European Journal of Inorganic Chemistry

Cover image for Vol. 2013 Issue 2

January 2013

Volume 2013, Issue 2

Pages 174–314

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Cover Profile
    4. Masthead
    5. Graphical Abstract
    6. News
    7. Further Masthead
    8. Microreview
    9. Short Communication
    10. Full Papers
    1. You have free access to this content
      Developments in the Coordination Chemistry of Phosphinines (Eur. J. Inorg. Chem. 2/2013)

      Christian Müller, Leen E. E. Broeckx, Iris de Krom and Jarno J. M. Weemers

      Version of Record online: 7 JAN 2013 | DOI: 10.1002/ejic.201390006

      Thumbnail image of graphical abstract

      The cover picture shows examples of coordination compounds containing aromatic phosphorus heterocycles as ligands. It illustrates the most recent developments in the coordination chemistry of functionalized, π-accepting phosphinines. Details are discussed in the Microreview by C. Müller et al. on p. 187 ff. This paper is dedictated to Prof. Dr. P.W.N.M. van Leeuwen on the occasion of his 70th birthday.

  2. Cover Profile

    1. Top of page
    2. Cover Picture
    3. Cover Profile
    4. Masthead
    5. Graphical Abstract
    6. News
    7. Further Masthead
    8. Microreview
    9. Short Communication
    10. Full Papers
    1. You have free access to this content
      Developments in the Coordination Chemistry of Phosphinines (page 174)

      Christian Müller, Leen E. E. Broeckx, Iris de Krom and Jarno J. M. Weemers

      Version of Record online: 7 JAN 2013 | DOI: 10.1002/ejic.201201434

      Thumbnail image of graphical abstract

      The most exciting aspect is the beauty and fascination of low-coordinate phosphorus compounds...

      Read more about the story behind the cover in the Cover Profile and about the research itself on p. 187 ff.

  3. Masthead

    1. Top of page
    2. Cover Picture
    3. Cover Profile
    4. Masthead
    5. Graphical Abstract
    6. News
    7. Further Masthead
    8. Microreview
    9. Short Communication
    10. Full Papers
    1. Masthead: Eur. J. Inorg. Chem. 2/2013 (page 4)

      Version of Record online: 7 JAN 2013 | DOI: 10.1002/ejic.201390007

  4. Graphical Abstract

    1. Top of page
    2. Cover Picture
    3. Cover Profile
    4. Masthead
    5. Graphical Abstract
    6. News
    7. Further Masthead
    8. Microreview
    9. Short Communication
    10. Full Papers
  5. News

    1. Top of page
    2. Cover Picture
    3. Cover Profile
    4. Masthead
    5. Graphical Abstract
    6. News
    7. Further Masthead
    8. Microreview
    9. Short Communication
    10. Full Papers
  6. Further Masthead

    1. Top of page
    2. Cover Picture
    3. Cover Profile
    4. Masthead
    5. Graphical Abstract
    6. News
    7. Further Masthead
    8. Microreview
    9. Short Communication
    10. Full Papers
  7. Microreview

    1. Top of page
    2. Cover Picture
    3. Cover Profile
    4. Masthead
    5. Graphical Abstract
    6. News
    7. Further Masthead
    8. Microreview
    9. Short Communication
    10. Full Papers
    1. Phosphorus Chemistry

      Developments in the Coordination Chemistry of Phosphinines (pages 187–202)

      Christian Müller, Leen E. E. Broeckx, Iris de Krom and Jarno J. M. Weemers

      Version of Record online: 7 NOV 2012 | DOI: 10.1002/ejic.201200912

      Thumbnail image of graphical abstract

      We highlight recent achievements in the design of donor-functionalized, chelating 2,4,6-triarylphosphinine derivatives by the pyrylium salt route and illustrate strategies to access new neutral and cationic phosphinine-based transition metal complexes containing metal centres in various oxidation states, such as M0, MI, MII and MIII. Comparisons with isostructural nitrogen analogues are made.

