Journal of the Chinese Chemical Society

Cover image for Vol. 60 Issue 1

January 2013

Volume 60, Issue 1

Pages 1–126

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Contents
    5. Articles
    6. Award
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    8. Articles
    1. You have free access to this content
      Cover Picture: Journal of the Chinese Chemical Society 1/2013

      Article first published online: 27 DEC 2012 | DOI: 10.1002/jccs.201290042

  2. Editorial

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    2. Cover Picture
    3. Editorial
    4. Contents
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      Celebrating the 60th Anniversary (page 1)

      Prof. Yu Wang

      Article first published online: 27 DEC 2012 | DOI: 10.1002/jccs.201290043

  3. Contents

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Contents
    5. Articles
    6. Award
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    8. Articles
  4. Articles

    1. Top of page
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    3. Editorial
    4. Contents
    5. Articles
    6. Award
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    8. Articles
    1. Metal-Porphyrin Orbital Interactions in Paramagnetic Iron Complexes Having Planar and Deformed Porphyrin Ring (pages 9–21)

      Mikio Nakamura, Akira Ikezaki and Masashi Takahashi

      Article first published online: 10 DEC 2012 | DOI: 10.1002/jccs.201200474

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      This review describes how the half-occupied iron 3d orbitals such as dπ(dxz, dyz), dxy, dmath image, and dmath image-math image interact with a specific porphyrin molecular orbital and affect the 1H and 13C NMR chemical shifts in planar, ruffled, saddled, and domed complexes.

    2. Solvent-free Synthesis of Novel and Known Octahydroquinazolinones/thiones by the Use of ZrOCl2.8H2O as a Highly Efficient and Reusable Catalyst (pages 22–26)

      Sajad Karami, Bahador Karami and Saeed Khodabakhshi

      Article first published online: 19 NOV 2012 | DOI: 10.1002/jccs.201200145

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      For the condensation of urea/thiourea, dimedone and aromatic aldehydes under solvent-free conditions, zirconium (IV) oxychloride octahydrate was found to be an efficient and reusable catalyst. The high yield of the pure products has allowed the synthesis of several octahydroquinazolinones/thiones via this methodology.

    3. Design, Synthesis, and Antifungal Activities of New β-Methoxyacrylate Analogues (pages 27–34)

      Hui-Jun Liu, Xiang Zhang, Yong-Xin Gao, Jian-Zhong Li and Hui-Li Wang

      Article first published online: 19 NOV 2012 | DOI: 10.1002/jccs.201200295

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      A series of new β-methoxyacrylate analogues containing substituted pyrimidine with strobilurin pharmacophore were synthesized. The bioassays indicated that most of the compounds 1 exhibited potent antifungal activities against all the tested fungi at a concentration of 50 μg mL−1.

    4. A New, Fast and Easy Strategy for One-pot Synthesis of Full Substituted Cyclopropanes: Direct Transformation of Aldehydes to 3-Aryl-1,1,2,2-tetracyanocyclopropanes (pages 35–44)

      Nader Noroozi Pesyan, Mohammad Ali Kimia, Mohammad Jalilzadeh and Ertan Şahin

      Article first published online: 4 OCT 2012 | DOI: 10.1002/jccs.201200189

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      A new, fast and easy method for one-pot reaction of aromatic aldehydes and dialdehydes with malononitrile and cyanogen bromide was afforded full substituted 3-arylcyclopropane-1,1,2,2-tetracarbonitriles in excellent yield in very short time (about 5 seconds).

    5. An Experimental and Theoretical Study on Influence of H-bonding on the Synthesized Azo Derivatives Structures (pages 45–52)

      Rahebeh Amiri, Mina Haghdadi, Ashkan Golshani, Maryam Mohamadian Amiri and Maryam Barikani

      Article first published online: 2 NOV 2012 | DOI: 10.1002/jccs.201200170

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      A simple and efficient reaction for the synthesis of some new functionalized azo structures has been performed by electron deficient acetylenic compounds in the presence of triphenylphosphine. The influence of H-bonding on the products has been investigated by different experimental analysis and DFT calculations at the B3LYP/6-31G level of theory.

