dark green, most likely arise from a major difference in one of the Cu–N equatorial bond lengths.

    3. Cage Compounds

      Tris-Dioximate Cobalt(I,II,III) Clathrochelates: Stabilization of Different Oxidation and Spin States of an Encapsulated Metal Ion by Ribbed Functionalization (pages 5401–5415)

      Yan Z. Voloshin, Oleg A. Varzatskii, Valentin V. Novikov, Nataly G. Strizhakova, Ivan I. Vorontsov, Anna V. Vologzhanina, Konstantin A. Lyssenko, Galina V. Romanenko, Matvey V. Fedin, Victor I. Ovcharenko and Yurii N. Bubnov

      Version of Record online: 29 OCT 2010 | DOI: 10.1002/ejic.201000444

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      Hexachlorine-containing cobalt(II) clathrochelates were prepared by means of template condensation on a Co2+ matrix. Their nucleophilic substitution with thiolate anions and aliphatic amines gave cobalt(II,III) sulfide and amine mono- and bis-clathrochelates, whereas reduction led to the cobalt(I) complexes. Cobalt(II) clathrochelates undergo equation image [LEFT RIGHT ARROW] 3/2 spin transition and Jahn–Teller distortion.

    4. Borole Systems

      Synthetic, Structural, Photophysical and Computational Studies on π-Conjugated 1,3,2-Benzodiazaboroles with Carbazole Building Blocks (pages 5416–5425)

      Lothar Weber, Johannes Halama, Vanessa Werner, Kenny Hanke, Lena Böhling, Anna Chrostowska, Alain Dargelos, Małgorzata Maciejczyk, Anna-Lena Raza, Hans-Georg Stammler and Beate Neumann

      Version of Record online: 25 OCT 2010 | DOI: 10.1002/ejic.201000665

      Thumbnail image of graphical abstract

      Molecules comprising benzodiazaborole and carbazole units either directly linked by a B–N bond or connected through a thiophene spacer were synthesized from 2-bromoboroles and the corresponding lithium amide or lithium thienyl. The structures and photophysical properties were studied experimentally as well as by DFT.

    5. Functionalised N-Heterocyclic Carbenes

      Donor-Functionalised Expanded Ring N-Heterocyclic Carbenes: Highly Effective Ligands in Ir-Catalysed Transfer Hydrogenation (pages 5426–5431)

      Abeer Binobaid, Manuel Iglesias, Dirk Beetstra, Athanasia Dervisi, Ian Fallis and Kingsley J. Cavell

      Version of Record online: 22 OCT 2010 | DOI: 10.1002/ejic.201000680

      Thumbnail image of graphical abstract

      Performances of a number of RhI and IrI complexes of unsymmetrical o-methoxyphenyl donor-functionalised NHCs with differing carbene ring sizes were tested in catalytic transfer hydrogenation. RhI complexes displayed no activity. However, the corresponding IrI complexes were found to be extremely effective catalysts, exhibiting excellent turnover frequencies and catalyst stability.

    6. Chelated Gallium Complexes

      Formation and Characterization of Gallium(III) Complexes with Monoamide Derivatives of 1,4,7-Triazacyclononane-1,4,7-triacetic Acid: A Study of the Dependency of Structure on Reaction pH (pages 5432–5438)

      Dinesh Shetty, Soo Young Choi, Jae Min Jeong, Lathika Hoigebazar, Yun-Sang Lee, Dong Soo Lee, June-Key Chung, Myung Chul Lee and Young Keun Chung

      Version of Record online: 27 OCT 2010 | DOI: 10.1002/ejic.201000748

      Thumbnail image of graphical abstract

      Amide derivatives of 1,4,7-triazacyclononane-1,4,7-triacetic acid (NOTA) can make stable chelates with GaIII, the structure of which is dependent on the reaction pH. This novel method provides a tool fordesigning small bioactive molecules, as well as a means of conveniently binding NOTA derivatives to biomolecules without the need of an extra linker group.

    7. Anti-Tumour Complexes

      Kinetic Studies on the Reactions of Different Bifunctional Platinum(II) Complexes with Selected Nucleophiles (pages 5439–5445)

      Jovana Bogojeski, Živadin D. Bugarčić, Ralph Puchta and Rudi van Eldik

      Version of Record online: 26 OCT 2010 | DOI: 10.1002/ejic.201000654

      Thumbnail image of graphical abstract

      Substitution reactions of the complexes cis-[Pt(NH3)2Cl2], [Pt(SMC)Cl2], [Pt(en)Cl2] and [Pt(dach)Cl2] (SMC = S-methyl-L-cysteine, en = ethylenediamine, dach = 1,2-diaminocyclohexane) with L-histidine, guanosine-5′-monophosphate and 1,2,4-triazole, were studied at pH = 7.2 and 310 K by using UV/Vis spectrophotometry. [Pt(SMC)Cl2] turns out to be the mostlabile complex of the series.