  8. Short Communication

    1. Top of page
    2. Cover Picture
    3. Cover Profile
    4. Masthead
    5. Graphical Abstract
    6. News
    7. Further Masthead
    8. Microreview
    9. Short Communication
    10. Full Papers
    1. Alkali Borates

      M2Cd3B16O28 (M = Rb, Cs): Two Isostructural Alkali Cadmium Borates with a New Type of Borate Layer (pages 203–207)

      Xiaoyu Dong, Yunjing Shi, Zhongxiang Zhou, Shilie Pan, Zhihua Yang, Bingbing Zhang, Yun Yang, Zhaohui Chen and Zhenjun Huang

      Version of Record online: 5 DEC 2012 | DOI: 10.1002/ejic.201201291

      Thumbnail image of graphical abstract

      M2Cd3B16O28 (M = Rb, Cs) consists of two-dimensional infinite (B16O34) SrBBO-like double layers, which are built up by BO3 triangles and BO4 tetrahedra.

  9. Full Papers

    1. Top of page
    2. Cover Picture
    3. Cover Profile
    4. Masthead
    5. Graphical Abstract
    6. News
    7. Further Masthead
    8. Microreview
    9. Short Communication
    10. Full Papers
    1. Ru(II)-DNA Photochemistry

      What Are the Parameters Controlling Inter- vs. Intra-Strand DNA Photodamage with Ru-TAP Oligonucleotides? (pages 208–216)

      Stéphane Le Gac, Mathieu Surin, Eric Defrancq, Cécile Moucheron and Andrée Kirsch-De Mesmaeker

      Version of Record online: 21 NOV 2012 | DOI: 10.1002/ejic.201201019

      Thumbnail image of graphical abstract

      Selective photodamaging: Ru-TAP complexes anchored to a guanine (G) containing ODN probe behave as “intelligent” DNA photoreagents, provided that a fine tuning of probe–target interactions could be reached. Selective DNA photodamage results from judicious selection of complex and probe/target sequence compatibilities.

    2. Arene–Ruthenium(II) Complexes

      Areneruthenium(II) Complexes Containing Bispyrazolylmethane Ligands: Effect of the Ligand Substituents on the Formation of an Isomer and on the Fluxional Behaviour (pages 217–227)

      M. Carmen Carrión, Francisco Sepúlveda, Félix A. Jalón, Blanca R. Manzano and Ana M. Rodríguez

      Version of Record online: 20 NOV 2012 | DOI: 10.1002/ejic.201200884

      Thumbnail image of graphical abstract

      New areneruthenium complexes with the ligand 2-methoxyphenyl-bis(3,5-dimethylpyrazol-1-yl)methane have been synthesized. The steric hindrance from the presence of the methoxy and methyl groups allows the formation of an unprecedented isomer, the detection of restricted rotation of some rings and the improvement of the catalytic behaviour in hydrogen transfer of ketones in the absence of base.

    3. Photochemistry

      Visible-Light Harvesting PtII Complexes as Singlet Oxygen Photosensitizers for Photooxidation of 1,5-Dihydroxynaphthalene (pages 228–231)

      Wenting Wu, Pei Yang, Lihua Ma, Jacques Lalevée and Jianzhang Zhao

      Version of Record online: 21 NOV 2012 | DOI: 10.1002/ejic.201200665

      Thumbnail image of graphical abstract

      Cyclometalated PtII complexes that show strong visible-light absorption and long-lived triplet excited states were used as efficient singlet oxygen (1O2) sensitizers for the photooxidation of 1,5-dihydroxynaphthalene (DHN). The photooxidation velocity of the cyclometalated PtII complex is 4.4 times that of the conventional IrIII complex triplet photosensitizer.

