European Journal of Inorganic Chemistry

Cover image for Vol. 2010 Issue 36

December 2010

Volume 2010, Issue 36

Pages 5603–5727

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
    1. New Chlorido(dimethyl sulfoxide)iridium(III) Complexes with N6-Substituted Adenines – Kinetic N(7) versus Thermodynamic N(9) Coordinated Adenine Isomers (Eur. J. Inorg. Chem. 36/2010)

      Angel García-Raso, Juan J. Fiol, Francisca M. Albertí, Yolanda Lagos, Marta Torres, Miquel Barceló-Oliver, María J. Prieto, Virtudes Moreno, Ignasi Mata, Elies Molins, Carolina Estarellas, Antonio Frontera, David Quiñonero and Pere M. Deyà

      Version of Record online: 10 DEC 2010 | DOI: 10.1002/ejic.201090109

  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
  4. Short Communication

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
    1. Mixed Valency

      Structural and Spectroscopic Evidence of Strong Electronic Delocalization through a Cyanido Bridge in a Mixed-Valence Os–Ru Complex (pages 5613–5616)

      Melina B. Rossi, Khalil A. Abboud, Pablo Alborés and Luis M. Baraldo

      Version of Record online: 22 NOV 2010 | DOI: 10.1002/ejic.201000912

      Thumbnail image of graphical abstract

      Matching the energy of metal fragments bonded by a cyanido bridge results in asystem that is better described as having partial RuII/III and OsII/III character as evidenced by its structure and its spectroscopic analysis.

  5. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communication
    6. Full Papers
    1. Adenine–Iridium Complexes

      New Chlorido(dimethyl sulfoxide)iridium(III) Complexes with N6-Substituted Adenines – Kinetic N(7) versus Thermodynamic N(9) Coordinated Adenine Isomers (pages 5617–5628)

      Angel García-Raso, Juan J. Fiol, Francisca M. Albertí, Yolanda Lagos, Marta Torres, Miquel Barceló-Oliver, María J. Prieto, Virtudes Moreno, Ignasi Mata, Elies Molins, Carolina Estarellas, Antonio Frontera, David Quiñonero and Pere M. Deyà

      Version of Record online: 12 NOV 2010 | DOI: 10.1002/ejic.201000821

      Thumbnail image of graphical abstract

      New chlorido(dimethyl sulfoxide)iridium(III) complexes with N6-substituted adenine derivatives, [IrIIICl4(DMSO-κS){H-AdeCx–κN(7)}]·and [IrIIICl4(DMSO-κS){H-AdeCx–κN(9)}], were synthesized and characterized. The kinetic/thermodynamic mechanisms yielding the different coordination products were studied by DFT. Their interaction with plasmid pBR322 DNA was studied by electrophoretic mobility and AFM.

    2. TiAs Thin Films

      Atmospheric Pressure Chemical Vapour Deposition of TiCl4 and tBuAsH2 to Form Titanium Arsenide Thin Films (pages 5629–5634)

      Tegan Thomas, Christopher S. Blackman, Ivan P. Parkin and Claire J. Carmalt

      Version of Record online: 4 NOV 2010 | DOI: 10.1002/ejic.201000839

      Thumbnail image of graphical abstract

      Atmospheric-pressure chemical vapour deposition of TiCl4 and tBuAsH2 using substrate temperatures between 450 and 550 °C resulted in the deposition of TiAs thin films. The film depositions, compositions and properties have been investigated.

    3. Magnetite Octahedra

      Uniform Fe3O4 Octahedra with Tunable Edge Length – Synthesis by a Facile Polyol Route and Magnetic Properties (pages 5635–5639)

      Lijun Zhao and LianFeng Duan

      Version of Record online: 22 NOV 2010 | DOI: 10.1002/ejic.201000580

      Thumbnail image of graphical abstract

      Fe3O4 octahedra having tunable size, sharp edge length distribution, and uniform shape were prepared by a polyol route. The influence of the dose of N2H4·H2O on size and shape was investigated. Fe3O4 octahedra with edge length in the range 70–1000 nm were synthesized. Interestingly, it is not the edge length but the angles of the octahedra that have the greatest effect on the magnetic properties.

