Spin Crossover and Solvate Effects in 1D FeII Chain Compounds Containing Bis(dipyridylamine)-Linked Triazine Ligands (pages 1395–1417)
Tamsyn M. Ross, Boujemaa Moubaraki, David. R. Turner, Gregory J. Halder, Guillaume Chastanet, Suzanne M. Neville, John D. Cashion, Jean-François Létard, Stuart R. Batten and Keith S. Murray
Article first published online: 7 FEB 2011 | DOI: 10.1002/ejic.201000876
New polymeric spin crossover compounds of type trans-[FeII(NCX)2(L)]·Solvent have been synthesised and characterised. In some cases ordered HS-LS FeII sites are observed at low temperatures, and LIESSTand Mössbauer effect measurements have been made. Powder and single-crystal X-ray data are used to draw magnetostructural correlations.