European Journal of Inorganic Chemistry

Cover image for Vol. 2013 Issue 36

December 2013

Volume 2013, Issue 36

Pages 6062–6174

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Cover Profile
    4. Masthead
    5. Graphical Abstract
    6. News
    7. Further Masthead
    8. Short Communication
    9. Full Papers
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      Proton and Electron Transfer to a Polymer-Supported Nitrido Molybdenum(VI) Complex (Eur. J. Inorg. Chem. 36/2013)

      Anica Wünsche von Leupoldt, Christoph Förster, Tobias J. Fiedler, Nicolas H. Bings and Katja Heinze

      Version of Record online: 9 DEC 2013 | DOI: 10.1002/ejic.201390164

      Thumbnail image of graphical abstract

      The cover picture shows the reactive EPR-active imido molybdenum(V) intermediate that has been obtained by protonation followed by reduction of the nitrido molybdenum(VI) precursor confined within a polymeric environment. By immobilizing the precursor, its deactivation by intermolecular reactions is prevented. This system models some steps in the final part of the Schrock–Yandulov cycle, which results in the release of ammonia from nitrido complexes. Details are discussed in the article by K. Heinze et al. on p. 6079 ff. For more on the story behind the cover research, see the Cover Profile.

  2. Cover Profile

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    3. Cover Profile
    4. Masthead
    5. Graphical Abstract
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    1. You have free access to this content
      Proton and Electron Transfer to a Polymer-Supported Nitrido Molybdenum(VI) Complex (page 6062)

      Anica Wünsche von Leupoldt, Christoph Förster, Tobias J. Fiedler, Nicolas H. Bings and Katja Heinze

      Version of Record online: 9 DEC 2013 | DOI: 10.1002/ejic.201301461

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      The most exciting aspect of functional biomimetic chemistry is the opportunity to watch nature managing reactions, then distill out the principle and create completely new compounds/materials for the desired task by using different elements and novel arrangements by synthetic chemical means...

      Read more about the story behind the cover in the Cover Profile and about the research itself on p. 6079 ff.

  3. Masthead

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    3. Cover Profile
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  4. Graphical Abstract

    1. Top of page
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    4. Masthead
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  5. News

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  7. Short Communication

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    1. Group 8 Transition Metal Complexes

      Group 8 Transition Metal Complexes of the Tripodal Triphosphino Ligands PhSi(CH2PR2)3 (R = Ph, iPr) (pages 6075–6078)

      Felix Neumeyer, Michael I. Lipschutz and T. Don Tilley

      Version of Record online: 19 NOV 2013 | DOI: 10.1002/ejic.201301074

      Thumbnail image of graphical abstract

      Complexes of iron, ruthenium, and osmium with the neutral tridentate tripodal phosphine ligands PhSi(CH2PPh2)3 and PhSi(CH2PiPr2)3 show tetrahedral coordination for iron and form cationic dimeric octahedral complexes with the heavier homologues ruthenium and osmium.

  8. Full Papers

    1. Top of page
    2. Cover Picture
    3. Cover Profile
    4. Masthead
    5. Graphical Abstract
    6. News
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    1. Polymer-Supported Complexes

      Proton and Electron Transfer to a Polymer-Supported Nitrido Molybdenum(VI) Complex (pages 6079–6090)

      Anica Wünsche von Leupoldt, Christoph Förster, Tobias J. Fiedler, Nicolas H. Bings and Katja Heinze

      Version of Record online: 16 OCT 2013 | DOI: 10.1002/ejic.201301156

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      A polymer-immobilized analogue of the Schrock–Yandulov nitrido triamidoamine molybdenum(VI) complex is prepared from a polymer-anchored triamidoamine ligand and [MoCl3N(CH3CN)]4. Protonation of the nitrido ligand yields the corresponding imido complex, which can be reduced to the EPR-active molybdenum(V) complex by cobaltocene. This system models two steps of the Schrock–Yandulov cycle.

    2. Solid-State Metathesis

      Synthesis and Characterization of the First Tetracyanamidogallate (pages 6091–6096)

      Markus Kalmutzki, Markus Ströbele, Scott Kroeker, John E. C. Wren and H. Jürgen Meyer

      Version of Record online: 12 NOV 2013 | DOI: 10.1002/ejic.201301090

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      The employment of the solid-state metathesis reaction has been used for the development of the tetracyanamidogallate compound LiSr2[Ga(CN2)4], the structure of which contains infinite chains of corner-sharing [LiGa(CN2)4]4– tetrahedra.

    3. Octamolybdate Hybrid

      Two Hybrid Compounds Based on Octamolybdate and an N-Donor Multidentate Ligand: Syntheses, Structures, and Properties (pages 6097–6102)

      Shi Zhou, Ya-Guang Chen, Bo Liu, Xiao-Min Li and Dong-Xiao Wang

      Version of Record online: 19 NOV 2013 | DOI: 10.1002/ejic.201301176

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      Under similar synthetic conditions, two metal ions, Ag+ and Ni2+, lead to rather different structures because of their different properties, including electronic configuration, oxidation state, and acid/base hardness. The softening of the acidity of MoVI after combining five oxygen atoms results in the formation of an Mo–N bond, and this gives a modified γ-Mo8O264– structure with a tridentate N ligand.

