Study of Raman spectrum of uranium using a surface-enhanced Raman scattering technique
Article first published online: 1 APR 2011
Copyright © 2011 John Wiley & Sons, Ltd.
Journal of Raman Spectroscopy
Volume 42, Issue 5, pages 885–887, May 2011
How to Cite
Ravindran, T. R. and Arora, A. K. (2011), Study of Raman spectrum of uranium using a surface-enhanced Raman scattering technique. J. Raman Spectrosc., 42: 885–887. doi: 10.1002/jrs.2926
- Issue published online: 20 MAY 2011
- Article first published online: 1 APR 2011
- Manuscript Accepted: 24 JAN 2011
- Manuscript Received: 14 DEC 2010
- Raman spectroscopy;
Raman spectroscopic investigation on weak scatterers such as metals is a challenging scientific problem. Technologically important actinide metals such as uranium and plutonium have not been investigated using Raman spectroscopy possibly due to poor signal intensities. We report the first Raman spectrum of uranium metal using a surface-enhanced Raman scattering-like geometry where a thin gold overlayer is deposited on uranium. Raman spectra are detected from the pits and scratches on the sample and not from the smooth polished surface. The 514.5- and 785-nm laser excitations resulted in the Raman spectra of uranium metal whereas 325-nm excitation did not give rise to such spectra. Temperature dependence of the B3g mode at 126 cm−1 is also investigated. Copyright © 2011 John Wiley & Sons, Ltd.