European Journal of Inorganic Chemistry

Cover image for Vol. 2010 Issue 9

March 2010

Volume 2010, Issue 9

Pages 1311–1430

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Titanacalixarenes in Homogeneous Catalysis: Synthesis, Conformation and Catalytic Activity in Ethylene Polymerisation (Eur. J. Inorg. Chem. 9/2010) (page 1311)

      Jeff Espinas, Ulrich Darbost, Jeremie Pelletier, Erwan Jeanneau, Christian Duchamp, François Bayard, Olivier Boyron, Jean-Pierre Broyer, Jean Thivolle-Cazat, Jean-Marie Basset, Mostafa Taoufik and Isabelle Bonnamour

      Article first published online: 9 MAR 2010 | DOI: 10.1002/ejic.201090022

  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
  4. Microreview

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Allyl Complexes

      Complexes with Sterically Bulky Allyl Ligands: Insights into Structure and Bonding (pages 1321–1337)

      Stephen C. Chmely and Timothy P. Hanusa

      Article first published online: 23 FEB 2010 | DOI: 10.1002/ejic.200900813

      Thumbnail image of graphical abstract

      Sterically bulky substituents on allyl ligands can dramatically enhance the thermal and kinetic stability of their associated metal complexes. Compounds with such ligands display a wide range of monomeric, oligomeric, and polymeric structures, and research in this area is greatly expanding the range of bonding types and associated reactions that can be incorporated into metal allyl chemistry.

  5. Short Communications

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Molecular Magnetism

      An Oximate-Free Ferromagnetically Coupled Triangular [MnIII33-O)]7+ Core (pages 1339–1342)

      Phalguni Chaudhuri, Rita Wagner and Thomas Weyhermüller

      Article first published online: 19 FEB 2010 | DOI: 10.1002/ejic.200901210

      Thumbnail image of graphical abstract

      Magnetic properties of the alkoxo-bridged trinuclear complex [L3MnIII33-O)(MeOH)3]PF6 are investigated. The compound is ferromagnetically coupled yielding an St = 6 spin ground state and is a very rare example of an oximate-free ferromagnetic manganese(III) complex containing the [MnIII3O]7+ core.

    2. Barium Titanate Nanostructures

      Low-Temperature Synthesis of Phase-Pure 0D–1D BaTiO3 Nanostructures Using H2Ti3O7 Templates (pages 1343–1347)

      Duk Kyu Lee, In-Sun Cho, SangWook Lee, Dong Hoe Kim, Hyun-Woo Shim, Dong-Wan Kim and Kug Sun Hong

      Article first published online: 16 FEB 2010 | DOI: 10.1002/ejic.200901230

      Thumbnail image of graphical abstract

      0D–1D BaTiO3 nanostructures with perovskite structure were synthesized by using H2Ti3O7 nanowire templates under low-temperature (80 °C) solvothermal conditions in an ethanol/water mixed solution.

  6. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Catalysts with Tunable Structure

      Titanacalixarenes in Homogeneous Catalysis: Synthesis, Conformation and Catalytic Activity in Ethylene Polymerisation (pages 1349–1359)

      Jeff Espinas, Ulrich Darbost, Jeremie Pelletier, Erwan Jeanneau, Christian Duchamp, François Bayard, Olivier Boyron, Jean-Pierre Broyer, Jean Thivolle-Cazat, Jean-Marie Basset, Mostafa Taoufik and Isabelle Bonnamour

      Article first published online: 12 FEB 2010 | DOI: 10.1002/ejic.200901185

      Thumbnail image of graphical abstract

      Titanium catalysts based on calixarene ligands have been prepared and screened for their performance as ethylene polymerisation catalysts. Upon methylaluminoxane (MAO) activation, some of these systems displayed high activity for the production of high-density polyethylene. Both the Ti coordination mode and the ligand conformation have been found to be significant for the catalytic performance.

    2. Sensors

      A Bipyridine-Based “Naked-Eye” Fluorimetric Cu2+ Chemosensor (pages 1360–1365)

      Anna Reynal, Juan Etxebarria, Natalia Nieto, Sílvia Serres, Emilio Palomares and Anton Vidal-Ferran

      Article first published online: 16 FEB 2010 | DOI: 10.1002/ejic.200900887

      Thumbnail image of graphical abstract

      A new molecular probe for the optical detection of CuII ions is described. The molecule can be used as a chemodosimeter to estimate the concentration of CuII ions in solution either by UV/Vis or photoluminescence spectrocopy.

    3. Zinc Oxide Thin Films

      Volatile, Monomeric, and Fluorine-Free Precursors for the Metal Organic Chemical Vapor Deposition of Zinc Oxide (pages 1366–1372)

      Daniela Bekermann, Detlef Rogalla, Hans-Werner Becker, Manuela Winter, Roland A. Fischer and Anjana Devi

      Article first published online: 12 FEB 2010 | DOI: 10.1002/ejic.200901037

      Thumbnail image of graphical abstract

      Two new bis(ketoiminato)zinc precursors for the growth of zinc oxide thin films were developed and evaluated for their use in chemical vapor deposition processes. Stoichiometric ZnO thin films with a preferred orientation were grown on Si(100) substrates.

