European Journal of Inorganic Chemistry

Cover image for Vol. 2010 Issue 3

January 2010

Volume 2010, Issue 3

Pages 339–489

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    1. Ordering Phenomena in Complex Chalcogenides – the Showcase of A2In12Q19 (A = K, Tl, NH4; Q = Se, Te) and Pseudobinary In2Q3 (Eur. J. Inorg. Chem. 3/2010) (page 339)

      Lorenz Kienle, Marc Schlosser, Manolis J. Manos, Christos D. Malliakas, Viola Duppel, Christof Reiner, Hans-Jörg Deiseroth, Mercouri G. Kanatzidis, Klemens Kelm and Arndt Simon

      Article first published online: 12 JAN 2010 | DOI: 10.1002/ejic.201090003

  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    1. Graphical Abstract: Eur. J. Inorg. Chem. 3/2010 (pages 339–344)

      Article first published online: 12 JAN 2010 | DOI: 10.1002/ejic.201090005

  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
  4. Short Communications

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    1. Hydroxylase Mechanism

      Water Dissociation and Dioxygen Binding in Phenylalanine Hydroxylase (pages 351–356)

      Elaine Olsson, Aurora Martinez, Knut Teigen and Vidar R. Jensen

      Article first published online: 14 DEC 2009 | DOI: 10.1002/ejic.200900489

      Thumbnail image of graphical abstract

      A density-functional theory study of the pterin-dependent non-heme iron(II) enzyme phenylalanine hydroxylase shows that dissociation of the initial ligating water molecules and the subsequent binding ofO2 to form a water-free, catalytic iron–O2 complex is facile and accompanied by entrance of the tetrahydrobiopterin (BH4) cofactor into the first coordination sphere of iron.

    2. Hollow Nanostructures

      Generation of Hollow MnSiO3 Nanostructures through the Solid-State Reaction of Mn3O4 and Pd/PdO Nanocrystals Dimensionally Confined within Nanosized Silica Spheres (pages 357–360)

      Jongmin Shin, Tae-Lin Ha and In Su Lee

      Article first published online: 17 DEC 2009 | DOI: 10.1002/ejic.200900946

      Thumbnail image of graphical abstract

      In the course of annealing Mn3O4 and Pd/PdO nanocrystals co-encapsulated within a nanosized silica sphere under the reducing environment, the Mn3O4 nanocrystals werereduced and transformed into a hollow MnSiO3 nanostructure through a process facilitated by the adjacent Pd nanocrystals.

    3. A Diamidocarbene Ligand

      Reprogramming of a Malonic N-Heterocyclic Carbene: A Simple Backbone Modification with Dramatic Consequences on the Ligand's Donor Properties (pages 361–365)

      Vincent César, Noël Lugan and Guy Lavigne

      Article first published online: 17 DEC 2009 | DOI: 10.1002/ejic.200901113

      Thumbnail image of graphical abstract

      The formal introduction of a second substituent on the malonate unit of the NHC ligand A blocks the electronic communication between backbone atoms, thereby inducing a reorganization of the electron distribution within the heterocycle. The resulting diamidocarbene B exhibits significantly reduced donor properties, but can still be complexed with transition metal ions as illustrated here for the case of rhodium.

  5. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    1. Complex Chalcogenides

      Ordering Phenomena in Complex Chalcogenides – the Showcase of A2In12Q19 (A = K, Tl, NH4; Q = Se, Te) and Pseudobinary In2Q3 (pages 367–378)

      Lorenz Kienle, Marc Schlosser, Manolis J. Manos, Christos D. Malliakas, Viola Duppel, Christof Reiner, Hans-Jörg Deiseroth, Mercouri G. Kanatzidis, Klemens Kelm and Arndt Simon

      Article first published online: 5 OCT 2009 | DOI: 10.1002/ejic.200900721

      Thumbnail image of graphical abstract

      From order to disorder and back: A combined approach of electron microscopy and X-ray diffraction was applied for the characterization of highly complex chalcogenide phases. In the course of observations, a new structural variant of (NH4)2In12Se19 was produced in situ, and the mechanism of structure formation was analyzed by electron microscopy.

    2. Magnetostructural Correlations

      Theoretical Study on the Structural Aspects of CuII Hybrid-Spin Complexes (pages 379–390)

      Tsveta Miteva, Julia Romanova, Anela Ivanova, Alia Tadjer and Martin Baumgarten

      Article first published online: 8 DEC 2009 | DOI: 10.1002/ejic.200900836

      Thumbnail image of graphical abstract

      The paper offers theoretical analysis of the factors governing the exchange interaction in hybrid-spin systems chosen as models of molecular magnets. The effect of molecular conformation and the importance of symmetry are brought up for the first time.

