European Journal of Inorganic Chemistry

Cover image for Vol. 2011 Issue 2

January 2011

Volume 2011, Issue 2

Pages 169–288

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communication
    7. Full Papers
    1. Water-Soluble and Biocompatible Cyclometalated Iridium(III) Complexes: Synthesis, Luminescence and Sensing Application (Eur. J. Inorg. Chem. 2/2011)

      Mei-Jin Li, Pengchong Jiao, Weiwen He, Changqing Yi, Cheuk-Wing Li, Xi Chen, Guo-Nan Chen and Mengsu Yang

      Version of Record online: 3 JAN 2011 | DOI: 10.1002/ejic.201190000

  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communication
    7. Full Papers
  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communication
    7. Full Papers
  4. Microreview

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communication
    7. Full Papers
    1. Modified Polyoxometalates

      Chemistry of Group IV Metal Ion-Containing Polyoxometalates (pages 179–196)

      Kenji Nomiya, Yoshitaka Sakai and Satoshi Matsunaga

      Version of Record online: 4 NOV 2010 | DOI: 10.1002/ejic.201000712

      Thumbnail image of graphical abstract

      Site-selective lacunary species of WVI atoms in polyoxometalates (POMs) can be utilized as a support for various metal ions and cationic species. This microreview is focused on the syntheses, molecular structures and properties of Group IV metal ion-containing POMs, which were prepared by the reactions of various lacunary species of POMs with TiIV, ZrIV and HfIV atoms.

  5. Short Communication

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communication
    7. Full Papers
    1. Glycoconjugated Iridium Complexes

      Water-Soluble and Biocompatible Cyclometalated Iridium(III) Complexes: Synthesis, Luminescence and Sensing Application (pages 197–200)

      Mei-Jin Li, Pengchong Jiao, Weiwen He, Changqing Yi, Cheuk-Wing Li, Xi Chen, Guo-Nan Chen and Mengsu Yang

      Version of Record online: 9 DEC 2010 | DOI: 10.1002/ejic.201000991

      Thumbnail image of graphical abstract

      New water-soluble, highly efficient and bio-compatible cyclometalated iridium(III) diimine complexes were synthesized and characterized and their potential application as lectin sensor was also studied. The new iridium(III) complexes might open up their application as bio- and chemosensors.

  6. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communication
    7. Full Papers
    1. Mechanism of Protonation

      Protonation of Zwitterionic Manganese and Rhenium Phosphoniostyryl Complexes (η5-C5H5)(CO)2M–C(+PR3)=C(H)Ph: Experimental and DFT Study (pages 201–211)

      Vasily V. Krivykh, Dmitry A. Valyaev, Kamil I. Utegenov, Andrei M. Mazhuga, Elena S. Taits, Oleg V. Semeikin, Pavel V. Petrovskii, Ivan A. Godovikov, Ivan V. Glukhov and Nikolai A. Ustynyuk

      Version of Record online: 12 NOV 2010 | DOI: 10.1002/ejic.201000868

      Thumbnail image of graphical abstract

      Protonation of Mn and Re Z-σ-phosphoniostyryl complexes 37 with HBF4·OEt2 leads to the E2-phosphonioalkene derivatives 812 rather than the phosphoniocarbene complexes 13. According to DFT calculations, protonation of Mn complex 5 proceeds at the metal atom followed by fast conversion of the resulting cis-hydride 14 into the agostic intermediate 15 and the final product 10. Quantitative formation of the cis-hydride intermediates 16 and 17 was evidenced by low-temperature protonation of the rhenium Z-σ-phosphoniostyryl complexes 6 and 7 with triflic acid.

    2. Copper–Thioether Complexes

      Electrochemical and Structural Characterization of Tri- and Dithioether Copper Complexes (pages 212–220)

      Paulina R. Martínez-Alanis, Víctor M. Ugalde-Saldívar and Ivan Castillo

      Version of Record online: 1 DEC 2010 | DOI: 10.1002/ejic.201000960

      Thumbnail image of graphical abstract

      The nitrilotrithioether 1 behaves like a chelating ligand toward CuI, whilst the dithioether 2 bridges Cu4I4 clusters. The redox potentials of all the thioether ligands 13 are below those of the Cu2+/Cu+ couples oftheir complexes, resulting in Cu2+-promoted oxidation. Electrochemical oxidation of the thioethers affords the same decomposition products.

    3. Mesoporous Rh Catalyst

      Highly Efficient Hydroformylation of 1-Hexene over an ortho-Metallated Rhodium(I) Complex Anchored on a 2D-Hexagonal Mesoporous Material (pages 221–227)

      Mahasweta Nandi, Paramita Mondal, Manirul Islam and Asim Bhaumik

      Version of Record online: 2 DEC 2010 | DOI: 10.1002/ejic.201000844

      Thumbnail image of graphical abstract

      An ortho-metallated RhI complex has been immobilised on a functionalised 2D-hexagonal mesoporous silica, and the resultingmaterial showed very good catalytic efficiency in the hydroformylation reaction of 1-hexene to n-heptanal.

    4. Thiocyanato Coordination Diversity

      Dimorphic Modifications of the Thiocyanato-Bridged Coordination Polymer [Ni(NCS)2(pyridazine)(H2O)0.5]n with Different Magnetic Properties (pages 228–234)

      Mario Wriedt and Christian Näther

      Version of Record online: 25 NOV 2010 | DOI: 10.1002/ejic.201000846

      Thumbnail image of graphical abstract

      The first coordination polymer, in which the three most common thiocyanato coordination modes are combined, has been prepared and investigated for its thermal and magnetic properties. On heating, this compound transforms quantitatively into a new anhydrate, which transforms on rehydration to a new polymorphic hemihydrate modification.

