European Journal of Inorganic Chemistry

Cover image for Vol. 2012 Issue 27

September 2012

Volume 2012, Issue 27

Pages 4247–4370

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    1. You have free access to this content
      Synthesis and Characterization of Ultrathin Tin-Doped Zinc Oxide Nanowires (Eur. J. Inorg. Chem. 27/2012)

      Yizheng Jin, Qing Yi, Limin Zhou, Dongdong Chen, Haiping He, Zhizhen Ye, Jinhua Hong and Chuanhong Jin

      Version of Record online: 11 SEP 2012 | DOI: 10.1002/ejic.201290083

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      The cover picture shows the synthesis of ultrathin tin-doped zinc oxide nanowires by employing an aminolysis approach. The molecular mechanism of the reactions was identified by Fourier transform infrared (FTIR) spectroscopy. This finding suggests that the introduction of group IV dopants may serve as an effective strategy to control the shape of doped ZnO nanocrystals. Details are discussed in the Short Communication by Y. Jin et al. on p. 4268 ff.

  2. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
  3. News

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
  4. Short Communications

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    1. Iron Hydrogenases

      An Air-Stable Fe3S4 Complex with Properties Similar to Those of the HOXair State of the Diiron Hydrogenases (pages 4259–4263)

      Yong Huang, Weiming Gao, Torbjörn Åkermark, Mingrun Li and Björn Åkermark

      Version of Record online: 17 AUG 2012 | DOI: 10.1002/ejic.201200632

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      An air-stable Fe3S4 complex was prepared as a mimic of the HOXair state of the active site of [FeFe]-hydrogenases. Electrochemical and photoinduced hydrogen evolution is promoted by this catalyst.

    2. NLO Materials

      Titanyl Iodate – A Promising Material for Infrared Nonlinear Optics Showing Structural Similarities with KTP (pages 4264–4267)

      Yan Suffren and Isabelle Gautier-Luneau

      Version of Record online: 23 AUG 2012 | DOI: 10.1002/ejic.201200792

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      TiO(IO3)2 was synthesized by the hydrothermal route. The acentric structure reveals alternating short and long Ti–O bonds, as observed in KTiOPO4 (KTP), which suggests significant charge transfer along the ···O–Ti–O··· chains.

    3. Doped Nanocrystals

      Synthesis and Characterization of Ultrathin Tin-Doped Zinc Oxide Nanowires (pages 4268–4272)

      Yizheng Jin, Qing Yi, Limin Zhou, Dongdong Chen, Haiping He, Zhizhen Ye, Jinhua Hong and Chuanhong Jin

      Version of Record online: 14 AUG 2012 | DOI: 10.1002/ejic.201200659

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      Ultrathin tin-doped zinc oxide (Sn-doped ZnO) nanowires with uniform diameters of 2.3 ± 0.2 nm were synthesized by a facile colloidal method. The introduction of group IV dopants may serve as an effective strategy to control the shape of doped ZnO nanocrystals. This doping procedure, based on the aminolysis approach, may be extended to the synthesis of other doped oxide nanocrystals.

  5. Full Papers

    1. Top of page
    2. Cover Picture
    3. Graphical Abstract
    4. News
    5. Short Communications
    6. Full Papers
    1. Tetranuclear Iron (III) Clusters

      A Discrete μ4-Oxido Tetranuclear Iron(III) Cluster (pages 4273–4278)

      Manas Sutradhar, Luca M. Carrella and Eva Rentschler

      Version of Record online: 14 AUG 2012 | DOI: 10.1002/ejic.201200396

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      A tetranuclear FeIII complex with a new discrete FeIII44-O) core has been synthesized from the Schiff base ligand salicyloyl hydrazide and diacetyl monooxime (H2L). Structural characterization, magnetic properties and Mössbauer spectra are reported.

