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Table S1. Secondary standard analyses of the Lipari standard made throughout the analytical period of the MD04-2822 material.

Table S2. Secondary standard analyses of the BHVO-2g standard made throughout the analytical period of the MD04-2822 material.

Table S3. Trace element analytical data from USGS Glass reference materials BHVO-2G and BCR-2G.

Table S4. Major oxide and trace element concentrations of shards from the MD04-2822 2385–2386 cm sample.

Table S5. Major oxide and trace element concentrations of shards from the MD04-2822 2424–2425 cm sample.

Table S6. Major oxide and trace element concentrations of shards from the MD04-2822 2490–2491 cm sample.

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