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Research Article
The effect of adding Crabtree's catalyst to rhodium black in direct hydrogen isotope exchange reactions
Article first published online: 23 JUN 2009
DOI: 10.1002/jlcr.1612
Copyright © 2009 John Wiley & Sons, Ltd.
Issue
1099-1344/asset/cover.gif?v=1&s=4b6abb1d01cc23d5bd78456a499412dee92e9998 "Journal of Labelled Compounds and Radiopharmaceuticals")
Journal of Labelled Compounds and Radiopharmaceuticals
Volume 52, Issue 9, pages 376–381, July 2009
Additional Information
How to Cite
Schou, S. C. (2009), The effect of adding Crabtree's catalyst to rhodium black in direct hydrogen isotope exchange reactions. Journal of Labelled Compounds and Radiopharmaceuticals, 52: 376–381. doi: 10.1002/jlcr.1612
Publication History
- Issue published online: 11 AUG 2009
- Article first published online: 23 JUN 2009
- Manuscript Accepted: 6 MAY 2009
- Manuscript Revised: 4 MAY 2009
- Manuscript Received: 9 FEB 2009
- Abstract
- Article
- References
- Cited By
Keywords:
- rhodium black;
- Crabtree's catalyst;
- deuterium;
- catalytic direct hydrogen isotope exchange
Graphical Abstract
A new catalyst based on rhodium black using Crabtree's catalyst as an additive for direct hydrogen isotope exchange in aromatic compounds has been investigated. The level of deuterium incorporation can be improved from for example 16% to 93%. The catalyst mixture tolerates a variety of solvents. Copyright © 2009 John Wiley & Sons, Ltd.
Abstract
A new catalytic system based on rhodium black using Crabtree's catalyst as an additive for direct hydrogen isotope exchange in aromatic compounds has been investigated. The level of deuterium incorporation can be improved from for example 16 to 93%. The new catalyst mixture tolerates a variety of solvents. Copyright © 2009 John Wiley & Sons, Ltd.