• 1
    Han WF, Li Y, Tang HD and Liu HZ, Treatment of the potent greenhouse gas, CHF3-An overview. J Fluorine Chem 140:716 (2012).
  • 2
    Houghton JT, Filho LGM, Callander BA, Harris N, Kattenburg A and Maskell K, Climate change 1995: The Science of Climate Change. Cambridge University Press, Cambridge, pp. 1921 (1996).
  • 3
    UNEP, Production and Consumption of Ozone Depleting Substances Under the Montreal Protocol. [Online]. Available at: [August 26, 2013].
  • 4
    Montzka SA, Kuijpers L, Battle MO, Aydin M, Verhulst KR, Saltzman ES et al., Recent increases in global HFC-23 emissions. Geophys Res Lett 37:L02808 (2010).
  • 5
    Velders GJM, Fahey DW, Daniel JS, McFarland M and Andersen SO, The large contribution of projected HFC emissions to future climate forcing. P Natl Acad Sci USA 106(27):1094910954(2009).
  • 6
    UNFCCC, Projects of thermal oxidation of synthetic greenhouse gases registered under CDM program of UNFCCC. [Online]. Available at: [Janauary 8, 2013].
  • 7
    Murphy AB, Farmer AJD, Horrigan EC and McAllister T, Plasma destruction of ozone depleting substances. Plasma Chem Plasma Process 22(3):371385(2002).
  • 8
    Yu H, Kennedy EM, Adesina AA and Dlugogorski BZ, A review of CFC and halon treatment technologies – The nature and role of catalysts. Catal Surv Asia 10(1):4054 (2006).
  • 9
    Moon DJ, Chung MJ, Kim H, Kwon YS and Ahn BS, Pyrolysis of trifluoromethane to produce hexafluoropropylene. Ind Eng Chem Res 41(12):2895902 (2002).
  • 10
    Han WF, Kennedy EM, Liu HZ, Li Y, Adesina AA, Mackie JC et al., Catalytic pyrolysis of CHF3 over activated carbon and activated carbon supported potassium catalyst. J Fluorine Chem 131(6):698703 (2010).
  • 11
    Wang YC, Wang XB, Geng ZY, Lv LL, Wang QA, Liu HW et al., Theoretical study of the activation of CH4-nFn (n = 1–3) molecules by platinum in the gas-phase. J Mol Struct Theochem 962(1/3):9096 (2010).
  • 12
    Nagasaki N, Morikuni Y, Kawada K and Arai S, Study on a novel catalytic reaction and its mechanism for CF3I synthesis. Catal Today88(3/4):121126 (2004).
  • 13
    Han WF, Kennedy EM, Mackie JC and Dlugogorski BZ, Mechanistic study of the reaction of CHF3 with CH4. Chem Eng J 166(3):822831 (2011).
  • 14
    Feaver WB and Rossin JA, The catalytic decomposition of CHF3 over ZrO2-SO4. Catal Today 54(1):1322 (1999).
  • 15
    Heberlein J and Murphy AB, Thermal plasma waste treatment. J Phys D Appl Phys 41(5):053001 (2008).
  • 16
    Vakulka A, Tavcar G and Skapin T, Interaction of trifluoromethane (CHF3) with alkali hydroxides and carbonates. J Fluorine Chem 142:5259 (2012).
  • 17
    Ahrens M, Scholz G, Braun T and Kemnitz E, Catalytic hydrodefluorination of fluoromethanes at room temperature by silylium-ion-like surface species. Angew Chem Int Edit 52(20):53285332 (2013).
  • 18
    Zanardi A, Novikov MA, Martin E, Benet-Buchholz J and Grushin VV, Direct cupration of fluoroform. J Am Chem Soc 133(51):2090120913(2011).
  • 19
    Novák P, Lishchynskyi A and Grushin VV, Fluoroform-derived CuCF3 for low-cost, simple, efficient, and safe trifluoromethylation of aryl boronic acids in air. Angew Chem Int Edit 51(31):77677770 (2012).