    8. Chalcogenide Cluster–POM Hybrids

      New Cluster–Polyoxometalate Hybrids Derived from the Incorporation of {Mo3S4} and {Mo3CuS4} Units into {EW15} Cores (E = AsIII, SbIII, TeIV) (pages 5446–5454)

      Maxim N. Sokolov, Eugenia V. Peresypkina, Irina V. Kalinina, Alexander V. Virovets, Vladimir S. Korenev and Vladimir P. Fedin

      Version of Record online: 28 OCT 2010 | DOI: 10.1002/ejic.201000693

      Thumbnail image of graphical abstract

      A new family of hybrid chalcogenide cluster-incorporated polyoxometalates (POMs) have been prepared in which the POM standard building block {W3O4}10+ is replaced by the topologically similar chalcogenide cluster fragments {Mo3S4}4+, {Mo3S2O2}4+, and {Mo3CuS4}5+ withmetal–metal bonds.

    9. Modified Magnetic Nanoparticles

      (Carboxymethyl–Dextran)-Modified Magnetic Nanoparticles Conjugated to Octreotide for MRI Applications (pages 5455–5461)

      Guo-Cheng Han, Yang Ouyang, Xue-Ying Long, Yu Zhou, Meng Li, You-Nian Liu and Heinz-Bernhard Kraatz

      Version of Record online: 25 OCT 2010 | DOI: 10.1002/ejic.201000715

      Thumbnail image of graphical abstract

      HE staining results show that the peptide octreotide successfully conjugates to nanoparticles and is an efficient delivery vehicle to transport MNPs to the cytoplasm viaendocytosis. This endocytosis occurs through special recognition by the somatostatin receptor.

    10. Oxidation Catalysis

      Synthesis and Characterization of Oligonuclear Ru, Co and Cu Oxidation Catalysts (pages 5462–5470)

      Bao-Lin Lee, Markus D. Kärkäs, Eric V. Johnston, Andrew K. Inge, Lien-Hoa Tran, Yunhua Xu, Örjan Hansson, Xiaodong Zou and Björn Åkermark

      Version of Record online: 22 OCT 2010 | DOI: 10.1002/ejic.201000758

      Thumbnail image of graphical abstract

      Three new oligonuclear complexes, Ru2(bbpmp)(μ-OAc)3, [Co2(bbpmp)(μ-OAc)(μ-OMe)](PF6) and [Cu4(Hbbpmp)2(μ-OAc)(H2O)2](OAc)(PF6)2 {H3bbpmp = 2,6-bis[(2-hydroxybenzyl)-(2-pyridylmethyl)aminomethyl]-4-methylphenol}, have been synthesized and characterized. They were found to catalyze allylic oxidation and oxidation of alcohols and di-tBu-catechol.

    11. Phospha-Grignard Reagent

      Synthesis and Reactivity of the Phospha-Grignard Reagent Mg(P{SiMe3}2)Br(thf) (pages 5471–5477)

      Benjamin M. Day and Martyn P. Coles

      Version of Record online: 28 OCT 2010 | DOI: 10.1002/ejic.201000810

      Thumbnail image of graphical abstract

      {Me3Si}2PH reacts with MgMeBr to afford the magnesium phosphide Mg(P{SiMe3}2)X(thf) (X = Br/Me). Reaction with Cp2ZrCl2 demonstrates that this is an effective phosphide transfer reagent. In contrast, reaction with Cp2TiCl2 gives reduced TiIII species. A hexametallic example, [Cp2TiMg2X5(thf)3]2 (X = Cl/Br), has been structurally determined, containing an “Mg4X10” core capped by “Cp2Ti” units.

    12. Polycatenation Networks

      Three New Polycatenation Networks Based on 4,4′-Oxybis(benzoate) and Bis(imidazole) Ligands: Synthesis, Structure and Photoluminescence (pages 5478–5483)

      Yun Xu, Pang-Kuan Chen, Yun-Xia Che and Ji-Min Zheng

      Version of Record online: 25 OCT 2010 | DOI: 10.1002/ejic.201000832

      Thumbnail image of graphical abstract

      Three new polycatenation networks have been prepared. Interestingly, compound 1 represents a rare 1D [RIGHTWARDS ARROW] 2D polycatenation formed by the catenation of 1D ladders and compounds 2 and 3 are uncommon 2D [RIGHTWARDS ARROW] 3D frameworks formed by parallel polycatenation of 2D (4,4) sheets.

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