European Journal of Inorganic Chemistry

Cover image for Vol. 2010 Issue 14

May 2010

Volume 2010, Issue 14

Pages 2063–2201

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    7. Correction
    1. Light Switches the Ligand! Photochromic Azobenzene–Phosphanes (Eur. J. Inorg. Chem. 14/2010) (page 2063)

      Maria Dolores Segarra-Maset, Piet W. N. M. van Leeuwen and Zoraida Freixa

      Version of Record online: 30 APR 2010 | DOI: 10.1002/ejic.201090037

  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    7. Correction
  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    7. Correction
  4. Short Communications

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    7. Correction
    1. Switchable Phosphane Ligands

      Light Switches the Ligand! Photochromic Azobenzene–Phosphanes (pages 2075–2078)

      Maria Dolores Segarra-Maset, Piet W. N. M. van Leeuwen and Zoraida Freixa

      Version of Record online: 8 APR 2010 | DOI: 10.1002/ejic.201000063

      Thumbnail image of graphical abstract

      Light can bring about steric changes in azobenzene–phosphane ligands in platinum complexes, and notably the photo-processes are not quenched by the metal atom.

    2. Carbonate Shortage in LDHs

      Origin of CO32– Shortage in MgAl Layered Double Hydroxides with Mg/Al < 2 (pages 2079–2083)

      Shulan Ma, Cuihong Fan, Gailing Huang, Yumei Li, Xiaojing Yang and Kenta Ooi

      Version of Record online: 12 APR 2010 | DOI: 10.1002/ejic.201000010

      Thumbnail image of graphical abstract

      A “substitution–filling” model based on the gibbsite-like layer with octahedral vacancies is proposed to explain the carbonate shortage (CO32–/Al < 0.5) in Al-rich MgAl layered double hydroxides synthesized by the urea hydrolysis method.

    3. Symmetrical Silver Nanoclusters

      Bromide-Induced Formation of a Highly Symmetric Silver Thiolate Cluster Containing 36 Silver Atoms from an Infinite Polymeric Silver Thiolate (pages 2084–2087)

      Xiaomin Liu, Huayan Yang, Nanfeng Zheng and Lansun Zheng

      Version of Record online: 13 APR 2010 | DOI: 10.1002/ejic.200900668

      Thumbnail image of graphical abstract

      When silver reacts with thiolates, it tends to produce polymeric complexes. With the help of Br, a high-nuclearity [Br@Ag36(SC6H4tBu-4)36] nanocluster was successfully prepared from a polymeric silverthiolate complex.

  5. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    7. Correction
    1. Multinuclear Sandwiches

      Systematic Structural Coordination Chemistry of p-tert-Butyltetrathiacalix[4]arene: Main Group Metal Complexes Other Than Those of Group 1 (pages 2089–2105)

      Alexander Bilyk, John W. Dunlop, Annegret K. Hall, Jack M. Harrowfield, M. Wais Hosseini, George A. Koutsantonis, Brian W. Skelton and Allan H. White

      Version of Record online: 24 MAR 2010 | DOI: 10.1002/ejic.200901069

      Thumbnail image of graphical abstract

      p-tert-Butyltetrathiacalix[4]arene forms complexes with metal ions from groups 2, 13 and 14 with mononuclear, dinuclear or tetranuclear forms depending upon both the metal ion and the method of crystallisation of the complex: BaII, for example, provides both mononuclear complexes and a novel tetranuclear species, the latter entrapping a carbonate ion.

    2. Paramagnetic Clusters

      Systematic Structural Coordination Chemistry of p-tert-Butyltetrathiacalix[4]arene: Further Complexes of Transition-Metal Ions (pages 2106–02126)

      Alexander Bilyk, John W. Dunlop, Rebecca O. Fuller, Annegret K. Hall, Jack M. Harrowfield, M. Wais Hosseini, George A. Koutsantonis, Ian W. Murray, Brian W. Skelton, Robert L. Stamps and Allan H. White

      Version of Record online: 8 APR 2010 | DOI: 10.1002/ejic.200901071

      Thumbnail image of graphical abstract

      Complexes formed by a variety of transition-metal ions with p-tert-butyltetrathiacalix[4]arene show a remarkable range of structures and nuclearity: a hydroxo-cluster involving NiII, for example, containing 32 metal ions enrobed by six thiacalixarene units disposed in an octahedral array.

    3. Lanthanide Aggregates

      Systematic Structural Coordination Chemistry of p-tert-Butyltetrathiacalix[4]arene: Further Complexes of Lanthanide Metal Ions (pages 2127–2152)

      Alexander Bilyk, John W. Dunlop, Rebecca O. Fuller, Annegret K. Hall, Jack M. Harrowfield, M. Wais Hosseini, George A. Koutsantonis, Ian W. Murray, Brian W. Skelton, Alexandre N. Sobolev, Robert L. Stamps and Allan H. White

      Version of Record online: 13 APR 2010 | DOI: 10.1002/ejic.200901070

      Thumbnail image of graphical abstract

      Complexes of lanthanide(III) ions with p-tert-butyltetrathiacalix[4]arene show forms that depend both on the particular lanthanide ion and a variety of subtle factors, probably including kinetic effects. Typically, the structures involve a sandwich-like array of calixarene units incorporating three or four metal ions, although EuIII, in particular, shows a remarkable variety in its complexes.

