Full Paper

A Convenient Route to 2-Hydroxy- and 2,15-Dihydroxyhexahelicene

  1. Filip Teplý,
  2. Irena G. Stará,
  3. Ivo Starý,
  4. Adrian Kollárovič,
  5. Daniel Luštinec,
  6. Zuzana Krausová,
  7. David Šaman,
  8. Pavel Fiedler

Article first published online: 27 JUL 2007

DOI: 10.1002/ejoc.200700381

Issue

European Journal of Organic Chemistry

European Journal of Organic Chemistry

Volume 2007, Issue 25, pages 4244–4250, September 2007

Additional Information

How to Cite

Teplý, F., Stará, I. G., Starý, I., Kollárovič, A., Luštinec, D., Krausová, Z., Šaman, D. and Fiedler, P. (2007), A Convenient Route to 2-Hydroxy- and 2,15-Dihydroxyhexahelicene. Eur. J. Org. Chem., 2007: 4244–4250. doi: 10.1002/ejoc.200700381

Author Information

  1. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo n. 2, 16610 Prague 6, Czech Republic, Fax: +420-220-183-133

Publication History

  1. Issue published online: 10 AUG 2007
  2. Article first published online: 27 JUL 2007
  3. Manuscript Received: 29 APR 2007

Funded by

  • FP6. Grant Number: FP6-015847
  • Grant Agency of the Czech Republic. Grant Number: 203/06/1792
  • Ministry of Education of the Czech Republic. Grant Numbers: LC512, 2005-06-041-1

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Keywords:

  • Alkynes;
  • Arenes;
  • Cyclotrimerisation;
  • Fused-ring systems

Abstract

2-Hydroxy- and 2,15-dihydroxyhexahelicene were synthesised from simple benzene and naphthalene building blocks by intramolecular CoI- or Ni0-catalysed [2+2+2] cycloisomerisation of CH3O-substituted aromatic triynes. This approach avoids vexing photodehydrocyclisation of stilbene-type precursors, providing thus a useful alternative to classical procedures. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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