Research Article
Raman study of Fano interference in p-type doped silicon
Article first published online: 19 FEB 2010
DOI: 10.1002/jrs.2614
Copyright © 2010 John Wiley & Sons, Ltd.
Additional Information
How to Cite
Burke, B. G., Chan, J., Williams, K. A., Wu, Z., Puretzky, A. A. and Geohegan, D. B. (2010), Raman study of Fano interference in p-type doped silicon. J. Raman Spectrosc., 41: 1759–1764. doi: 10.1002/jrs.2614
Publication History
- Issue published online: 16 DEC 2010
- Article first published online: 19 FEB 2010
- Manuscript Accepted: 17 DEC 2009
- Manuscript Received: 27 OCT 2009
Funded by
- Scientific User Facilities Division
- Office of Basic Energy Sciences
- U.S. Department of Energy
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- Cited By
Keywords:
- silicon;
- Fano interference;
- Raman spectroscopy;
- deep UV;
- penetration depth;
- inter-valence band transitions
Abstract
As the silicon industry continues to push the limits of device dimensions, tools such as Raman spectroscopy are ideal to analyze and characterize the doped silicon channels. The effect of inter-valence band transitions on the zone center optical phonon in heavily p-type doped silicon is studied by Raman spectroscopy for a wide range of excitation wavelengths extending from the red (632.8 nm) into the ultra-violet (325 nm). The asymmetry in the one-phonon Raman lineshape is attributed to a Fano interference involving the overlap of a continuum of electronic excitations with a discrete phonon state. We identify a transition above and below the one-dimensional critical point (E
= 3.4 eV) in the electronic excitation spectrum of silicon. The relationship between the anisotropic silicon band structure and the penetration depth is discussed in the context of possible device applications. Copyright © 2010 John Wiley & Sons, Ltd.

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