European Journal of Inorganic Chemistry

Cover image for Vol. 2011 Issue 4

February 2011

Volume 2011, Issue 4

Pages 445–596

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. Water Adsorption Characteristics of MIL-101 for Heat-Transformation Applications of MOFs (Eur. J. Inorg. Chem. 4/2011)

      Johannes Ehrenmann, Stefan K. Henninger and Christoph Janiak

      Version of Record online: 26 JAN 2011 | DOI: 10.1002/ejic.201190006

  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
  4. Microreview

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. The Gang of III's

      Three-Coordinate [Pt(N,N′-chelate)(η2-olefin)] Complexes: Synthesis, Properties and Reactions with Electrophiles (pages 457–469)

      Maria Elena Cucciolito, Vincenzo De Felice, Giuseppina Roviello and Francesco Ruffo

      Version of Record online: 28 DEC 2010 | DOI: 10.1002/ejic.201001021

      Thumbnail image of graphical abstract

      This review provides a survey of the key-class of Pt0 complexes of general formula [Pt(N,N′-chelate)(η2-olefin)] (III). The main spectroscopic and structural featuresare discussed. The versatile reactivity towards A-B electrophiles is also described as a very useful entry to PtII compounds (V) with a wide assortment of ligands.

  5. Short Communications

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. MOFs for Heat Transformation

      Water Adsorption Characteristics of MIL-101 for Heat-Transformation Applications of MOFs (pages 471–474)

      Johannes Ehrenmann, Stefan K. Henninger and Christoph Janiak

      Version of Record online: 23 DEC 2010 | DOI: 10.1002/ejic.201001156

      Thumbnail image of graphical abstract

      A new application for MOFs – heat transformation and adsorption chilling: MIL-101 is one of the most promising water sorbent materials for heat-transformation applications known so far, as 1 g adsorbs up to 1 g of water and is stable even over several cycles.

    2. Facile Synthesis of a Rare Chlorosilylene–BH3 Adduct (pages 475–477)

      Ramachandran Azhakar, Gašper Tavčar, Herbert W. Roesky, Jakob Hey and Dietmar Stalke

      Version of Record online: 22 DEC 2010 | DOI: 10.1002/ejic.201001188

      Thumbnail image of graphical abstract

      The first stable silylene–BH3 adduct formed by the reaction of N-heterocyclic carbene stabilized dichlorosilylene either with LiBH4 or with a BH3·THF solution.

  6. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Microreview
    6. Short Communications
    7. Full Papers
    1. C–H···π Driven Cyclisation

      The Role of the C–H···π Interactions in the Cyclisation Reactions Leading to New Aryl-Bridged Tetraazamacrocyclic Complexes of Copper and Nickel (pages 479–488)

      Radosław Kamiński, Jarosław Kowalski, Iwona Mames, Bohdan Korybut-Daszkiewicz, Sławomir Domagała and Krzysztof Woźniak

      Version of Record online: 22 DEC 2010 | DOI: 10.1002/ejic.201000818

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      A series of neutral macrocyclic complexes of CuII and NiII with bridging polyether linkers to aromatic fragments has been synthesised. These molecules do not form intramolecular cavities but adopt an “equatorial” conformation of the bridge due to the C–H···π interactions. These interactions are responsible for the formation of cyclic products. DFT calculations confirm the experimental findings.

    2. Polyoxometalates

      Bonding Interactions between Nitrous Oxide (N2O) and Mono-Ruthenium Substituted Keggin-Type Polyoxometalates: Electronic Structures of Ruthenium/N2O Adducts (pages 489–494)

      Chun-Guang Liu, Wei Guan, Li-Kai Yan and Zhong-Min Su

      Version of Record online: 23 DEC 2010 | DOI: 10.1002/ejic.201000907

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      The mono-ruthenium(II) substituted Keggin-type POM can serve as a potential reagent for the activation of the N2O molecule because of the strong Ru–NNO bondand significant RuNN–O π*-antibonding orbital character, according to density functional theory calculations.