    6. Mesoporous Silica-coated Magnetic Nanoparticles for Mixed Hemimicelles Solid-phase Extraction of Phthalate Esters in Environmental Water Samples with Liquid Chromatographic Analysis (pages 53–62)

      Pei-Lu Liu, Ye-Ping Xu, Ping Zheng, Hong-Wu Tong, Yu-Xin Liu, Zheng-Gen Zha, Qing-De Su and Shao-Min Liu

      Article first published online: 10 DEC 2012 | DOI: 10.1002/jccs.201200096

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      A novel mixed hemimicelles solid-phase extraction method based on mesoporous silica-coated magnetic nanoparticles as adsorbent for extraction of environmental pollutions prior to determination by high performance liquid chromatography were investigated in this paper. The proposed method exhibited high extraction efficiency and relatively short time for extracting the target compounds.

    7. Adsorptive Stripping Differential Pulse Voltammetric Determination of Risperidone with a Multi-Walled Carbon Nanotube-Ionic Liquid Paste Modified Glassy Carbon Electrode (pages 63–72)

      Majid Arvand and Akram Pourhabib

      Article first published online: 24 SEP 2012 | DOI: 10.1002/jccs.201200161

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      In the past years, ionic liquids (ILs) have emerged as a frontier and novel area of research because of their unique chemical and physical properties.

    8. Oxygen Reduction Reaction (ORR) on Huge Gold (Au) Particles Prepared by a Pyrolysis Process of AuCl3 Dissolved in Distilled Water in the Presence of MWCNTs (pages 73–80)

      Yahui Wang, Fuli Yang, Hongwei Yang, Chunbao Zheng, Yanli Cao and Keqiang Ding

      Article first published online: 4 OCT 2012 | DOI: 10.1002/jccs.201200100

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      Gold (Au) huge particles were prepared by a pyrolysis process of AuCl3 dissolved in distilled water in the presence of multi-walled carbon nanotubes (MWCNTs). Results demonstrated that the mechanism of ORR on the as-prepared huge Au modified electrode was rather different from the previously reported one.

    9. Characterization of Nano-porous TiO2 Film Prepared by Sol-gel Process and Its Application to Dye-sensitized Solar Cell (pages 81–84)

      Brandon Chiou, Ru-Yuan Yang, Hui-Ju Chuang and Cheng-Jye Chu

      Article first published online: 4 OCT 2012 | DOI: 10.1002/jccs.201100762

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      This paper describes effects of ethylene glycol (EG) and indium tin oxide (ITO) solution on the morphology, porosity, and roughness of TiO2 film prepared by sol-gel process. The results show that the optimum efficiency of 1.32% is obtained when DSSC is assembled with TiO2 film prepared from the solution containing 20 wt% EG.

    10. Synthesis and Characterization of Iron Nanowires (pages 85–91)

      Wei-Syuan Lin, Zih-Jie Jian, Hong-Ming Lin, Li-Chung Lai, Wen-An Chiou, Yeu-Kuang Hwu, She-Huang Wu, Wen-Chang Chen and Y. D. Yao

      Article first published online: 17 SEP 2012 | DOI: 10.1002/jccs.201200263

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      This study develop a novel process to produce iron nanowires with large quantitates and can control its length and diameter by various the concentration of precursors for various applications.

    11. Analytical Characterization of Fatty Acids Composition of Bioactive Stem Oil of Maytenus royleanus by Gas Chromatography Mass Spectrometry (pages 92–96)

      Ghias Uddin, Ala Ud Din, Amna Khurshid, Frederick A. Valeriote and M. Iqbal Choudhary

      Article first published online: 24 SEP 2012 | DOI: 10.1002/jccs.201100686

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      GC-MS profile of methyl ester derivatives of fatty acids, showed that Palmitic acid (35.41%), Oleic acid (10.91%), Stearic acid (5.31%), Margaric acid (5.13%), Behenic acid (5.18%) and Hexanoic acid (4.97%) were the major components in the isolated oily fraction, while rest of the other fatty acids were present in minor concentration. The literature revealed that no such work has been done for the determination of fatty acid in M. royleanus stem oil.