    4. Coordination Chemistry

      Synthesis, Characterization, Reactivity, and Linkage Isomerization of Ru(Cl)2(L)(DMSO)2 Complexes (pages 232–240)

      Stephan Roeser, Somnath Maji, Jordi Benet-Buchholz, Josefina Pons and Antoni Llobet

      Version of Record online: 21 NOV 2012 | DOI: 10.1002/ejic.201200809

      Thumbnail image of graphical abstract

      Isomeric [Ru(Cl)2(L)(DMSO)2] complexes [L = 5-phenyl-3-(2-pyridyl)-1H-pyrazole, DMSO = dimethyl sulfoxide] are reported together with their structures, spectroscopic properties, electrochemistry, and S-to-O linkage isomerization. Additionally, a photolytic reaction of both isomers in chloroform is reported, which results in the formation of a third complex, [Ru(Cl)3(L)­(DMSO)].

    5. Hydrotalcite with V(III) and V(V)

      VO2+ Reaction with Hydrotalcite and Hydrotalcite-Derived Oxide: The Effect of the Vanadium Loading on the Structure of Catalyst Precursors and on the Vanadium Species (pages 241–247)

      Fernando Rabello de Castro, Yiu Lau Lam, Marcelo Hawrylak Herbst, Marcelo Maciel Pereira, Thiago Crispim da Silva, Narcis Homs and Pilar Ramirez de la Piscina

      Version of Record online: 21 NOV 2012 | DOI: 10.1002/ejic.201200860

      Thumbnail image of graphical abstract

      Interaction of VO2+ with Mg6Al2(OH)16(CO3)·nH2O gives a hydrotalcite-like compound containing VIII in the layers and vanadate(V) species in the interlayers. When VO2+ interacts with the mixed derived oxide, VIV is easily oxidised by air, and supported oligomerised VV species are obtained.

    6. In–Sn Ordering

      Effect of In–Sn Ordering on Semiconducting Properties in InSnCo3S2 – X-ray, 119Sn Mößbauer Spectroscopy, and DFT Studies (pages 248–255)

      Jan Rothballer, Frederik Bachhuber, Florian Pielnhofer, Falko M. Schappacher, Rainer Pöttgen and Richard Weihrich

      Version of Record online: 21 NOV 2012 | DOI: 10.1002/ejic.201200892

      Thumbnail image of graphical abstract

      InSnCo3S2 shows ordering of In and Sn, depending on which the compound behaves like a metal or like an insulator – as shown by combined XRD, Mößbauer spectroscopy, and DFT studies

    7. Graphene-Based Nanocomposites

      Optical Properties and a Simple and General Route for the Rapid Syntheses of Reduced Graphene Oxide–Metal Sulfide Nanocomposites (pages 256–262)

      Song Bai, Xiaoping Shen, Guoxing Zhu, Hu Zhou, Huan Xu, Guohua Fu and Zhefei Ye

      Version of Record online: 20 NOV 2012 | DOI: 10.1002/ejic.201200905

      Thumbnail image of graphical abstract

      A general microwave route is developed for the synthesis of reduced graphene oxide (RGO)–metal sulfide nanocomposites, and a mechanism for the formation of the nanocomposites is proposed. The RGO–metal sulfide nanocomposites are photoluminescent in the UV/Vis and near IR (NIR) regions. This method could be extended to the synthesis of other RGO–metal chalcogenide nanocomposites.

    8. Molecular Conductance

      Synthesis, Structure, Magnetism, and Single Molecular Conductance of Linear Trinickel String Complexes with Sulfur-Containing Ligands (pages 263–268)

      Ching-Chun Yang, Isiah Po-Chun Liu, Yu-Ju Hsu, Gene-Hsiang Lee, Chun-hsien Chen and Shie-Ming Peng

      Version of Record online: 21 NOV 2012 | DOI: 10.1002/ejic.201200934

      Thumbnail image of graphical abstract

      A new ligand, (4-methylpyridyl)thiazolylamine (Hmpta), and related trinuclear metal string complexes have been synthesized and characterized. Their structures, magnetic properties, and conductances have been investigated by single crystal X-ray diffraction, superconducting quantum interference device (SQUID) magnetometry, and scanning tunneling microscopy.