    4. Thiophosphinoyl Complexes

      Synthesis and Structural Characterization of Thiophosphinoyl Late-Transition-Metal and Divalent Lanthanide Complexes Derived from 2-Quinolyl-Linked (Thiophosphorano)methane (pages 6103–6110)

      Wing-Por Leung, Yuk-Chi Chan and Thomas C. W. Mak

      Version of Record online: 14 NOV 2013 | DOI: 10.1002/ejic.201300797

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      A series of homoleptic manganese(II), iron(II), cobalt(II), and divalent ytterbium and europium complexes supported by 2-quinolyl-linked (thiophosphorano)methane have been synthesized and characterized. The structures of all compounds have been characterized by X-ray crystallography.

    5. Coordination Polymers

      A Series of Exceptionally Robust Luminescent Coordination Polymers Based on a Bipyridyldicarboxylate Ligand and Rare-Earth-Metal Ions (pages 6111–6118)

      Liangjun Li, Sifu Tang, Xiaoxia Lv, Jinjun Cai, Chao Wang and Xuebo Zhao

      Version of Record online: 14 NOV 2013 | DOI: 10.1002/ejic.201301010

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      A series of isostructural coordination polymers based on rare-earth-metal ions and a bipyridyldicarboxylate ligand were synthesized and characterized. The photoluminescent properties, thermal stability, and water resistance of these coordination polymers were investigated.

    6. Graphene-Based Nanocomposites

      Graphene Oxide Modified Ag2O Nanocomposites with Enhanced Photocatalytic Activity under Visible-Light Irradiation (pages 6119–6125)

      Zhenyuan Ji, Xiaoping Shen, Jinglei Yang, Yuling Xu, Guoxing Zhu and Kangmin Chen

      Version of Record online: 7 NOV 2013 | DOI: 10.1002/ejic.201301105

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      A novel Ag2O/GO photocatalyst has been successfully synthesized by a facile solution route. The nanocomposites exhibit remarkably enhanced photocatalytic activity in comparison with bare Ag2O. The kinetics and mechanism of the photocatalytic reaction are discussed.

    7. Core–Shell Nanoparticles

      A Facile Synthesis of Multifunctional Iron Oxide@Ag Core–Shell Nanoparticles and Their Catalytic Applications (pages 6126–6136)

      Geetu Sharma and Pethaiyan Jeevanandam

      Version of Record online: 15 NOV 2013 | DOI: 10.1002/ejic.201301193

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      Iron oxide@Ag core–shell nanoparticles have been synthesized by an easy and facile thermal decomposition approach. They serve as better catalysts for the reduction of 4-nitrophenol and methylene blue compared to individual constituents.

    8. Europium(III) Complexes

      Substituted Phenanthrolines as Antennae in Luminescent EuIII Complexes (pages 6137–6146)

      Sebastiaan Akerboom, Jos J. M. H. van den Elshout, Ilpo Mutikainen, Maxime A. Siegler, Wen Tian Fu and Elisabeth Bouwman

      Version of Record online: 15 NOV 2013 | DOI: 10.1002/ejic.201301000

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      Eight new EuIII complexes with 1,10-phenanthroline ligands substituted on the 2-position have been prepared, analyzed, and the photoluminescence properties studied. The complex with the 2-chloro substituent exhibits bright photoluminescence with a high quantum yield of 78 %. The complex with the 2-amino substituent is nonluminescent.

    9. Coordination Polymers

      Cation Exchange in Layered Copper(II) Coordination Polymers (pages 6147–6155)

      Krapa Shankar, Babulal Das and Jubaraj B. Baruah

      Version of Record online: 19 NOV 2013 | DOI: 10.1002/ejic.201300906

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      Protonated cytidinium ions held in anionic layers of copper(II) 2,3-pyridinedicarboxylate are exchanged by various cations to form modified layered structures with different interlayer spacings.

    10. Bromination

      Magnetic-Nanoparticle-Supported 2,2′-Bis[3-(triethoxysilyl)propyl]imidazolium-Substituted Diethyl Ether Bis(tribromide): A Convenient Recyclable Reagent for Bromination (pages 6156–6163)

      Liqiang Wu and Zhikui Yin

      Version of Record online: 12 NOV 2013 | DOI: 10.1002/ejic.201300755

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      A new maghemite nanoparticle bromination reagent has been prepared. The nanoparticle reagent was obtained with good loading levels and has been successfully used for the efficient bromination of a wide range of alkenes, alkynes, ketones, and aromatic substrates.

    11. Palladium–Indium Selenides

      Pd17In4Se4, a Metal-Rich Palladium–Indium Selenide with an Open-Framework Structure (pages 6164–6169)

      Elena Yu. Zakharova, Andrei V. Churakov, Thomas Doert and Alexey N. Kuznetsov

      Version of Record online: 19 NOV 2013 | DOI: 10.1002/ejic.201300970

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      We report a palladium–indium selenide with an open framework, Pd17In4Se4, which belongs to a new type of structure, which is based on the [Pd12In] cuboctahedra featuring multicentered Pd–In bonds.

    12. Thorium Oxalates

      Spectroscopic Studies and Crystal Structures of Double Thorium(IV) Oxalates with Sodium Ions (pages 6170–6174)

      Yingjie Zhang, Mohan Bhadbhade, Inna Karatchevtseva, Jiabin Gao, Jason R. Price and Gregory R. Lumpkin

      Version of Record online: 8 NOV 2013 | DOI: 10.1002/ejic.201301099

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      The synthesis and characterization of two new double thorium oxalates with Na+ ions are reported. The crystal structures comprise either infinite [Th(μ2-C2O4)2(C2O4)3]n4n chains or [Th22-C2O4)(C2O4)8]10– dimers with Na+ ions and water molecules linking the structures into three dimensions. The dimeric complex is the first tetravalent actinide oxalato complex.

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