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Towards Allopumiliotoxins: A Concise Synthesis of the Indolizidine Core

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Abstract

The common bicyclic indolizidine core present in several allopumiliotoxins was synthesized by the sequential use of a Crimmins' aldol reaction, an SOCl2-mediated SNi displacement, and an intramolecular nucleophilic acyl substitution (INAS) as the key transformations.

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