    4. Pentaorganostannates

      Formation of Pentaorganostannates from Bis(2-bromo-2′-biphenyl)stannanes and tert-Butyllithium upon Substitution of Alkyl and Aryl Groups on Tin Atoms (pages 2153–2157)

      Masaichi Saito, Sanae Imaizumi and Tomoyuki Tajima

      Version of Record online: 9 APR 2010 | DOI: 10.1002/ejic.201000089

      Thumbnail image of graphical abstract

      The reaction of bis(2-bromo-2′-biphenyl)stannanes 1 with tert-butyllithium in the presence of diaryl- and dialkyldichlorostannanes leads to the extrusion of aryl and alkyl groups on the tin atom, affording9-stannafluorene derivatives bearing biphenyl groups. The intermediates of the reactions were assigned to the corresponding pentaorganostannates, which were characterized by NMR spectroscopy.

    5. Rhodium Thiolato Oligomers

      MS-TOF Study of the Formation of Thiolato-Bridged Rhodium Oligomers (pages 2158–2164)

      Josée Boudreau, Jérôme Grenier-Desbiens and Frédéric-Georges Fontaine

      Version of Record online: 8 APR 2010 | DOI: 10.1002/ejic.200901201

      Thumbnail image of graphical abstract

      Ligand exchange and coordination studies were done on the dinuclear thiolato-briged complex [Cp*Rh(μ-SPh)3RhCp*]Cl. Oligomeric materials of the general formula[Cp*Rh(μ-SPh)x(μ-Cl)3–x{Rh(μ-SPh)3}nRhCp*] (x = 1 to 3; n = 1 to 4) were formed by insertion of [Rh(SPh)3] units when the bridging coordination mode of the thiophenolato ligands was altered.

    6. Dye-Sensitized Solar Cells

      Formation of Silica Nanolayers on ZnO Electrodes in Dye-Sensitized Solar Cells (pages 2165–2171)

      Shintaro Ueno and Shinobu Fujihara

      Version of Record online: 8 APR 2010 | DOI: 10.1002/ejic.200901205

      Thumbnail image of graphical abstract

      Silica nanolayers were coated on ZnO electrodes by a simple sol–gel transformation under precise control of the coating methods, coating periods, and solution composition. The open-circuit photovoltage of dye-sensitized solar cells can be substantially enhanced by using SiO2-coated ZnO electrodes.

    7. Luminescent Ionic Liquid

      A Luminescent Ionic Liquid Crystal: [C12mim]4[EuBr6]Br (pages 2172–02177)

      Anna Getsis, Sifu Tang and Anja-Verena Mudring

      Version of Record online: 10 MAR 2010 | DOI: 10.1002/ejic.200901220

      Thumbnail image of graphical abstract

      [C12mim]4[EuBr6]Br in the temperature range of –3 to 98 °C adopts a smectic liquid crystal phase. At 77 K it shows a strong red emission with a lifetime of about 2.6 ms. The quantum efficiency of emission is about 0.45.

    8. Sulfur Diimide Grignards

      Magnesium Diimidosulfinates – Conformational Studies in the Solid State and in Solution (pages 2178–2184)

      Thomas Schulz, Stephan Deuerlein and Dietmar Stalke

      Version of Record online: 7 APR 2010 | DOI: 10.1002/ejic.201000045

      Thumbnail image of graphical abstract

      Sulfur diimides react readily with different Grignard reagents to form highly pure magnesium diimidosulfinates in excellent yields. These diimidosulfinates have been studied in solution and in the solid state.

    9. Sulfur Triimide Grignards

      Magnesium Triimidosulfonates from Grignard Reagents (pages 2185–2192)

      Thomas Schulz and Dietmar Stalke

      Version of Record online: 7 APR 2010 | DOI: 10.1002/ejic.201000046

      Thumbnail image of graphical abstract

      In contrast to bulky organolithium complexes, the sulfur triimide S(NtBu)3 reacts readily with Grignard reagentss to form magnesium triimidosulfonates with a third pendent imido group in an ideal position to coordinate a second metal. The conformation of these novel Mg complexes is studied in the solid state and in solution.

    10. Lanthanide Salicylaldimines

      Self-Assembled Lanthanide Salicylaldimines with a Unique Coordination Mode (pages 2193–2200)

      Małgorzata T. Kaczmarek, Maciej Kubicki, Anna Mondry, Rafał Janicki and Wanda Radecka-Paryzek

      Version of Record online: 31 MAR 2010 | DOI: 10.1002/ejic.200901083

      Thumbnail image of graphical abstract

      The monodentate O donor coordination behavior of a neutral salen-type ligand is documented in lanthanide salicylaldimine complexes formed in situ from aldehyde and diamine precursors. The lanthanide ions serve as templating and organizing centers for the construction of complex species that act as hosts for an additional salicylaldimine guest, stabilizing the overall self-assembled supramolecular network.

  6. Correction

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    7. Correction
    1. You have free access to this content
      Correction: Chemistry and Physical Properties of the Phosphide Telluride Zr2PTe2 (page 2201)

      Kristina Tschulik, Michael Ruck, Michael Binnewies, Edgar Milke, Stefan Hoffmann, Walter Schnelle, Boniface P. T. Fokwa, Michael Gilleßen and Peer Schmidt

      Version of Record online: 13 APR 2010 | DOI: 10.1002/ejic.201000335

      This article corrects:

      Chemistry and Physical Properties of the Phosphide Telluride Zr2PTe21

      Vol. 2009, Issue 21, 3102–3110, Version of Record online: 17 JUN 2009

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