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Supporting information may be found in the version of this article.

FilenameFormatSizeDescription
jms_3160_sm_fS1a_17_12_12.tifTIFF image750KFigure 1 supplement. Single-ion chromatogram m/z 611.1650 ± 0.005 and CID MS/MS spectra of luteolin 6-C-hexosyl-O-hexoside 3 (MW = 610), luteolin 7-O-hexoside 8-C-hexoside 5 (MW = 610), luteolin 7-O-hexoside 6-C-hexoside 8 (MW = 610) – positive ion mode (a); single-ion chromatogram m/z 609.1480 ± 0.005 and CID MS/MS spectra of luteolin 6-C-hexosyl-O-hexoside 3 (MW = 610), luteolin 7-O-hexoside 8-C-hexoside 5 (MW = 610), luteolin 7-O-hexoside 6-C-hexoside 8 (MW = 610) – negative ion mode (b).
jms_3160_sm_fS1b_17_12_12.tifTIFF image689KSupporting information Figure 1b
jms_3160_sm_fS2 popr.tifTIFF image1195KFigure 2 supplement. CID MS/MS spectra of luteolin C-[(O-caffeoyl-hexosyl)-O-hexoside] 13 (MW = 772): (a) positive ion mode; (b) negative ion mode.
jms_3160_sm_fS3 popr.tifTIFF image1417KFigure 3 supplement. CID MS/MS spectra of luteolin C-[hexosyl-(O-feruoyl-hexoside)] 25 (MW = 756): (a) positive ion mode; (b) negative ion mode.
jms_3160_sm_fS4 popr.tifTIFF image1202KFigure 4 supplement. CID MS/MS spectra of chrysoeriol C-[(O-caffeoyl-hexosyl)-O-hexoside] – 20 (MW = 786): (a) positive ion mode; (b) negative ion mode.
jms_3160_sm_fS5 popr.tifTIFF image1215KFigure 5 supplement. CID MS/MS spectra of chrysoeriol 7-O-hexoside C-(O-feruoyl-hexoside) – 29 (MW = 800): (a) positive ion mode; (b) negative ion mode.
jms_3160_sm_fS6.tifTIFF image547KFigure 6 supplement. CID MS/MS spectra of apigenin 6-C-hexoside 8-C-pentoside 10 (MW = 564): (a) positive ion mode; (b) negative ion mode.
jms_3160_sm_fS7ab.tifTIFF image548KFigure 7 supplement. CID MS/MS spectra of tricin 7-O-hexosyl-O-hexoside – 24 (MW 656): (a) product ion MS spectrum registered with normal ESI source; (b) product ion MS spectrum registered with nano-ESI source; (c) product ion MS spectrum registered with nano-ESI source after fractionation of UPLC column eluate.
jms_3160_sm_fS7c.tifTIFF image656KSupporting information Figure 7c
jms_3160_sm_fS8ab.tifTIFF image445KFigure 8 supplement. CID MS/MS spectra of luteolin O-(O-caffeoyl-hexoside) C-hexoside – 23 (MW 772): (a) product ion MS spectrum registered with normal ESI source; (b) product ion MS spectrum registered with nano-ESI source; (c) product ion MS spectrum registered with nano-ESI source after fractionation of UPLC column eluate.
jms_3160_sm_fS8c.tifTIFF image727KSupporting information Figure 8c

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