    4. Organolithium Chemistry

      α-Lithiated (R,R)-TMCDA as an Efficient Building Block for the Preparation of Chiral N,N,O Ligands by Asymmetric 1,2-Addition (pages 5640–5649)

      Viktoria H. Gessner, Benjamin Fröhlich and Carsten Strohmann

      Version of Record online: 17 NOV 2010 | DOI: 10.1002/ejic.201000631

      Thumbnail image of graphical abstract

      (R,R)-TMCDA and its racemic mixture can be directly deprotonated at its methyl group. With 2 equiv. of the deprotonation reagent a mixed aggregate 8 of the lithiated amine 7 and tBuLi was formed. By addition of α-lithiated (R,R)-TMCDA onto carbonyl compounds a series of novel N,N,O ligands of type 4 with different substituents and a further stereocentre are accessible.

    5. Titanium–Oxo Clusters

      Ti8O8(OOCR)16, a New Family of Titanium–Oxo Clusters: Potential NBUs for Reticular Chemistry (pages 5650–5659)

      Théo Frot, Sébastien Cochet, Guillaume Laurent, Capucine Sassoye, Michael Popall, Clément Sanchez and Laurence Rozes

      Version of Record online: 17 NOV 2010 | DOI: 10.1002/ejic.201000807

      Thumbnail image of graphical abstract

      New titanium–oxo clusters have been synthesized. The clusters [Ti8O8(OOCR)16], consisting of an octameric oxo core surrounded by 16 carboxylate ligands, are obtained under solvothermal conditions inhigh yields. For the first time, the ability of these nanoobjects to be post-modified by other organic acids with the preservation of the octameric oxo core is demonstrated.

    6. Mixed-Aldol Condensation

      Di(2-pyridyl) Ketone Complexes of CuI- and CuII-Containing Iodide and Thiocyanate Ligands: An Unusual Case of a Mixed-Aldol Condensation (pages 5660–5667)

      Katherine B. Szpakolski, Kay Latham, Colin J. Rix and Jonathan M. White

      Version of Record online: 12 NOV 2010 | DOI: 10.1002/ejic.201000860

      Thumbnail image of graphical abstract

      The conversion of a CuI polymer to a CuII dimer incorporating a transition-metal-promoted mixed-aldol condensation.

    7. Molybdenum Cluster Compounds

      Solvent-Dependent cis/trans Isomerism at the Paddlewheel Mo2 Core of Linear Tetranuclear Clusters of MoII and CuI Supported by 6-(Diphenylphosphanyl)pyridin-2-olate (pyphos) (pages 5668–5674)

      Kuntal Pal, Keisuke Nakao and Kazushi Mashima

      Version of Record online: 22 NOV 2010 | DOI: 10.1002/ejic.201000896

      Thumbnail image of graphical abstract

      We have demonstrated the solvent-dependent synthesis and structural characterization of cis and trans isomers of linear tetranuclear clusters [Mo2{Cu(CH3CN)2}2(pyphos)4]2+ (pyphos = 6-diphenylphosphanyl-2-pyridonato). The trans isomer was readily converted into its cis isomer by an intramolecular rearrangement of the paddle-wheel Mo2 core upon dissolution in a coordinating solvent such as acetonitrile.

    8. Silane Hydrolysis

      Nonclassical Ruthenium Silyl Dihydride Complexes TpRu(PPh3)(η3-HSiR3H) [Tp = Hydridotris(pyrazolyl)borate]: Catalytic Hydrolytic Oxidation of Organosilanes to Silanols with TpRu(PPh3)(η3-HSiR3H) (pages 5675–5684)

      Ting Yan Lee, Li Dang, Zhongyuan Zhou, Chi Hung Yeung, Zhenyang Lin and Chak Po Lau

      Version of Record online: 9 NOV 2010 | DOI: 10.1002/ejic.201000951

      Thumbnail image of graphical abstract

      An X-ray crystallographic study showed that the previously reported complexes TpRu(PPh3)(Ha)(η2-HbSiR3) and TpRu(PPh3)(Hb)(η2-HaSiR3) should be formulated as TpRu(PPh3)(η3-HSiR3H), a structure containing a hypervalent Si center. One of these complexes was used for the catalytic hydrolytic oxidation of organosilanes to silanols. A mechanism, supported by theoretical calculation, is proposed.