    3. Stereochemistry at Rhenium

      Diastereoselective Protonation, Substitution and Addition Reactions at Pseudotetrahedral Rhenium Complexes (pages 391–402)

      Frank Bock, Frank Fischer, Krzysztof Radacki and Wolfdieter A. Schenk

      Article first published online: 4 DEC 2009 | DOI: 10.1002/ejic.200901011

      Thumbnail image of graphical abstract

      Diastereomerically pure rhenium complexes [CpRe(NO)(P*–N)(R)] have been obtained through a highly diastereoselective intramolecular proton-transfer reaction. The stereochemistry of chelate ring closure/opening was followed by X-raycrystallography for each step. The Re–SH complex reacts with aldehydes to give diastereomerically pure thioaldehyde complexes which add nucleophiles with 42–89 % de.

    4. Chemoselective Nickel Coordination

      Reactions of Unsaturated Nickel–Molybdenum and –Tungsten Complexes with Primary Amines: Chemoselective N-Coordination to Nickel To Give the First Structurally Characterised Primary Amine–Organonickel Complexes (pages 403–409)

      Carmen Cuncillos Carmona, Sarah Clapham, Mathieu Gonidec, Vincent Ritleng, Pierre Braunstein, Richard Welter and Michael J. Chetcuti

      Article first published online: 3 DEC 2009 | DOI: 10.1002/ejic.200900900

      Thumbnail image of graphical abstract

      Primary amines react reversibly with unsaturated Ni=Mo or Ni=W complexes to give adducts in which the amine is N-coordinated to the nickel atom. This contrasts with previously reported results with P-donor ligands where always coordination to the group 6 metal is observed.

    5. 1D Tin Coordination Compounds

      1-D-Tin(II) Phenylchalcogenolato Complexes 1[Sn(EPh)2] (E = S, Se, Te) – Synthesis, Structures, Quantum Chemical Studies and Thermal Behaviour (pages 410–418)

      Andreas Eichhöfer, Ji-Jun Jiang, Heino Sommer, Florian Weigend, Olaf Fuhr, Dieter Fenske, Cheng-Yong Su and Gernot Buth

      Article first published online: 10 DEC 2009 | DOI: 10.1002/ejic.200900940

      Thumbnail image of graphical abstract

      Single crystalline 1-D-tin(II) phenylchalcogenolato complexes 1[Sn(EPh)2] (E = S, Se, Te) were synthesized in high yields and their bonding situation rationalized by DFT. Thermal investigations partially reveal their suitability as precursors for the synthesis of the corresponding binary SnE phases.

    6. Cobalt Ferrite Octahedra

      Low-Temperature Synthesis, Magnetic and Microwave Electromagnetic Properties of Substoichiometric Spinel Cobalt Ferrite Octahedra (pages 419–426)

      Xi'an Fan, Jianguo Guan, Xiaofen Cao, Wei Wang and Fangzhi Mou

      Article first published online: 4 DEC 2009 | DOI: 10.1002/ejic.200900681

      Thumbnail image of graphical abstract

      Substoichiometric cobalt ferrite octahedra were prepared by controlling the nucleation and selective crystallographic direction growth by a simple optimization of [Co2+]. As this method is carried out in a low-temperature (45 °C) aqueous system and does not need any directing agents, it can be easily generalized in a large-scale synthesis of spinel MxFe2O4 (0 ≤ x ≤ 1) octahedra.

    7. Cluster-Based Cu–Azido Polymers

      Cluster-Based CuII–Azide Polymers: Synthesis, Structure, Magnetic Properties, and Effect of Polyamines on Crystal Structures (pages 427–437)

      Chong-Bin Tian, Zhi-Hua Li, Jian-Di Lin, Shu-Ting Wu, Shao-Wu Du and Ping Lin

      Article first published online: 15 DEC 2009 | DOI: 10.1002/ejic.200900776

      Thumbnail image of graphical abstract

      Four new copper(II)–azide polymers [Cu8(N3)16(222-tet)2]n (1), [Cu10(N3)20(dien)2]n (2), [Cu12(N3)24(Me5dien)2]n (3), and [Cu3(N3)6(dien)]n (4) were synthesized by using different kinds of polyamines under hydrothermal conditions. Their magnetic properties were studied.

    8. Platinum Complexes

      Mononuclear Platinum(II) Complexes of a Bis(bidentate) Ligand Based on 1,3,4-Oxadiazole and Their Reactions with Copper(I) Salts (pages 438–446)

      Marc-Etienne Moret and Peter Chen

      Article first published online: 8 DEC 2009 | DOI: 10.1002/ejic.200900890

      Thumbnail image of graphical abstract

      A series of mononuclear platinum(II) complexes of the bis(bidentate) ligand 2,5-bis[2-(dimethylamino)phenyl]-1,3,4-oxadiazolewere synthesized, and their reaction with CuI salts was studied. In one case, a complex containing an acetate-supported, linear PtII–CuII–PtII chain was obtained.