    9. Nanostructures

      Synthesis of Guanosine 5′-Monophosphate (GMP)-Mediated Ag/CdS Nanohybrids: Their Self-Assembly and Optoelectronic Properties (pages 269–279)

      Anil Kumar, Vidhi Chaudhary and Vinit Kumar

      Version of Record online: 26 NOV 2012 | DOI: 10.1002/ejic.201200943

      Thumbnail image of graphical abstract

      The presence of Ag in a guanosine 5′-monophosphate (GMP)-mediated Ag/CdS nanohybrid induces self-assembly through supramolecular interaction and enhances the optoelectronic properties of CdS.

    10. Coordination Polymers

      A Series of 1D, 2D, and 3D Coordination Polymers Based on Flexible 3-Carboxy-1-Carboxymethyl-2-Oxidopyridinium and Different N-Donor Ligands – Syntheses, Structures, and Luminescent Properties (pages 280–292)

      Ying-Qi Yang, Jin Yang, Wei-Qiu Kan, Yan Yang, Jiao Guo and Jian-Fang Ma

      Version of Record online: 20 NOV 2012 | DOI: 10.1002/ejic.201200998

      Thumbnail image of graphical abstract

      A series of coordination polymers constructed with different N-donor ligands and 3-carboxy-1-carboxymethyl-2-oxidopyridinium have been successfully prepared under hydrothermal conditions, and their thermal and photoluminescent properties have also been investigated.

    11. Magnetism in Coordination Polymers

      One-Pot Synthesis of Two Magnetic Coordination Polymers with Different Structures Due to the Connectivity of Sulfate Ions (pages 293–298)

      Kang-Yu Zou, Jun-Long Zhao, Chao Liu, Zhang Wang and Zuo-Xi Li

      Version of Record online: 21 NOV 2012 | DOI: 10.1002/ejic.201200706

      Thumbnail image of graphical abstract

      Two new coordination polymers isolated from the same one-pot synthesis have different dimensional frameworks, illustrating the importance of the counterion in the structure of coordination polymers. Their magnetic properties have been studied to give the exchange coupling constant by fitting the experimental data.

    12. Metallopolymeric Materials

      Syntheses and Coordination Studies of 2-(Phosphanylmethyl)pyridine Dioxide toward Silver (I) (pages 299–308)

      Daniel A. Padron and Kevin K. Klausmeyer

      Version of Record online: 26 NOV 2012 | DOI: 10.1002/ejic.201200793

      Thumbnail image of graphical abstract

      A planar hexasilver cluster and two coordination polymers are isolated upon reaction of the N,P-dioxide of 2-(phosphanylmethyl)pyridine with silver(I) and its trifluoroacetate, triflate, and BF4 salts.

    13. Fullerenes

      The Formation of 3D Fullerene Packing in Molecular Complexes of C60 and C70 with Metal Diethyl Dithiophosphates: [M(dedtp)2]·[C60(70)]3 (M = NiII, CoII, and VIVO) (pages 309–314)

      Dmitri V. Konarev, Leokadiya V. Zorina, Salavat S. Khasanov and Rimma N. Lyubovskaya

      Version of Record online: 6 NOV 2012 | DOI: 10.1002/ejic.201200822

      Thumbnail image of graphical abstract

      A series of molecular complexes [M(dedtp)2]·[C60(70)]3 (M = NiII, CoII, and VIVO; 14; dedtp=diethyl dithiophosphate) were obtained and structurally characterized. The fullerenes in the complexes pack in a three-dimensional manner. Both [NiII(dedtp)2] and [CoII(dedtp)2] have square-planar geometry around the metal centers, whereas vanadium atoms in [VIVO(dedtp)2] exhibit a square-pyramidal environment.

SEARCH

SEARCH BY CITATION