    2. Imaging Agents

      A Phenylbenzothiazole Conjugate with the Tricarbonyl fac-[M(I)(CO)3]+ (M = Re, 99Tc, 99mTc) Core for Imaging of β-Amyloid Plaques (pages 4279–4286)

      Marina Sagnou, Stamatia Tzanopoulou, Catherine P. Raptopoulou, Vassilis Psycharis, Henrik Braband, Roger Alberto, Ioannis C. Pirmettis, Minas Papadopoulos and Maria Pelecanou

      Version of Record online: 9 AUG 2012 | DOI: 10.1002/ejic.201200450

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      The fac-[M(NNO)(CO)3] complex (M = Re, 99Tc, and 99mTc) conjugated to6-methyl-2-(4′-aminophenyl)benzothiazolewas synthesized, completely characterized, and biologically evaluated in vitro and in vivo as a potential amyloid imaging agent.

    3. Organometallic Chemistry

      Salen-Type Triple-Decker Trinuclear Dy3 Complexes Showing Slow Magnetic Relaxation Behavior (pages 4287–4293)

      Fan Yang, Pengfei Yan, Quan Li, Peng Chen and Guangming Li

      Version of Record online: 14 AUG 2012 | DOI: 10.1002/ejic.201200357

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      Two similar triple-decker sandwich Dy3 complexes have been isolated from the reactions of tetradentate and hexadentate salen-type ligands with Dy(NO3)3·6H2O and Dy(OAc)3·6H2O, respectively. Complex 1 exhibits antiferromagnetic coupling between Dy3+ ions but complex 2 shows ferromagnetic behavior. Both 1 and 2 exhibit slow magnetic relaxation processes of single ion origin.

    4. Precursor Chemistry

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      Zinc(II) Complexes with Dangling Functional Organic Groups (pages 4294–4300)

      Jingxia Yang, Michael Puchberger, Renzhe Qian, Christian Maurer and Ulrich Schubert

      Version of Record online: 16 AUG 2012 | DOI: 10.1002/ejic.201200558

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      Zinc(II) complexes with dangling functional organic groups were synthesized by reaction of zinc acetate with a series of bifunctional p-substituted benzene derivatives. Selective coordination to carboxylate groups was observed when the second functional group was an oxime or β-ketoimine group.

    5. Ruthenium Nitrosyl Complexes

      An Electron-Rich {RuNO}6 Complex: trans-[Ru(DMAP)4(NO)(OH)]2+ – Structure and Reactivity (pages 4301–4309)

      Nicolás Osa Codesido, Ariel G. De Candia, Thomas Weyhermüller, José A. Olabe and Leonardo D. Slep

      Version of Record online: 14 AUG 2012 | DOI: 10.1002/ejic.201200413

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      The pseudo-octahedral nitrosyl species trans-[Ru(DMAP)4(NO)(OH)]2+ [DMAP = 4-(dimethylamino)pyridine] displays properties compatible with strong backbonding interactions between dπ metal orbitals and π*NO orbitals of the (formal) NO+ (nitrosonium) ligand, which is consistent with an electron-rich ligand environment.

    6. Oxygen Atom Chirality

      Differentiation of Oxygen Atom Chirality in Copper(II) Complexes with Dipicolylamine-Derived Ligands (pages 4310–4317)

      Yuji Mikata, Tomomi Fujimoto, Noko Imai and Shin-ichi Kondo

      Version of Record online: 7 AUG 2012 | DOI: 10.1002/ejic.201200521

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      The coordination of the ether oxygen atom to copper(II) centers supported by five dipicolylamine (DPA) derived ligands has been examined. The factors that facilitate the coordination of the ether oxygen atom of these ligands to the copper center and the differentiation of chirality around the copper-coordinated oxygen atoms are discussed.

    7. Redox-Active Ligands

      The Reduction of Sterically Hindered o-Quinone and o-Iminoquinone with Gallium and “GaI” (pages 4318–4326)

      Alexandr V. Piskunov, Arina V. Maleeva, Irina N. Mescheryakova and Georgii K. Fukin

      Version of Record online: 8 AUG 2012 | DOI: 10.1002/ejic.201200535

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      The reduction of sterically hindered o-benzo- and o-iminobenzoquinone with gallium as well as with “GaI” was found to be a versatile method for the synthesis of gallium complexes that are based on these redox-active ligands. The described reactions allowed metal derivatives that contain differently charged organic ligands to be obtained depending on the reaction conditions.

