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Miyaura Borylations of Aryl Bromides in Water at Room Temperature

Authors

  • Bruce H. Lipshutz,

    Corresponding author
    1. Department of Chemistry & Biochemistry, University of California, Santa Barbara, CA 93106, USA phone: +(805) 893-2521 fax: +(805) 893-8265
    • Department of Chemistry & Biochemistry, University of California, Santa Barbara, CA 93106, USA phone: +(805) 893-2521 fax: +(805) 893-8265
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  • Ralph Moser,

    1. Department of Chemistry & Biochemistry, University of California, Santa Barbara, CA 93106, USA phone: +(805) 893-2521 fax: +(805) 893-8265
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  • Karl R. Voigtritter

    1. Department of Chemistry & Biochemistry, University of California, Santa Barbara, CA 93106, USA phone: +(805) 893-2521 fax: +(805) 893-8265
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Abstract

New technology for palladium-catalyzed cross-couplings between B2pin2 and aryl bromides leading to arylboronates is described. Micellar catalysis serves to enable borylations to take place in water as the only medium at ambient temperatures.

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