    3. Ferromagnetic Spin Ladder

      Ferromagnetic Spin Ladder System: Stack of Chlorido-Bridged Dinuclear Copper(II) Complexes with 2-Methylisothiazol-3(2H)-one (pages 495–502)

      Masaru Kato, Kazuo Hida, Takashi Fujihara and Akira Nagasawa

      Version of Record online: 14 DEC 2010 | DOI: 10.1002/ejic.201000096

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      Chlorido-bridged dinuclear copper(II) complexes with 2-methylisothiazol-3(2H)-one (mi) stack one on top of another to form a ladder structure in the solid state. Magnetic susceptibility measurements suggest a ferromagnetic spin ladder. DFT calculations show that mi plays an essential role in the emerging intramolecular ferromagnetic interaction.

    4. Singlet Oxygen Photosensitizers

      Water-Soluble Transition-Metal-Phthalocyanines as Singlet Oxygen Photosensitizers in Ene Reactions (pages 503–509)

      Primiano D'Ambrosio, Lucia Tonucci, Nicola d'Alessandro, Antonino Morvillo, Salvatore Sortino and Mario Bressan

      Version of Record online: 16 DEC 2010 | DOI: 10.1002/ejic.201000784

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      Water-soluble platinum and palladium tetrasulfophthalocyanines show good photostability and photosensitize the generation of singlet oxygen, which can be efficiently used in ene reactions for synthetic purposes.

    5. Half-Sandwich Complexes

      Preparation of Pyrazole–Pyrazolate Half-Sandwich Complexes of Ruthenium and Osmium (pages 510–520)

      Gabriele Albertin, Stefano Antoniutti, Jesús Castro and Soledad García-Fontán

      Version of Record online: 22 DEC 2010 | DOI: 10.1002/ejic.201000799

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      The reactivity of half-sandwich complexes, MCl26-p-cymene)L, towards pyrazole or imidazole ligands, yielding three different types of azole complexes, is described. X-ray crystal structure determination of the three compounds [RuCl(η6-p-cymene)(HRpz){PPh(OEt)2}]BPh4 (1b), [Ru(Rpz)(η6-p-cymene)(HRpz){P(OEt)3}]BPh4 (11a) and [RuCl(η6-p-cymene)(HRpz)2]BPh4 (15) is reported.

    6. Aluminum Amides

      Low-Coordinate Aluminum Amides from Silylanilines and Alkylalanes (pages 521–526)

      Manish Khandelwal, Douglas R. Powell and Rudolf J. Wehmschulte

      Version of Record online: 15 DEC 2010 | DOI: 10.1002/ejic.201000869

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      Aluminum amides featuring three-coordinate aluminum and nitrogen centers are obtained in simple procedures from commercially available and easy to synthesize starting materials.

    7. Macrocyclic Complexes

      A New Tris(phosphonomethyl) Monoacetic Acid Cyclam Derivative: Synthesis, Acid-Base and Metal Complexation Studies (pages 527–538)

      Luís M. P. Lima, Rita Delgado, Jan Plutnar, Petr Hermann and Jan Kotek

      Version of Record online: 28 DEC 2010 | DOI: 10.1002/ejic.201000919

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      A new cyclam derivative, which has one acetate and three methylphosphonate pendant arms, forms complexes of high thermodynamic stability with the transition metal and lanthanide ions. The coordination of the metal ion in solution involves only one phosphonate group in the ZnII complex but uses all three phosphonates in the CdII complex.

    8. Hydrogen-Bonded Architectures

      Coordination Chemistry of Thiazole-Based Ligands: New Complexes Generating 3D Hydrogen-Bonded Architectures (pages 539–548)

      Andrea Rossin, Barbara Di Credico, Giuliano Giambastiani, Luca Gonsalvi, Maurizio Peruzzini and Gianna Reginato

      Version of Record online: 22 DEC 2010 | DOI: 10.1002/ejic.201000928

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      The coordination chemistry and supramolecular assembly of novel thiazole-based ligands with several 3d late-transition-metal ions has been explored. An extended network in the solid state is generatedthrough multiple intra- and intermolecular hydrogen bonds between the several polar groups present. The macroscopic effect is the creation of insoluble crystalline materials of polymeric nature.