    8. Germanium Clusters

      Preparation of Germyl Complexes of Osmium(II) (pages 4327–4333)

      Gabriele Albertin, Stefano Antoniutti and Jesús Castro

      Version of Record online: 14 AUG 2012 | DOI: 10.1002/ejic.201200548

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      The reaction of dihydride OsH2P4 [P = P(OEt)3] with GeCl2·dioxane, which leads to the oxo-germanium cluster Os[Ge3Cl6(OH)2]P4, is discussed. The preparation of the mixed-ligand complex Os[Ge3Cl6(OEt)(OH)4](SnCl3)P4, which contains germyl and stannyl groups, is also described.

    9. Tricarbonylrhenium(I) Complexes

      Synthesis and Characterization of fac-Re(CO)3-aspartic-N-monoacetic Acid: Structural Analogue of a Potential Renal Tracer, fac-99mTc(CO)3(ASMA) (pages 4334–4341)

      Jeffrey Klenc, Malgorzata Lipowska, Andrew T. Taylor and Luigi G. Marzilli

      Version of Record online: 13 AUG 2012 | DOI: 10.1002/ejic.201200599

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      Rhenium complexes that are structural analogues for potential technetium renal tracers are synthesized and explicitly characterized. Isolation of each coordination product through manipulation of product equilibrium helps to guide ligand design related to radiopharmaceutical applications.

    10. Metallocorroles

      BiIII–Corroles: A Versatile Platform for the Synthesis of Functionalized Corroles (pages 4342–4349)

      Lorenz Michael Reith, Michael Koenig, Clemens Schwarzinger and Wolfgang Schoefberger

      Version of Record online: 14 AUG 2012 | DOI: 10.1002/ejic.201200697

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      The BiIII ion in the center of the corrole macrocyclic ring system was employed to stabilize and protect the corrole inner core during the functionalization at the periphery (meso positions) of the π-conjugated ring system. The ease of demetalation makes BiIII–corroles attractive candidates for functionalization and subsequent demetalation to the free-base corroles.

    11. Polyazides

      Structural Characterization of Amidinatobismuth(III) Diazides (pages 4350–4355)

      Benjamin Lyhs, Dieter Bläser, Christoph Wölper, Rebekka Haack, Georg Jansen and Stephan Schulz

      Version of Record online: 17 AUG 2012 | DOI: 10.1002/ejic.201200699

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      Oligomeric amidinatobismuth(III) diazides LBi(N3)2 were synthesized by metathesis reactions of the corresponding amidinatobismuth(III) dihalides with AgN3 and structurally characterized by using single-crystal X-ray diffraction. The bonding nature of the central azide units in the tetrameric complex 2 was investigated by theoretical calculations.

    12. Phosphaferrocenes

      Unsaturated Organic Derivatives of Phosphaferrocene – Synthesis and Reactivity of Vinyl- and Alkynylphosphaferrocenes (pages 4356–4364)

      Julia Faßbender, Walter Frank and Christian Ganter

      Version of Record online: 9 AUG 2012 | DOI: 10.1002/ejic.201200588

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      Vinylphosphaferrocenes A were synthesized by olefination reactions from the parent formylphosphaferrocene, and yielded carbonyliron complexes of type C upon treatment with Fe(CO)5. The alkynyl derivative (B, R = H) was obtained by dehydrobromination of the 2-bromovinyl compound. The alkynyl species with R = H, SiMe3 were converted into the dicobaltatetrahedranes D.

    13. Ru Phosphane Complexes

      “In situ” Activation of Racemic RuII Complexes: Separation of trans and cis Species and Their Application in Asymmetric Reduction (pages 4365–4370)

      Giorgio Facchetti, Edoardo Cesarotti, Michela Pellizzoni, Daniele Zerla and Isabella Rimoldi

      Version of Record online: 14 AUG 2012 | DOI: 10.1002/ejic.201200643

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      RuII complexes with racemic atropoisomeric diphosphanes and 1,2-diphenylethane-1,2-diamine as ligands have been synthesised. trans and cis complexes were obtained with atropoisomeric ligands of low basicity. The cis and trans isomers were completely separated and their use in the asymmetric reduction of ketones was evaluated.

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