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Environmentally Friendly Reduction of Graphene Oxide Using Tyrosine for Nonenzymatic Amperometric H2O2 Detection

Authors

  • Qi Wang,

    1. Institut de Recherche Interdisciplinaire (IRI, USR CNRS 3078), Université Lille 1, Parc de la Haute Borne, 50 Avenue de Halley, BP 70478, 59658 Villeneuve d'Ascq, France tel: +33 3 62 53 17 24; fax: +33 3 62 53 17 01
    2. Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, P. R. China
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  • Musen Li,

    1. Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, P. R. China
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  • Sabine Szunerits,

    1. Institut de Recherche Interdisciplinaire (IRI, USR CNRS 3078), Université Lille 1, Parc de la Haute Borne, 50 Avenue de Halley, BP 70478, 59658 Villeneuve d'Ascq, France tel: +33 3 62 53 17 24; fax: +33 3 62 53 17 01
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  • Rabah Boukherroub

    Corresponding author
    1. Institut de Recherche Interdisciplinaire (IRI, USR CNRS 3078), Université Lille 1, Parc de la Haute Borne, 50 Avenue de Halley, BP 70478, 59658 Villeneuve d'Ascq, France tel: +33 3 62 53 17 24; fax: +33 3 62 53 17 01
    • Institut de Recherche Interdisciplinaire (IRI, USR CNRS 3078), Université Lille 1, Parc de la Haute Borne, 50 Avenue de Halley, BP 70478, 59658 Villeneuve d'Ascq, France tel: +33 3 62 53 17 24; fax: +33 3 62 53 17 01

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Abstract

Herein, we report on the simultaneous reduction and functionalization of graphene oxide (GO) with environmentally friendly tyrosine through the direct reaction of GO with tyrosine (Tyr) at 100 °C for 24 h. The resultant material (rGO/Tyr) has been characterized using UV-vis spectrometry, FTIR spectroscopy, X-ray photoelectron spectroscopy (XPS), and electrochemical measurements. The rGO/Tyr nanomaterial displayed good electrocatalytic activity for the detection of hydrogen peroxide (H2O2) with a wide linear range from 100 µM to 2.1 mM, a detection limit of 80 µM and a sensitivity of 69.07 µA mM−1 cm−2. In addition, the rGO/Tyr electrode showed good selectivity for H2O2 detection in the presence of uric acid, ascorbic acid, dopamine and glucose.

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