The relation of resonance Raman scattering to resonance fluorescence

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Abstract

If and only if spontaneous resonance Raman scattering is excited by irradiation upon a single, discrete and non-degenerate energy level sufficiently distant from other levels can it be interpreted as resonance fiuorescence, i.e. a sequence of two independent one-photon processes, an absorption and an emission in definte order of succession. This decomposition of the resonance scattering process is independent of the bandwidth of the exciting radiation relative to the widths of the combining levels. These widths however determine quantitatively the temporal decay of the resonance scattering (= resonance fluorescence) probability given explicitly in the paper.

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