    12. Glass Wool Catalysed Regioselective Isomerization of Styrene Oxides (pages 97–102)

      Govindarajan K. Ramaswamy, Angalan Somasundaram, Balasubramanian K. Kuppuswamy and Murugesan Velayudham

      Article first published online: 17 SEP 2012 | DOI: 10.1002/jccs.201200269

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      We establish for the first time, Glass wool as a mild heterogeneous acidic catalyst with potentially important applications including production of pharmaceutical agents and other useful organic chemicals. Regioselective rearrangement of styrene oxides has been established with the novel use of glass wool as heterogeneous catalyst under gas phase. This method provides very good yields with halogen-containing styrene oxides which are very difficult to prepare by other methods.

  5. Award

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Contents
    5. Articles
    6. Award
    7. Preview
    8. Articles
    1. Best Article Award In 2012

      Article first published online: 27 DEC 2012 | DOI: 10.1002/jccs.201290044

  6. Preview

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Contents
    5. Articles
    6. Award
    7. Preview
    8. Articles
    1. Preview: Journal of the Chinese Chemical Society 1/2013

      Article first published online: 27 DEC 2012 | DOI: 10.1002/jccs.201290045

  7. Articles

    1. Top of page
    2. Cover Picture
    3. Editorial
    4. Contents
    5. Articles
    6. Award
    7. Preview
    8. Articles
    1. Synthesis of (−)-3-Carene-2,5-dione via Allylic Oxidation of (+)-3-Carene (pages 103–107)

      Xiaoling Sun, Xiaoyan Zhao, Ying Jiang and Bochun Xu

      Article first published online: 24 SEP 2012 | DOI: 10.1002/jccs.201100694

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      A facile and environment-friendly method of preparing (−)-3-carene- 2,5-dione has been developed in this study. 2,5-Dione was prepared by allylic oxidation of (+)-3-carene with TBHP/O2 catalyzed by CuCl2/AC. The catalyst was characterized via X-ray diffraction. The possible reaction mechanism was investigated. Under the optimal conditions, the conversion of (+)-3-carene reached 100%, the selectivity for (−)-3-carene-2,5 -dione reached 78%.

    2. Determined GA by FI-CE in Luminol-H2O2 System (pages 108–112)

      Yanjie Dong and Zhongling Wang

      Article first published online: 4 OCT 2012 | DOI: 10.1002/jccs.201200086

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      Based on the inhibiting effect of GA on the luminol-H2O2 involving Co(II)-catalyzed CL reaction, a new flow injection CL method was developed for the determination of GA. The method was simple, rapid, and sensitive, and was applied to the analysis of gibberellic acid in bacteria-free culture liquid.

    3. Analysis of Calix[4]arenes Using Nonaqueous Capillary Electrophoresis (pages 113–119)

      Hsiu-Li Su, Yi-Ping Lee, Huan-Yi Hung, Cheng-Yu Lee, Wen-Sheng Chung and You-Zung Hsieh

      Article first published online: 4 OCT 2012 | DOI: 10.1002/jccs.201200259

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      We employed NACE with UV detection for the analysis of eight calix[4]arenes within 11 min. We examined the influence of several parameters—the buffer composition and the nonaqueous solvent's composition and proportion—on the efficiency of the electrophoretic separation. The separation was achieved through the analyte's different effective mobility via different degrees of deprotonation on the phenolic OH groups.

    4. Selective Voltammetric Determination of Tartrazine in the Presence of Red 10B by Nanogold-modified Carbon Paste Electrode (pages 120–126)

      Sayed Mehdi Ghoreishi, Mohsen Behpour and Mahshid Golestaneh

      Article first published online: 4 OCT 2012 | DOI: 10.1002/jccs.201200143

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      Cyclic voltammograms of 2.0 μmol l−1 Tartrazine in the presence of 1.5 μmol l−1 Red 10B in pH 4.0 phosphate buffer at the surface of carbon paste electrode (curve A) and gold nanoparticles carbon paste electrode (curve B).

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