These authors contributed equally to this work.
Tsuji–Trost N-Allylation with Allylic Acetates by Using a Cellulose–Palladium Catalyst
Article first published online: 30 OCT 2012
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
European Journal of Organic Chemistry
Volume 2012, Issue 34, pages 6707–6709, December 2012
How to Cite
Vaddula, B. R., Saha, A., Varma, R. S. and Leazer, J. (2012), Tsuji–Trost N-Allylation with Allylic Acetates by Using a Cellulose–Palladium Catalyst. Eur. J. Org. Chem., 2012: 6707–6709. doi: 10.1002/ejoc.201201241
- Issue published online: 20 NOV 2012
- Article first published online: 30 OCT 2012
- Manuscript Received: 18 SEP 2012
- Allylic compounds;
- Heterogeneous catalysis
Allylic amines were synthesized by a simple procedure using a biodegradable and easily recyclable heterogeneous cellulose–Pd catalyst through N-allylation of primary and secondary amines. The scope of this protocol includes aliphatic and benzylamines with substituted and unsubstituted allyl acetates and culminates in high yield syntheses. The highlights of the protocol include a ligand-free reaction, simple workup, and catalyst recyclability.