    9. Rare Earth Oxysulfides and -selenides

      Synthesis and Characterization of Hierarchically Structured La2O2M@C:Eu3+ (M = S, Se) Microflowers by a Single-Step RAPET Method (pages 5685–5690)

      Ramakrishnan Kalai Selvan and Aharon Gedanken

      Version of Record online: 12 NOV 2010 | DOI: 10.1002/ejic.201000632

      Thumbnail image of graphical abstract

      Hierarchically structured La2O2M@C:Eu3+(M = S, Se) microflowers have been successfully prepared by a facile one-pot synthesis at a low temperature of 950 °C by the RAPET technique. The structural (XRD, Raman), morphological (HRSEM, TEM and HRTEM) and optical (UV/Vis) properties of the materials have been studied.

    10. Organotin and -lead Thiocarboxylates

      Synthesis and Structural Studies of Organotin(IV) and Organolead(IV) Thiophene-2-thiocarboxylate (pages 5691–5699)

      Suryabhan Singh, Subrato Bhattacharya and Heinrich Nöth

      Version of Record online: 12 NOV 2010 | DOI: 10.1002/ejic.201000692

      Thumbnail image of graphical abstract

      Organotin ([R2SnCl2], [R3SnCl]; R = Me, Ph, nPr, and nBu) and organolead ([Ph2PbCl2], [Ph3PbCl]) compounds that contain the thiophene-2-thiocarboxylate ligand have been synthesized and characterized by spectral and crystallographic studies. Structures and electronic transitions have been explained on the basis of DFT calculations.

    11. Hierarchical Lead Sulfide

      Flowerlike PbS Microcrystals: Citric Acid Assisted Synthesis, Shape Evolution, and Electrical Conductivities (pages 5700–5708)

      Rencheng Jin, Gang Chen, Qun Wang, Jian Pei, Gang Wang and Lin Wang

      Version of Record online: 12 NOV 2010 | DOI: 10.1002/ejic.201000725

      Thumbnail image of graphical abstract

      Flowerlike PbS has been synthesized by means of a simple solution route, whichshows a higher electrical conductivity relative to other morphologies.

    12. Zinc Coordination Polymers

      Syntheses, Structures and Properties of a Series of ZnII Complexes Constructed from a Tetrakis(imidazole) Ligand and Various Anions (pages 5709–5717)

      Hong-Ye Bai, Jian-Fang Ma, Jin Yang, Bo Liu, Lai-Ping Zhang, Ji-Cheng Ma and Ying-Ying Liu

      Version of Record online: 12 NOV 2010 | DOI: 10.1002/ejic.201000766

      Thumbnail image of graphical abstract

      Six ZnII containing coordination polymers based on tetrakis(imidazol-1-ylmethyl)methane and different anions have been synthesized successfully under hydrothermal conditions. The thermal and photoluminescent properties of the complexes were also investigated.

    13. Oxidorhenium(V) Complexes

      Oxidorhenium(V) Complexes with Tridentate and Tetradentate Phenol-Based Ligands (pages 5718–5727)

      Pedro Traar, Albert Schröckeneder, Martina E. Judmaier, Ferdinand Belaj, Judith Baumgartner, Anna Sachse and Nadia C. Mösch-Zanetti

      Version of Record online: 18 NOV 2010 | DOI: 10.1002/ejic.201000771

      Thumbnail image of graphical abstract

      Oxidorhenium(V) complexes of the type [ReOX2L] (X = Cl, Br) that contain tridentate and tetradentate phenolate-based ligands were prepared and tested for their catalytic activity in epoxidation reactions.

SEARCH

SEARCH BY CITATION