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Efficient Preparation of Anhydrous Metallic Triflates and Triflimides under Ultrasonic Activation

Authors

  • Nathalie Legrave,

    1. Institut de Chimie de Nice, Université de Nice-Sophia Antipolis, CNRS, UMR 7272, Faculté des Sciences, Parc Valrose, 06108 Nice cedex 2, France, Fax: +33-4-92076189
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  • Audrey Couhert,

    1. Institut de Chimie de Nice, Université de Nice-Sophia Antipolis, CNRS, UMR 7272, Faculté des Sciences, Parc Valrose, 06108 Nice cedex 2, France, Fax: +33-4-92076189
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  • Sandra Olivero,

    1. Institut de Chimie de Nice, Université de Nice-Sophia Antipolis, CNRS, UMR 7272, Faculté des Sciences, Parc Valrose, 06108 Nice cedex 2, France, Fax: +33-4-92076189
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  • Jean-Roger Desmurs,

    1. CDP-Innovation, G2C Business Center, 63 rue André Bollier, Lyon, France
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  • Elisabet Duñach

    1. Institut de Chimie de Nice, Université de Nice-Sophia Antipolis, CNRS, UMR 7272, Faculté des Sciences, Parc Valrose, 06108 Nice cedex 2, France, Fax: +33-4-92076189
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Abstract

Several metallic triflates and triflimides, among them anhydrous salts, were prepared in high yields under ultrasonic activation from the corresponding metal powders andstoichiometric amounts of triflic or triflimidic acid in different solvents. Different InIII and BiIII salts were tested as catalysts in hydrothiolation of olefins and in hydroarylation processes, respectively.

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