A Selective Chromium Catalyst System for the Trimerization of Ethene and Its Coordination Chemistry (pages 1167–1171)
Stephan Peitz, Normen Peulecke, Bhaskar R. Aluri, Sven Hansen, Bernd H. Müller, Anke Spannenberg, Uwe Rosenthal, Mohammed H. Al-Hazmi, Fuad M. Mosa, Anina Wöhl and Wolfgang Müller
Version of Record online: 9 FEB 2010 | DOI: 10.1002/ejic.201000044
A new trimerization system for ethene consisting of CrCl3(thf)3, a novel aminophosphane ligand, and Et3Al was developed, showing very promising results in selectivity and applicability (see picture). Investigations on organometallic model compounds give an indication of the nature of the active catalyst species.