    9. Heterobimetallic Complexes

      Synthesis, Structure, and Catalytic Activity of Bimetallic PtII–IrIII Complexes Bridged by Cyclooctane-1,2-dithiolato Ligands (pages 447–453)

      Norio Nakata, Masahiro Sakashita, Chizuru Komatsubara and Akihiko Ishii

      Article first published online: 8 DEC 2009 | DOI: 10.1002/ejic.200900958

      Thumbnail image of graphical abstract

      Cationic PtII–IrIII bimetallic complexes bridged by cyclooctane-1,2-dithiolato ligands were synthesized by reaction of (cyclooctane-1,2-dithiolato)PtII complexes with [IrCl(μ-Cl)(η5-Cp*)]2 in thf in the presence of AgSbF6. The bimetallic complexes serve as a catalyst in the hydrosilylation of terminal alkynes with tertiary hydrosilanes to afford selectively the β-(Z)-vinylsilanes in high yields.

    10. Ln–Nitrile Frameworks

      Frameworks by Solvent-Free Synthesis of Rare Earth Chlorides with Molten 1,3-Benzodinitrile and Tailoring of the Particle Size: 3[LnCl3{1,3-C6H4(CN)2}], Ln = Y, Dy, Ho, Er, Yb (pages 454–460)

      Christoph J. Höller and Klaus Müller-Buschbaum

      Article first published online: 11 DEC 2009 | DOI: 10.1002/ejic.200900962

      Thumbnail image of graphical abstract

      Solvent-free melt reactions of anhydrous rare earth trichlorides with molten 1,3-benzodinitrile result in isophthalonitrile frameworks of the rare earth elements. The particle size of the products can be varied from the millimeter to the nanometer scale (50–400 nm) depending on the synthesis conditions. A constitution of 1:1 concerning LnCl3/1,3-C6H4(CN)2 is found for Y, Dy, Ho, Er and Yb in isotypic3[LnCl3{1,3-C6H4(CN)2}].

    11. Silicon Hypercoordination

      A Distorted Trigonal Antiprismatic Cationic Silicon Complex with Ureato Ligands: Syntheses, Crystal Structures and Solid State 29Si NMR Properties (pages 461–467)

      Dana Schöne, Daniela Gerlach, Conny Wiltzsch, Erica Brendler, Thomas Heine, Edwin Kroke and Jörg Wagler

      Article first published online: 8 DEC 2009 | DOI: 10.1002/ejic.200900784

      Thumbnail image of graphical abstract

      The N-silylated ureato ligand 1, accessible via insertion of phenyl isocyanate into the Si–N bond of Me3SiNEt2, proved an interesting κ(O,N) chelator, capable of setting up distorted trigonal antiprismatic coordination spheres about silicon. The 29Si CSA tensor of a silicon tris-chelate of this ligand was found to exhibit pronounced axiality and remarkably narrow span.

    12. Tricarbonyliron Chalcogenolates

      The Tricarbonyliron Chalcogenolates [(OC)3Fe(μ-ESitBu3)]2 (E = S, Se, Te) (pages 468–475)

      Theresa Kückmann, Frauke Schödel, Inge Sänger, Michael Bolte, Matthias Wagner and Hans-Wolfram Lerner

      Article first published online: 9 DEC 2009 | DOI: 10.1002/ejic.200900806

      Thumbnail image of graphical abstract

      The tricarbonyliron thiolate and selenolate [(OC)3Fe(μ-ESitBu3)]2 (E = S, Se) were synthesized photochemically by the reaction of pentacarbonyliron with the dichalcogenides tBu3Si–E2–SitBu3 (E = S, Se).

    13. Titania Fibrous Hybrids

      Simple and Efficient Aqueous Process for Nanostructured Fibrous TiO2 Regulated by Linear Polyethyleneimine Aggregates (pages 476–482)

      Pei-Xin Zhu and Ren-Hua Jin

      Article first published online: 2 DEC 2009 | DOI: 10.1002/ejic.200900830

      Thumbnail image of graphical abstract

      The biomimetic construction of belt-like TiO2-LPEI fibrous hybrids was successfully achieved in an aqueous solution by using linear poly(ethyleneimine) (LPEI) aggregates as a catalytic mediator.

    14. “Naked” Manganese Triangles

      “Naked” [Mn3O]7+ Triangles: The Effect of Auxiliary Ligands on Magnetic Exchange (pages 483–489)

      Efi Manolopoulou, Constantinos C. Stoumpos, Milosz Siczek, Tadeusz Lis, Euan K. Brechin and Constantinos J. Milios

      Article first published online: 2 DEC 2009 | DOI: 10.1002/ejic.200900905

      Thumbnail image of graphical abstract

      Capping ligands on [Mn3] triangles induce a small but vital effect on magnetic exchange properties. Although the bridging/capping ligand has little effect on the magnitude of the magnetic interactions, its presence is vital in achieving maximal structural distortion, and, therefore, interesting magnetic properties.

SEARCH

SEARCH BY CITATION