SEARCH

SEARCH BY CITATION

Chemistry Terms

Choose one or more boxes to highlight terms.

Abstract

A novel triazene, 4-[(E)-2-(4-cyanophenyl)diazenyl]-morpholine (1) was prepared via a diazonium ion coupling reaction between 4-aminobenzonitrile and morpholine. The x-ray structure of 1 was determined and evidenced π delocalization in the triazene subunit. The room temperature absorption spectrum of 1 in acetonitrile was dominated by an intense triazene-centered π[RIGHTWARDS ARROW]π* transition at 325 nm. Compound 1 was observed to be luminescent, with an emission maximum at 434 nm in room temperature acetonitrile solution. The emission spectrum of 1 in propionitrile glass at 77K exhibited a narrowed emission band with a maximum at 449 nm. Broad emission from 400–700 nm with poorly resolved vibrational structure was observed from solid 1 at room temperature. J. Heterocyclic Chem., 2011.

Featured Compounds

VIEW

  1. 1
Compound 1
Molecular Weight:216.2392
Molecular Formula:C11H12N4O
InChIKey:GPLBWDBTNHEVKY-BUHFOSPRSA-N
View compound in article | Full details | Search for this compound

VIEW

  1. 1