  • 20
    Prakash GKS, Jog PV, Batamack PTD and Olah GA, Taming of fluoroform: Direct nucleophilic trifluoromethylation of Si, B, S, and C Centers. Science 338(6112):13241327 (2012).
  • 21
    Haufe G, Putting a greenhouse gas to work. Science 338(6112):1298 (2012).
  • 22
    Onoda H, Ohta T, Tamaki J and Kojima K, Decomposition of trifluoromethane over nickel pyrophosphate catalysts containing metal cation. Appl Catal A 288(1/2):98103 (2005).
  • 23
    Fujita T, Hari T, Kojima Y, Matsuda H and Huang LW, Influence of O2 concentration on non-thermal plasma decomposition of halide gases containing Cl and F. Kagaku Kogaku Ronbunshu 31(3):226230 (2005).
  • 24
    El-Bahy ZM, Ohnishi R and Ichikawa M, Hydrolysis of CF4 over alumina-based binary metal oxide catalysts. Appl Catal B 40:8191 (2003).
  • 25
    Jeon JY, Xu X-F, Choi MH, Kim HY and Park Y-K, Hydrolytic decomposition of PFCs over AlPO4–Al2O3 catalyst. Chem Commun 11:12441245 (2003).
  • 26
    El-Bahy ZM, Ohnishi R and Ichikawa M, Hydrolytic decomposition of CF4 over alumina-based binary metal oxide catalysts: High catalytic activity of gallia-alumina catalyst. Catal Today 90(3):283290 (2004).
  • 27
    Xu XF, Jeon JY, Choi MH, Kim HY, Choi WC and Park YK, The modification and stability of gamma-Al2O3 based catalysts for hydrolytic decomposition of CF4. J Mol Catal A Chem 266(1/2):131138 (2007).
  • 28
    Shekar SC, Rao KSR and Sahle-Demessie E, Characterization of palladium supported on gamma-Al2O3 catalysts in hydrodechlorination of CCl2F2. Appl Catal A 294(2):235243 (2005).
  • 29
    Legawiec-Jarzyna M, Srebowata A, Juszczyk W and Karpinski Z, Hydrodechlorination of dichlorodifluoromethane (CFC-12) on Pd-Pt/Al2O3 catalysts. Catal Today 88(3/4):93101 (2004).
  • 30
    Xu X-F, Jeon JY, Choi MH, Kim HY, Choi WC and Park Y-K, A strategy to protect Al2O3-based PFC decomposition catalyst from deactivation. Chem Lett 34(3):364365 (2005).
  • 31
    Farris MM, Klinghoffer AA, Rossin JA and Tevault DE, Deactivation of a Pt/Al2O3 catalyst during the oxidation of hexafluoropropylene. Catal Today 11(4):501516 (1992).
  • 32
    Furusawa T, Ogawa T, Numao T, Sato M and Suzuki N, Production of CaF2 by the destructive adsorption of trifluoromethane and a binary mixture of trifluoromethane/chlorodifluoromethane with CaO powder under air-flow. J Chem Eng Jpn 45(6):459465 (2012).
  • 33
    Hass KC, Schneider WF, Curioni A and Andreoni W, First-principles molecular dynamics simulations of H2O on alpha-Al2O3 (0001). J Phys Chem B 104(23):55275540 (2000).
  • 34
    Copeland JR, Shi X-R, Sholl DS and Sievers C, Surface interactions of C2 and C3 polyols with γ-Al2O3 and the role of coadsorbed water. Langmuir 29(2):581593 (2012).
  • 35
    Song J-Y, Chung S-H, Kim M-S, Seo M-g, Lee Y-H, Lee K-Y et al., The catalytic decomposition of CF4 over Ce/Al2O3 modified by a cerium sulfate precursor. J Mol Catal A Chem 370(0):5055(2013).
  • 36
    Takita Y, Moriyama J, Yoshinaga Y, Nishiguchi H, Ishihara T, Yasuda S et al., Adsorption of water vapor on the AlPO4-based catalysts and reaction mechanism for CFCs decomposition. Appl Catal A 271(1/2):5560 (2004).