Full Paper

Synthesis of Phenyl Arylsulfonyl-alkyl-dithiocarbamates and Their Hydrolytic Reactivity in Hydroxide and Hydroperoxide Media

  1. Fátima Norberto1,2,
  2. M. Eduarda M. Araújo1,
  3. Lídia Santos1,
  4. Marta S. P. Jaime1,
  5. Pedro M. V. Mateus1,
  6. Pablo Hervés3

Article first published online: 15 SEP 2005

DOI: 10.1002/ejoc.200500248

Issue

European Journal of Organic Chemistry

European Journal of Organic Chemistry

Volume 2005, Issue 21, pages 4710–4714, November 2005

Additional Information

How to Cite

Norberto, F., Araújo, M. E. M., Santos, L., Jaime, M. S. P., Mateus, P. M. V. and Hervés, P. (2005), Synthesis of Phenyl Arylsulfonyl-alkyl-dithiocarbamates and Their Hydrolytic Reactivity in Hydroxide and Hydroperoxide Media. European Journal of Organic Chemistry, 2005: 4710–4714. doi: 10.1002/ejoc.200500248

Author Information

  1. 1

    CQB and Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, 1749-016 Lisboa, Portugal, Fax: +351-217500088

  2. 2

    Departamento de Ciências da Saúde, Universidade Lusófona de Humanidades e Tecnologia, Av. Campo Grande, 376-1749, Lisboa, Portugal

  3. 3

    Departamento de Química Física, Facultad de Ciencias, Universidade de Vigo, Apartado 874, Vigo (Pontevedra), España

Publication History

  1. Issue published online: 17 OCT 2005
  2. Article first published online: 15 SEP 2005
  3. Manuscript Received: 7 APR 2005

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Keywords:

  • Phenyl arylsulfonyl-alkyl-dithiocarbamates;
  • Kinetics;
  • Hydrolysis;
  • Nucleophilic catalysis;
  • Hydroperoxide effectiveness

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Abstract

Eight previously unreported phenyl arylsulfonyl-alkyl-dithiocarbamates were synthesized by treatment of arylsulfonamides with phenyl chlorodithioformate in an adaptation of a general amine acylation method. A kinetic investigation of their alkaline hydrolysis was performed and the experimental data are discussed. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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