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Keywords:

  • ammonium-silver monofluorophosphate;
  • site-symmetry analysis;
  • infrared spectra;
  • Raman spectra

Abstract

The powder Fourier-transform (FT) infrared (IR) and Raman spectra of the recently characterized NH4Ag3(PO3F)2 were recorded and are discussed with a site-symmetry analysis based on its known structural data. Some comparisons are made with the solution spectra of the PO3F2− anion and with those of crystalline Ag2PO3F. Copyright © 2009 John Wiley & Sons, Ltd.