    4. Substituent Effects in Cu Complexes

      Substituent Effects on Structural, Electronic, and Redox Properties of Bis(N-alkyl-2-oxy-1-naphthaldiminato)copper(II) Complexes Revisited – Inequivalence in Solid- and Solution-State Structures by Electronic Spectroscopy and X-ray Diffraction Explained by DFT (pages 1373–1380)

      Manuel Villagrán, Francesco Caruso, Miriam Rossi, José H. Zagal and Juan Costamagna

      Article first published online: 12 FEB 2010 | DOI: 10.1002/ejic.200900298

      Thumbnail image of graphical abstract

      Stereochemical differences between the solid and solution state structures for bis(N-alkyl-2-oxy-1-naphthaldiminato)copper(II) complexes are correlated to the CuII/CuI potential.

    5. Platinum Arene Complexes

      Synthesis, Characterization, and Protonation Reactions of Ar-BIAN and Ar-BICAT Diimine Platinum Diphenyl Complexes (pages 1381–1394)

      Jerome Parmene, Alexander Krivokapic and Mats Tilset

      Article first published online: 11 FEB 2010 | DOI: 10.1002/ejic.200900975

      Thumbnail image of graphical abstract

      The nature of the N–N ligand has clear influences on the structural and spectroscopic characteristics of the Pt complexes. The rates of protonation and benzene elimination starting from the new (N–N)PtPh2 complexes strongly depend on the identity of the N–N ligand.

    6. Mixed Tellurides

      Mixed Tellurides Ni3–xGaTe2 (0 ≤ x ≤ 0.65): Crystal and Electronic Structures, Properties, and Nickel Deficiency Effects on Vacancy Ordering (pages 1395–1404)

      Anna A. Isaeva, Olga N. Makarevich, Alexey N. Kuznetsov, Thomas Doert, Artem M. Abakumov and Gustaaf Van Tendeloo

      Article first published online: 12 FEB 2010 | DOI: 10.1002/ejic.200901027

      Thumbnail image of graphical abstract

      The NiAs-derivative crystal structure of mixed tellurides Ni3–xGaTe2 (0 ≤ x ≤ 0.65) hosts a variable content of Ni atoms in 2D heterometallic Ni/Ga slabs and Te-confined van der Waals gaps. At low values of Ni content, x < 0.5, the extra Ni atoms arrange in a superstructural ordered fashion aimed to relax the structural strain between the occupied and vacant sites in the ab plane.

    7. Nanostructured Epoxidation Catalyst

      Nanostructured Dioxomolybdenum(VI) Catalyst for the Liquid-Phase Epoxidation of Olefins (pages 1405–1412)

      Alichandra Castro, João C. Alonso, Anabela A. Valente, Patrícia Neves, Paula Brandão, Vitor Félix and Paula Ferreira

      Article first published online: 12 FEB 2010 | DOI: 10.1002/ejic.200901093

      Thumbnail image of graphical abstract

      A benzenosilica hybrid mesoporous material containing phosphane oxide surface groups (HM), prepared via the “dual”organosilane templated co-condensation method, was used as an effective catalyst support for [Mo(O)2Cl2] (HM-Mo). The catalyst is active and selective in the liquid-phase epoxidation of olefins with tBuOOH.

    8. Chiral NHC-Palladacycle

      Synthesis and Characterisation of a Novel Chiral Bidentate Pyridine-N-Heterocyclic Carbene-Based Palladacycle (pages 1413–1418)

      Minyi Chiang, Yongxin Li, Deepa Krishnan, Pullarkat Sumod, Kim Hong Ng and Pak-Hing Leung

      Article first published online: 12 FEB 2010 | DOI: 10.1002/ejic.200901142

      Thumbnail image of graphical abstract

      We have successfully prepared a novel chiral pyridine-NHC-based palladacycle via the optical resolution of its amino acid adduct. This method provides a simple and efficient route towards the synthesis of chiral bidentate NHC-based pallacycles.

    9. Hydrogenation Catalysts

      Benzo[h]quinoline Pincer Ruthenium and Osmium Catalysts for Hydrogenation of Ketones (pages 1419–1423)

      Walter Baratta, Lidia Fanfoni, Santo Magnolia, Katia Siega and Pierluigi Rigo

      Article first published online: 15 FEB 2010 | DOI: 10.1002/ejic.200901253

      Thumbnail image of graphical abstract

      Ru and Os complexes [MX(CN′N)(PP)] {M = Ru, Os; X = Cl, OCH(p-C6H4F)2; PP = dppb, (S,R)-Josiphos} efficiently catalyze the hydrogenation (5 atm) of ketones to secondary alcohols in methanol or methanol/ethanol mixtures and in the presence of KOtBu with a S/C ratio of 10000–50000. Josiphos diphosphanes reduce alkyl aryl ketones with ee values up to 99 % and turnover frequencies up to 5.6 × 104 h–1.

    10. Zinc Aryloxides

      A Family of 1,1,3,3-Tetraalkylguanidine (H-TAG) Solvated Zinc Aryloxide Precatalysts for the Ring-Opening Polymerization of rac-Lactide (pages 1424–1430)

      Julia J. Ng, Christopher B. Durr, Jacob M. Lance and Scott D. Bunge

      Article first published online: 18 FEB 2010 | DOI: 10.1002/ejic.200900986

      Thumbnail image of graphical abstract

      Six 1,1,3,3-tetraalkylguanidine (H-TAG) solvated zinc aryloxides have been synthesized and characterized for use as precatalysts for the ring-opening polymerization of rac-lactide.

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