European Journal of Inorganic Chemistry

Cover image for Vol. 2010 Issue 35

December 2010

Volume 2010, Issue 35

Pages 5491–5596

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
    1. Graphical Abstract: Eur. J. Inorg. Chem. 35/2010 (pages 5491–5495)

      Article first published online: 1 DEC 2010 | DOI: 10.1002/ejic.201090108

  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
  4. Short Communication

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
    1. Sb–N Heterocycles

      Synthesis and Characterization of 1,3-Dihalogeno-2,4-bis(2,4,6-tri-tert-butylphenyl)-cyclo-1,3-distiba-2,4-diazanes, [X–Sb(μ-NR)]2 (X = F, Cl, Br, and I) (pages 5501–5508)

      Mathias Lehmann, Axel Schulz and Alexander Villinger

      Article first published online: 3 NOV 2010 | DOI: 10.1002/ejic.201000885

      Thumbnail image of graphical abstract

      The whole halogen series of supermesityl-substituted cyclo-distiba-diazanes has been synthesized and fully characterized for the first time.

  5. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
    1. Ru–Anthracene Donor–Acceptors

      Supramolecular and Intramolecular Energy Transfer with Ruthenium–Anthracene Donor–Acceptor Couples: Salt Bridge versus Covalent Bond (pages 5509–5516)

      Jonathan C. Freys and Oliver S. Wenger

      Article first published online: 4 NOV 2010 | DOI: 10.1002/ejic.201000815

      Thumbnail image of graphical abstract

      A ruthenium(II) biimidazole complex forms closely interacting cation–anion adducts with anthracene-9-carboxylate. Energy transfer within these adducts and a covalent donor-bridge-acceptor system is compared.

    2. Mixed-Valent Keggin Polyoxometalates

      Design of Tri-Substituted Dodecatungstosilicate from a Trilacunary Silicotungstate by Insertion of Manganese Ions of [Mn33-O)(2-Cl-benzoato)6(py)3]: Synthesis, Structure, Redox and Magnetic Studies (pages 5517–5522)

      Daipayan Dutta, Atish D. Jana, Mainak Debnath, Golam Mostafa, Rodolphe Clérac, Javier G. Tojal and Mahammad Ali

      Article first published online: 5 NOV 2010 | DOI: 10.1002/ejic.201000603

      Thumbnail image of graphical abstract

      A Keggin polyoxometalate α-[MnIIMnIII2(H2O)3SiW9O37]8– (3) has been designed by insertion of three Mn atoms from [MnIIMnIII23-O)(2-Cl-benzoato)6(py)3] (1) into the vacant sites of Na10[A-α-SiW9O34] (2). Compound 3 exhibits antiferromagnetic interaction between the Mn centres, which leads to an S = 5/2 ground state.

    3. Rhenium Dithioalkyne Cyclization

      Facile Formation of a Rhenium Allenylcarbene Complex with an Internal Dithioalkyne (pages 5523–5528)

      Wolfram W. Seidel, Matthias J. Meel, David Schallenberg, Tania Pape, Alexander Villinger and Dirk Michalik

      Article first published online: 2 NOV 2010 | DOI: 10.1002/ejic.201000370

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      Allenylcarbene complexes are potentialalkyne oligomerization intermediates. A surprisingly facile synthesis of this complex type with an internal dithioalkyne and the plain [(C5H5)ReBr2] fragment by a concerted rearrangement cycloaddition reaction is reported.

    4. Organoborate Ligands

      Coordination Properties of Organoborate Ligands – Steric Hindrance Around the Distal Boron Center Directs the Conformation of the Dialkylbis(imidazolyl)borate Scaffold (pages 5529–5537)

      Shiro Hikichi, Koyu Fujita, Yoshitaka Manabe, Munetaka Akita, Jun Nakazawa and Hidehito Komatsuzaki

      Article first published online: 29 OCT 2010 | DOI: 10.1002/ejic.201000629

      Thumbnail image of graphical abstract

      The configuration of the functional groups attached to the boron atom in the organoborate ligands, Lalkyl, is controlled by steric congestion around the boron center. Sterically enforced anagostic C–H···M interactions are observed in [NiII(Lalkyl)2], where alkyl = Me and nBu. In the mixed-ligand complexes [NiII(LX)(TpiPr2)], steric hindrance around the metal center also affects the structure of the dialkylbis(imidazolyl)borate scaffold.

    5. BN Hollow Microspheres

      Novel BN Hollow Microspheres with Open Mouths – Facile Synthesis, Growth Mechanism, Resonant Raman Scattering Effect, and Cathodoluminescence Performance (pages 5538–5544)

      Guangwu Wen, Bo Zhong, Xiaoxiao Huang, Hongming Yu, Xiaodong Zhang, Tao Zhang and Hongwei Bai

      Article first published online: 29 OCT 2010 | DOI: 10.1002/ejic.201000703

      Thumbnail image of graphical abstract

      Novel BN hollow microspheres with open mouths have been fabricated. The unique open-mouth feature makes them potential candidates as microreactors. They show excellent cathodoluminescence performance in the region of 200–400 nm and could be used as compact ultraviolet laser emitters. Moreover, they exhibit an unexpectedRaman scattering effect.

