Nano-Raman spectroscopy with side-illumination optics
Article first published online: 19 SEP 2005
Copyright © 2005 John Wiley & Sons, Ltd.
Journal of Raman Spectroscopy
Volume 36, Issue 11, pages 1068–1075, November 2005
How to Cite
Mehtani, D., Lee, N., Hartschuh, R. D., Kisliuk, A., Foster, M. D., Sokolov, A. P. and Maguire, J. F. (2005), Nano-Raman spectroscopy with side-illumination optics. J. Raman Spectrosc., 36: 1068–1075. doi: 10.1002/jrs.1409
- Issue published online: 25 OCT 2005
- Article first published online: 19 SEP 2005
- Manuscript Accepted: 24 JUN 2005
- Manuscript Received: 29 MAR 2005
- NSF-MRI. Grant Number: DMR-0215966.
- The OBR Action Fund.
- The Cooperative Center for Polymer Photonics.
- surface-enhanced Raman spectroscopy (SERS);
- tip-enhanced Raman spectroscopy (TERS);
- apertureless near-field spectroscopy
We describe an apertureless near-field Raman spectroscopy setup that has successfully produced substantial enhancements for a wide variety of samples and achieved a high contrast. The tremendous potential of tip-enhanced Raman spectroscopy (TERS) for nanoscale chemical characterization has been demonstrated by various groups by measuring organic dyes, biological molecules, single-walled carbon nanotubes and silicon. Keys to rapid advances in the application of TERS to pressing scientific problems include the optimization of the method to achieve greater reproducibility and greater enhancement factors if possible, but more importantly, greater imaging contrast. Using a side-illumination geometry, we demonstrate reproducible enhancements of the Raman signal per volume on the order of 103–104 using silver- and gold-coated tips on various molecular, polymeric and semiconducting materials as well as on carbon nanotubes. We have experimentally verified localization of the enhancement to a depth of ∼20 nm. Most importantly, optimization of the polarization geometry makes possible a contrast between the near-field and far-field signals of 900% in the case of silicon—a level that makes the technique attractive for various applications. Copyright © 2005 John Wiley & Sons, Ltd.