European Journal of Lipid Science and Technology

Cover image for Vol. 116 Issue 1

Special Issue: Fats and oils as renewable feedstock for the chemical industry

January 2014

Volume 116, Issue 1

Pages 1–96

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Editorial Board
    4. In this Issue
    5. Contents
    6. Editorial
    7. Review Article
    8. Research Articles
    1. You have free access to this content
  2. Editorial Board

    1. Top of page
    2. Cover Picture
    3. Editorial Board
    4. In this Issue
    5. Contents
    6. Editorial
    7. Review Article
    8. Research Articles
    1. You have free access to this content
  3. In this Issue

    1. Top of page
    2. Cover Picture
    3. Editorial Board
    4. In this Issue
    5. Contents
    6. Editorial
    7. Review Article
    8. Research Articles
    1. You have free access to this content
      In this issue

      Version of Record online: 3 JAN 2014 | DOI: 10.1002/ejlt.201470003

  4. Contents

    1. Top of page
    2. Cover Picture
    3. Editorial Board
    4. In this Issue
    5. Contents
    6. Editorial
    7. Review Article
    8. Research Articles
    1. You have free access to this content
      Contents: Eur. J. Lipid Sci. Technol. 1∕2014

      Version of Record online: 3 JAN 2014 | DOI: 10.1002/ejlt.201470004

  5. Editorial

    1. Top of page
    2. Cover Picture
    3. Editorial Board
    4. In this Issue
    5. Contents
    6. Editorial
    7. Review Article
    8. Research Articles
    1. You have free access to this content
      Fats and oils as renewable feedstock for the chemical industry (page 1)

      Jürgen O. Metzger and Michael A. R. Meier

      Version of Record online: 3 JAN 2014 | DOI: 10.1002/ejlt.201300486

  6. Review Article

    1. Top of page
    2. Cover Picture
    3. Editorial Board
    4. In this Issue
    5. Contents
    6. Editorial
    7. Review Article
    8. Research Articles
    1. 2-(Vinyloxy)ethyl soyate as a versatile platform chemical for coatings: An overview (pages 2–15)

      Samim Alam, Harjoyti Kalita, Anurad Jayasooriya, Satyabrata Samanta, James Bahr, Andrey Chernykh, Michael Weisz and Bret J. Chisholm

      Version of Record online: 19 SEP 2013 | DOI: 10.1002/ejlt.201300217

      Thumbnail image of graphical abstract

      A schematic of the process used to produce 2-VOES.

  7. Research Articles

    1. Top of page
    2. Cover Picture
    3. Editorial Board
    4. In this Issue
    5. Contents
    6. Editorial
    7. Review Article
    8. Research Articles
    1. Towards a better understanding of how to improve lipase-catalyzed reactions using deep eutectic solvents based on choline chloride (pages 16–23)

      Erwann Durand, Jérôme Lecomte, Bruno Baréa and Pierre Villeneuve

      Version of Record online: 21 OCT 2013 | DOI: 10.1002/ejlt.201300246

      Thumbnail image of graphical abstract

      Deep eutectic solvents (DES) are generally claimed to be renewable and environmentally friendly. Nevertheless, this classification depends entirely on the nature of the selected components. The DES derived from choline chloride combined with a safe hydrogen-bond donor, such as urea, seemed ideal for the design of eco-friendly processes. In mixtures with water, it has been successfully used for lipase-catalyzed reactions of polar substrates.

    2. Degradable polyurethane nanoparticles containing vegetable oils (pages 24–30)

      Alexsandra Valério, Sandro R. P. da Rocha, Pedro H. H. Araújo and Claudia Sayer

      Version of Record online: 14 NOV 2013 | DOI: 10.1002/ejlt.201300214

      Thumbnail image of graphical abstract

      Using natural renewable oil as polyol to obtain polyurethane nanoparticles combined with incorporation of other vegetable oil therein showed good results in terms of molar mass and nanoparticle size. The simple and straightforward procedure to prepare polyurethane nanoparticles containing vegetable oils by step polymerization in miniemulsion contributes to improve the application range of these polymers.

    3. Renewable co-polymers derived from castor oil and limonene (pages 31–36)

      Maulidan Firdaus, Michael A. R. Meier, Ursula Biermann and Jürgen O. Metzger

      Version of Record online: 22 OCT 2013 | DOI: 10.1002/ejlt.201300206

      Thumbnail image of graphical abstract

      Renewable monomers were polymerized via thiol-ene chemistry and subsequently oxidized to polysulfones, which significantly improved their thermal properties.

