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Ti-Mediated Synthesis of Aminocyclopropyl-Substituted Carbohydrates

  1. Christophe Laroche,
  2. Jean-Bernard Behr,
  3. Jan Szymoniak,
  4. Philippe Bertus,
  5. Richard Plantier-Royon

Article first published online: 12 OCT 2005

DOI: 10.1002/ejoc.200500406

Issue

European Journal of Organic Chemistry

European Journal of Organic Chemistry

Volume 2005, Issue 23, pages 5084–5088, December 2005

Additional Information

How to Cite

Laroche, C., Behr, J.-B., Szymoniak, J., Bertus, P. and Plantier-Royon, R. (2005), Ti-Mediated Synthesis of Aminocyclopropyl-Substituted Carbohydrates. European Journal of Organic Chemistry, 2005: 5084–5088. doi: 10.1002/ejoc.200500406

Author Information

  1. Laboratoire “ Réactions Sélectives et Applications ”, Université de Reims Champagne-Ardenne, UMR URCA/CNRS 6519, UFR Sciences, B. P. 1039, 51687 Reims cedex 2, France, Fax: +33-3-26913166

Publication History

  1. Issue published online: 15 NOV 2005
  2. Article first published online: 12 OCT 2005
  3. Manuscript Received: 7 JUN 2005

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Keywords:

  • Carbohydrates;
  • Cyanides;
  • Cyclopropanes;
  • Grignard reagents;
  • Titanium

Graphical Abstract

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Abstract

Carbohydrates bearing aminocyclopropyl moieties were conveniently prepared from the corresponding nitriles by titanium-mediated addition of Grignard reagents. A wide range of protective groups are tolerated. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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