    9. Metal–Organic Frameworks

      Crystal Structures and Physical Properties of Three New Manganese-Based Coordination Polymers with p-Biphenyldicarboxylic Acid Linkers (pages 549–555)

      Mads R. V. Jørgensen, Henrik F. Clausen, Mogens Christensen, Rasmus D. Poulsen, Jacob Overgaard and Bo B. Iversen

      Version of Record online: 28 DEC 2010 | DOI: 10.1002/ejic.201001001

      Thumbnail image of graphical abstract

      Three new manganese-containing metal–organic frameworks were synthesized by using p-biphenyldicarboxylic acid as linker and three different solvents. One of these compounds has an irreversible phase transition at 2 K and is thus metastable. In the metastable state the compound is antiferromagnetic.

    10. Polyphosphane Iron Complexes

      Bond Activation in Iron(II)-Coordinated Polypodal Phosphane Ligands (pages 556–566)

      Simon-Andreas Gentschow, Stephan W. Kohl, Walter Bauer, Markus Hummert and Andreas Grohmann

      Version of Record online: 22 DEC 2010 | DOI: 10.1002/ejic.201001014

      Thumbnail image of graphical abstract

      Upon reaction with CO, the iron(II) complex containing a specialized NP3 ligand and diethylphosphane is transformed intothe expected carbonyl complex – and a side product in which P–C bond formation has occurred.

    11. Acylphosphane Complexes

      New Access to and Reactions of P-Functional Acylphosphane Complexes (pages 567–572)

      Vitaly Nesterov, Lili Duan, Gregor Schnakenburg and Rainer Streubel

      Version of Record online: 27 DEC 2010 | DOI: 10.1002/ejic.201001122

      Thumbnail image of graphical abstract

      P-Functional (acylphosphane)tungsten complexes 2 were prepared in goodyields by the reaction of phosphinidenoid complexes 1 with acyl chlorides. The reactions of acyl(chloro)phosphane complexes2 (X = Cl; R = Ph) with organolithium reagents selectively led to the formation of phospha-enolate 3, which showed ambident reactivity towards electrophiles such as PhC(O)Cl, MeI, and Me3SiCl.

    12. Modified Titanium Alkoxides

      Modification of Titanium Isopropoxide with Aromatic Aldoximes (pages 573–580)

      Stefan O. Baumann, Maria Bendova, Michael Puchberger and Ulrich Schubert

      Version of Record online: 22 DEC 2010 | DOI: 10.1002/ejic.201000881

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      Benzaldoximate- and anisaldoximate-modified titanium alkoxides were synthesized and structurally characterized. Reaction with perillaldoxime or trans-cinnamaldoxime allows derivatives with functional ligands to be prepared.

    13. Hydrogen from [2Fe2S(Si)] Clusters

      Influence of the Introduction of Cyanido and Phosphane Ligands in Multifunctionalized (Mercaptomethyl)silane [FeFe] Hydrogenase Model Systems (pages 581–588)

      Ulf-Peter Apfel, Yvonne Halpin, Helmar Görls, Johannes G. Vos and Wolfgang Weigand

      Version of Record online: 20 DEC 2010 | DOI: 10.1002/ejic.201000918

      Thumbnail image of graphical abstract

      Inspired by the properties of [2Fe2S(Si)] clusters as well as the nonsymmetric active site in [FeFe] hydrogenase, [2Fe2S(Si)] clusters containing cyanido and triphenylphosphane ligands were synthesized. In this contribution we present the structural, spectroscopic and electrochemical features of these compounds.

    14. Dinuclear Dye Sensitiser

      Dinuclear Ru–Cu Complexes: Electronic Characterisation and Application to Dye-Sensitised Solar Cells (pages 589–596)

      Keri L. McCall, James R. Jennings, Hongxia Wang, Ana Morandeira, Laurence M. Peter, James R. Durrant, Lesley J. Yellowlees and Neil Robertson

      Version of Record online: 27 DEC 2010 | DOI: 10.1002/ejic.201001039

      Thumbnail image of graphical abstract

      A dimetallic Ru–Cu complex has been used as a sensitiser for dye-sensitised solar cells showing moderate efficiency. Both metals are involved in the frontier orbitals, and multiple redox steps result.

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