    4. Emulsion copolymerization of styrene and acrylated methyl oleate (pages 37–43)

      Alan T. Jensen, Claudia Sayer, Pedro H. H. Araújo and Fabricio Machado

      Version of Record online: 17 SEP 2013 | DOI: 10.1002/ejlt.201300212

      Thumbnail image of graphical abstract

      Modified oleic acid has been successfully employed in emulsion polymerization process to synthesize styrene/acrylated methyl oleate copolymers, presenting good storage stability, low glass transition temperatures, and relatively high molar masses.

    5. A more sustainable Wohl–Ziegler bromination: Versatile derivatization of unsaturated FAMEs and synthesis of renewable polyamides (pages 44–51)

      Matthias Winkler, Michael Steinbiß and Michael A. R. Meier

      Version of Record online: 17 JUN 2013 | DOI: 10.1002/ejlt.201300126

      Thumbnail image of graphical abstract

      Within this contribution, a more sustainable procedure for the Wohl–Ziegler bromination of unsaturated FAME was investigated. The resulting allylic bromide functional FAMEs were used for elimination reactions to prepare conjugated fatty acids. Moreover, the fatty acid derived allylic bromides were used as initiators for atom transfer radical polymerization (ATRP). Furthermore, the synthesis of AB-type polyamide monomers was accomplished by a complementary hydrobromination of FAME and subsequent modification. The obtained polyamides were characterized by GPC, NMR, and DSC analysis.

    6. Hydroboration of unsaturated fatty acid methyl esters and conversion of the boron adducts* (pages 52–62)

      Theodor Lucas and Hans J. Schäfer

      Version of Record online: 11 DEC 2013 | DOI: 10.1002/ejlt.201300220

      Thumbnail image of graphical abstract

      By hydroboration–oxidation methyl 10-undecenoate, methyl oleate, methyl ricinoleate and methyl linoleate are converted into hydroxy- and dihydroxyesters in 82–92% yield. Hydroboration of oleic acid and subsequent isomerization of the organoborane by heating to 220°C leads after oxidative work-up to 70% of 1,4-octadecanediol. Fatty ester groups of organoboranes can be attached to the carbonyl-equivalent: dichloromethyl methyl ether (DCME) to afford in one step and 55–80% yield dimers of fatty esters with an inserted ketocarbonyl group.

    7. New biobased epoxy materials from cardanol (pages 63–73)

      Fanny Jaillet, Emilie Darroman, Amédée Ratsimihety, Rémi Auvergne, Bernard Boutevin and Sylvain Caillol

      Version of Record online: 3 SEP 2013 | DOI: 10.1002/ejlt.201300193

      Thumbnail image of graphical abstract

      Commercial epoxidized cardanol from cashew nut shell liquid was thoroughly analyzed using 1H and 13C NMR, SEC and titration in order to determine the structure. This epoxidized cardanol was reacted with isophorone diamine and Jeffamine D400 diamine in order to synthesize epoxy networks that exhibit interesting mechanical and thermal properties for coatings.

    8. Reduction of high oleic sunflower oil to glyceryl trioleyl ether (pages 74–79)

      Ursula Biermann and Jürgen O. Metzger

      Version of Record online: 18 NOV 2013 | DOI: 10.1002/ejlt.201300320

      Thumbnail image of graphical abstract

      A most efficient and sustainable reaction protocol allows the conversion of “High oleic” sunflower oil into the respective triether using GaBr3 (0.005–0.01 eq. Ga/ester functionality) as catalysts and stoichiometric amounts of 1,1,3,3-tetramethyldisiloxane (TMDS) as reducing agent in solvent-free reaction.

    9. Potassium fluoride impregnated CaO/NiO: An efficient heterogeneous catalyst for transesterification of waste cottonseed oil (pages 80–88)

      Mandeep Kaur and Amjad Ali

      Version of Record online: 18 NOV 2013 | DOI: 10.1002/ejlt.201300213

      Thumbnail image of graphical abstract

      The prepared catalyst 20-KF/CaO/NiO-700 was able to complete the transesterification (>99% FAMEs yield) of waste cottonseed oil (WCO) during four successive catalytic runs. However, in fifth catalytic run, partial conversion was achieved. Thus catalyst shows reasonably good recyclability toward the transesterification of the WCO.

    10. Efficient and sensitive method for the quantification of saturated monoacylglycerols in biodiesel by gas chromatography–mass spectrometry (pages 89–96)

      Lena Hirschegger, Sigurd Schober and Martin Mittelbach

      Version of Record online: 11 DEC 2013 | DOI: 10.1002/ejlt.201300285

      Thumbnail image of graphical abstract

      Representative gas chromatogram of biodiesel from waste animal fats. The main saturated MAGs could be separated and identified unambiguously. As internal standard glycerol monononadecanoate (1-C19:0) was used. The LOD of the method was 8–20 ng/g and the LOQ was 26–61 ng/g.

SEARCH

SEARCH BY CITATION