    6. Coordination Polymers

      Structural Investigation of Coordination Polymers Constructed from a Conformational Bis-triazole Ligand and V-Shaped Bridging Carboxylate Anions: Hydrothermal Syntheses, Crystal Structures, and Property Studies (pages 5545–5555)

      Chen Ren, Ping Liu, Yao-Yu Wang, Wen-Huan Huang and Qi-Zhen Shi

      Article first published online: 4 NOV 2010 | DOI: 10.1002/ejic.201000731

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      This work reports on the synthesis and characterization of seven new coordination polymers containing a conformational bis-triazole ligand. The long flexible btmb ligand displays cis and anti conformational features. The thermogravimetric analysis of these polymers indicates striking thermostability.

    7. Picolyl Carbene Catalysts

      Bulky Picolyl Substituted NHC Ligands and Their Pd0 Complexes (pages 5556–5562)

      Stefan Warsink, Carien M. S. van Aubel, Jan J. Weigand, Shiuh-Tzung Liu and Cornelis J. Elsevier

      Article first published online: 26 OCT 2010 | DOI: 10.1002/ejic.201000768

      Thumbnail image of graphical abstract

      The use of differently substituted secondary picolyl donors on NHC ligands leads to stable palladium(0) complexes. The complexes are active precatalysts for the selective transfer semihydrogenation of alkynes to Z-alkenes.

    8. Iron(III) Spin Crossover Complex

      [FeIII(bztpen)(OCH3)](PF6)2: Stable Methoxide–Iron(III) Complex Exhibiting Spin Crossover Behavior in the Solid State (pages 5563–5567)

      Norma A. Ortega-Villar, M. Carmen Muñoz and José A. Real

      Article first published online: 5 NOV 2010 | DOI: 10.1002/ejic.201000791

      Thumbnail image of graphical abstract

      Magnetic studies, EPR spectroscopy, and single-crystal X-ray diffraction analysis demonstrate that complex [FeIII(bztpen)(OCH3)](PF6)2 (1) undergoes solid-state spin crossover (SCO) behavior in the temperature range 300–50 K. This result supports the observation of SCO in solution in related biomimetic iron(III) complexes.

    9. Asymmetric Sulfoxidation

      Titanium(IV)–Salan Catalysts for Asymmetric Sulfoxidation with Hydrogen Peroxide (pages 5568–5578)

      Pedro Adão, Fernando Avecilla, Marcella Bonchio, Mauro Carraro, João Costa Pessoa and Isabel Correia

      Article first published online: 2 NOV 2010 | DOI: 10.1002/ejic.201000792

      Thumbnail image of graphical abstract

      The solution and solid-phase characterization of several titanium(IV)–salan complexes is reported. The Ti–salan complexes were tested as catalysts in the benchmark oxidation of thioanisole with several oxidants in organic solvents and ionic liquids. The best catalyst bears no substituents on the aromatic groups and tert-butyl hydroperoxide is the most suitable oxidant for use in ILs.

    10. Lanthanide Alkoxide Clusters

      Synthesis and Crystal Structure of Novel Biheterometal and Triheterometal Alkoxide Clusters – Highly Active Catalysts for the Polymerization of ϵ-Caprolactone (pages 5579–5586)

      Hongting Sheng, Yan Feng, Yong Zhang and Qi Shen

      Article first published online: 5 NOV 2010 | DOI: 10.1002/ejic.201000831

      Thumbnail image of graphical abstract

      Five lanthanide–potassium and lanthanide–potassium–sodium heterometal alkoxide clusters were synthesized in highyield. These clusters exhibited good catalytic activity for the ring-opening polymerization of ϵ-caprolactone. The catalytic activity was found to depends on the ratio of alkali metal to lanthanide metal as well as the ratio of potassium to sodium.

    11. Phyllosilicate Hybrids

      Mg Environments in the Octahedral Sheet of 2:1 Talc-Like Hybrid Phyllosilicates: A Comparative XAFS Study (pages 5587–5591)

      Jocelyne Miehé-Brendlé, Marie-Hélène Tuilier, Claire Marichal, Jean-Christophe Gallego and Marc Reinholdt

      Article first published online: 3 NOV 2010 | DOI: 10.1002/ejic.201000221

      Thumbnail image of graphical abstract

      The electronic and atomic structures of sixfold Mg cations within the frame of synthesized phyllosilicates and organophyllosilicates are investigated by using X-ray absorption spectroscopy as a selective local probe. The stability of the octahedral sheet, which is much less affected by the presence of organic moieties than the tetrahedral one, could be due to the strong overlap of Mg orbitals.

    12. Metal-Organic Polymers

      Construction of Metal-Organic Frameworks with the Pyridine-3,5-dicarboxylate Anion and Bis(imidazole) Ligands: Synthesis, Structure, and Thermostability Studies (pages 5592–5596)

      Yanyan Lv, Yan Qi, Lixin Sun, Feng Luo, Yunxia Che and Jimin Zheng

      Article first published online: 27 OCT 2010 | DOI: 10.1002/ejic.201000402

      Thumbnail image of graphical abstract

      Three complexes, which self-assembled from the metal ions, pyridine-3,5-dicarboxylic acid, and the bis(imidazole) ligands, show desirable structural features that depend on both the coordination modes of the 3,5-pdc2– anions and the various configurations of the N-donor ligands.

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