    5. Germa-closo-dodecaborate: An Ambident and Flexible Coordinating Ligand (pages 235–240)

      Jörg-Alexander Dimmer and Lars Wesemann

      Version of Record online: 4 NOV 2010 | DOI: 10.1002/ejic.201000857

      Thumbnail image of graphical abstract

      Germa-closo-dodecaborate [GeB11H11]2– coordinated at iron or ruthenium triphos fragments [(triphos)M]2+ [triphos = MeC(CH2PPh2)3; M = Fe, Ru] shows a reversible η1(Ge) to η3(B–H) rearrangement.Coordinated through the three B–H units, the germanium vertex is still nucleophilic enough to react with [Mo(CO)5thf] under complexation.

    6. MOF Epoxidation Catalysts

      Heterogeneous Catalytic Epoxidation of Olefins Over Hydrothermally Synthesized Lanthanide Containing Framework Compounds (pages 241–248)

      Rupam Sen, Subratanath Koner, Dipak K. Hazra, Madeleine Helliwell and Monika Mukherjee

      Version of Record online: 9 DEC 2010 | DOI: 10.1002/ejic.201000937

      Thumbnail image of graphical abstract

      A series of novel compounds [Ln2(N3)(nic)2(OH)3(Hnic)(H2O)]n (Ln = YIII1 and GdIII2; Hnic = nicotinic acid) and [Sm4(N3)2(nic)4(OH)6(Hnic)2(H2O)2]n, 3, have been hydrothermally synthesized and structurally characterized. The overall structures of complexes 1, 2 and 3 are ribbon-like 1D infinite chains. All the compounds exhibit excellent catalytic performance in olefin epoxidation reactions.

    7. (Biscarbene)platinum(II) Complexes

      Synthesis and Structural Characterization of New Chiral (Biscarbene)platinum(II) Complexes (pages 249–254)

      Stephanie K. U. Riederer, Bettina Bechlars, Wolfgang A. Herrmann and Fritz E. Kühn

      Version of Record online: 29 NOV 2010 | DOI: 10.1002/ejic.201000939

      Thumbnail image of graphical abstract

      Novel chiral (biscarbene)platinum(II) complexes [Pt{bis(NHC)}X2] (X = Br, I) have been prepared and fully characterized. They were successfully tested as catalysts for hydrosilylation reactions. One of the new complexes has also been characterised by X-ray crystallography. These complexes were shown to be efficient precatalysts for the hydrosilylation of 1-octene.

    8. Copper Complexes

      Syntheses, Characterization and Properties of Open-Chain Copper(I) Complexes (pages 255–267)

      Diana Utz, Sandra Kisslinger, Frank W. Heinemann, Frank Hampel and Siegfried Schindler

      Version of Record online: 25 NOV 2010 | DOI: 10.1002/ejic.201000954

      Thumbnail image of graphical abstract

      A mononuclear complex, [Cu(L1)(CH3CN)]PF6, is formed from the reaction of a tridentate imine ligand (L1) with [Cu(CH3CN)4]PF6. In contrast, use of [Cu(CH3CN)4]ClO4 led to the formation of a dinuclear helical complex, [Cu2(L1)2](ClO4)2, due to an anionic effect.

    9. Chlorinated Fullerenes

      In Situ Synthesis of Chlorinated Fullerenes by the High-Frequency Furnace Method (pages 268–272)

      Andreas Mueller, Karolin Ziegler, Konstantin Yu. Amsharov and Martin Jansen

      Version of Record online: 7 DEC 2010 | DOI: 10.1002/ejic.201000990

      Thumbnail image of graphical abstract

      Chlorinated fullerenes have been synthesized by the high-frequency furnace method in the presence of CCl4. In particular, several isomers of chlorinated higher fullerenes, namely C72, C74 and C78 species, were obtained in high yields by using this approach.

    10. Au Nanoparticle Precursor

      Hydrolytic Decomposition of Tetramethylammonium Bis(trifluoromethyl)aurate(I), [NMe4][Au(CF3)2]: A Route for the Synthesis of Gold Nanoparticles in Aqueous Medium (pages 273–280)

      David Zopes, Silke Kremer, Harald Scherer, Lhoussaine Belkoura, Ingo Pantenburg, Wieland Tyrra and Sanjay Mathur

      Version of Record online: 23 NOV 2010 | DOI: 10.1002/ejic.201000863

      Thumbnail image of graphical abstract

      Time-dependent NMR and UV/Vis spectroscopic studies revealed the chemical species and reaction cascade involved in the decomposition of a molecular species into gold clusters. The size and stability of the naked AuNPs was modulated simply by changing the precursor concentration.

    11. Reactivity of Phosphagermaallene

      Reactivity of Quinones with Phosphagermaallene Tip(tBu)Ge=C=PMes* Leading to Four- and Six-Membered Heterocycles with an Exocyclic P=C Double Bond (pages 281–288)

      Dumitru Ghereg, Heinz Gornitzka and Jean Escudié

      Version of Record online: 7 DEC 2010 | DOI: 10.1002/ejic.201000747

      Thumbnail image of graphical abstract

      The reaction of phosphagermaallene Tip(tBu)Ge=C=PMes* with one equivalent of p-quinone leads to 1-oxa-2-germacyclobutane with an exocyclic –P=C< double bond by [2 + 2] cycloaddition. Benzil and9,10-phenanthrenequinone react with 1 by [2 + 4] cycloaddition, involving oxygen atoms of the O=C–C=O unit to afford 1,4-dioxa-2-germacyclo-hex-5-ene.

SEARCH

SEARCH BY CITATION