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Raman and infrared spectra of doped La8+xSr2−y(SiO4)6O2+δ compounds compared to the ab initio-obtained spectroscopic characteristics of fully stoichiometric La8Sr2(SiO4)6O2

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Abstract

Vibrational spectroscopy data were used to gain insight into the possible locations of extra oxygen ions introduced into La8+xSr2−y(SiO4)6O2+δ compounds to raise their ionic conductivity. Perturbations observed in the Raman and infrared spectra of these compounds with increasing δ were explained by using the ab initio calculation results for the fully stoichiometric (x = y = δ = 0) lattice. This allowed the inference that the extra oxygen ions are incorporated into La[BOND]O tunnel-like fragments inherent in the studied structures. Copyright © 2010 John Wiley & Sons, Ltd.

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