Conference Report

New applications of dithiocarbamates in organic synthesis

  1. Richard S. Grainger1,*,
  2. Paolo Innocenti2

Article first published online: 10 JUL 2007

DOI: 10.1002/hc.20336

Issue

Heteroatom Chemistry

Heteroatom Chemistry

Special Issue: ISOCS-22

Volume 18, Issue 5, pages 568–571, July 2007

Additional Information

How to Cite

Grainger, R. S. and Innocenti, P. (2007), New applications of dithiocarbamates in organic synthesis. Heteroatom Chemistry, 18: 568–571. doi: 10.1002/hc.20336

Author Information

  1. 1

    School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT, UK

  2. 2

    Department of Chemistry, King's College London, Strand, London WC2R 2LS, UK

*School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT, UK

Publication History

  1. Issue published online: 10 JUL 2007
  2. Article first published online: 10 JUL 2007
  3. Manuscript Received: 10 NOV 2006

Funded by

  • King's College London
  • The University of Birmingham
  • EPSRC
  • AstraZeneca
  • EPSRC Advanced Research Fellowship. Grant Number: 2005–2010

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Abstract

The application of dithiocarbamates in group transfer radical cyclization reactions is described. Carbamoyl diethyldithiocarbamates are synthesized in two high-yielding steps from secondary amines and act as sources of carbamoyl radicals through chemical or photochemical initiation. Group transfer radical cyclization reactions lead to dithiocarbamate-functionalized lactams. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:568–571, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20336

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